国内外企业安全培训调查及模式的探讨

分析了国际劳工组织、日本和德国企业"双元制"培训模式的基本要点和我国"系统型"、"过渡型"、"组合型"、"发展型"、"顾问型"、"索罗门型"和"螺旋型"企业培训模式的基本要点;以国内大型、中型和小型企业为对象,对2007年和2008年的调查数据进行统计分析,根据"企业"与"个人"对安全培训的响应,揭示了不同企业当前的安全培训现状。结果表明:企业安全培训在借鉴国外先进经验的基础上,逐步趋于规模化、规范化,形成了安全知识结构、安全综合能力、安全管理技能、事故应急救援等方面的复合培训模式;实现了高层次管理人员对安全培训的认同达95%以上,员工对安全培训的认同达89%以上;使员工的安全意识、安全价值观、工作态度和工作技能得以提升,其在工作岗位上的表现达到安全要求,并为企业创造更多的效益。同时笔者还对当前我国企业安全培训工作存在的问题提出了改进意见,对今后各类企业安全培训具有参考价值和借鉴作用。     

安全生产效益的分析评价及其与安全投入的关系

通过把握和界定安全效益、安全投入等反映安全生产的经济活动特征和规律的经济学范畴的内涵,指出从企业的经营利润指标上看安全投入不能带来直接经济效益,只产生远期(长远)的、潜在的间接性效益,包括间接经济效益和非经济效益,安全投入的效益具有间接性、潜在性、隐形性、不确定性和迟滞性。由于生产安全事故风险不可能为零,当事故预防水平达到一定程度(可接受的程度及其以下)时,通过增加经济投入提高预防水平而对于事故风险的削减无明显的效果,就应考虑与经济效益的结合问题。笔者提出安全投入数量限度问题和安全投入的阈值;并进一步建立安全效益评价模型和安全投入与安全指标的函数关系模型,对安全投入与安全水平(安全指标)、安全效益的关联关系进行了定性分析。     

基于指标规范值的室内空气客观评价的概率神经网络模型

为了建立简单、普适、通用的概率神经网络的室内空气评价模型,在适当设定室内空气各项指标的参照值及指标值的规范变换式基础上,使室内空气同级标准不同指标的规范值差异尽可能小,从而用规范值表示的各指标都可用同一个规范指标"等效"替代。因此,概率神经网络隐层各类模式的基函数中心矢量的各指标分量值与同级标准所有15项指标规范值的均值等同。将基于指标规范值的概率神经网络模型用于室内空气的评价实例进行检验,验证了该模型的普适性、通用性和简便性。     

Contamination of polychlorinated biphenyls and organochlorine pesticides in breast milk in Korea: Time-course variation,influencing factors,and exposure assessment

Breast milk is a noninvasive specimen to assess maternal and infant exposure to polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs). In this study, 206 breast milk samples were collected from 87 participants during lactation, at <7, 15, 30, or 90 days postpartum in four cities in Korea. The total concentrations of PCBs (ΣPCB) and OCPs (ΣOCP) ranged from <LOQ to 84.0 (median: 12.1) ng g⁻¹ lipid weight and from <LOQ to 559 (median: 144) ng g⁻¹ lipid weight, respectively. The residue levels of these contaminants measured in our study were relatively lower than those reported for European, African and Asian populations. Within a month postpartum typically after day seven the levels of ΣPCB and ΣOCP significantly increased. Some OCP compounds were correlated with maternal age, BMI, parity, and delivery mode. Certain types of dietary habits such as seafood and noodle consumption were significantly associated with ΣPCB and ΣOCP. The estimated daily intakes (EDIs) of ΣPCB and ΣOCP were 45.2–127 ng kg⁻¹ bw day⁻¹ and 625–1259 ng kg⁻¹ bw day⁻¹ during lactation, respectively, which are lower than the threshold values proposed by the US EPA and Health Canada. The exposure of Korean infants to chlordanes via breast milk had a potential health risk which deserves further investigation.     

Photolysis Behavior of Herbicide Propisochlor in Water Media and Preliminary Analysis of Photoproducts Under Different Light Sources

Photolysis behavior of a new herbicide propisochlor in water media as well as the effects of light sources, initial concentration of propisochlor, pH value, dissolved oxygen (DO) level, and salinity on the photolysis process was investigated. It was found that the relationship between initial concentration of propisochlor and its photodegradation rate was negatively correlated. The changes in acidity and alkalinity of the reaction medium influenced the photoreaction rate evidently. In the alkaline solution the degradation was accelerated. In the reaction media with different pH values, the photolysis followed the first-order kinetics. The presence of dissolved oxygen may promote the photolysis and there existed an optimum of dissolved oxygen concentrations. Increasing the DO level can weaken the promotion and even have an adverse effect. It was demonstrated that with dissolved oxygen the photodegradation of propisochlor followed the first-order kinetics equation. The addition of salt ions Ca²⁺ and Mg²⁺ changed the ionic strength and solvent polarity, resulting in the effect on propisochlor photolysis. The photoproducts were detected by both HPLC and GC-MS methods. It was found that photolysis products varied under different light sources. Conclusions may be reached that in the photodegradation of propisochlor, the benzene ring remained intact under irradiation of both solar light and high-pressure mercury lamp, and the amido link was relatively stable, while dechlorination was liable to take place; moreover, α-hydrogen at the substituent of benzene ring was active.     

鼎湖山主要森林类型土壤pH值动态变化

鼎湖山主要森林类型土壤pH值都较低,但从1994年以来土壤酸化都得到了控制,pH值比较稳定。针叶林土壤pH值比混交林高,季风常绿阔叶林pH值最低。     

地下水有机污染调查采样精密度评估方法探讨

对国际标准化组织(ISO)在《水样采集与处理的质量控制指南》中提出的采样精密度控制方法不完全适用于地下水有机污染调查评价工作的部分进行了分析。在华北平原地下水有机污染调查评价工作的基础上,探讨了一种改进的采样精密度控制与评估方法,提高相关工作的质量控制水平。     

环境空气污染物预测浓度与环境背景值叠加应注意的问题

着重阐述了建设项目环境影响评价中环境空气污染物的预测值和背景值相加必须具备的条件 ,得出了在大气环境影响评价中一、二类评价的叠加及三类评价的操作方法。     

An Integrated Approach Towards Assessing the Value of Water: A Case Study on the Zambezi Basin

The aim of this paper is to develop a methodology for assessing the value of water in the different stages in the water cycle. It is hypothesised that if a cubic metre of water provides some benefit in some spot at a certain moment, this cubic metre of water has a certain value not only at that point in space and time, but in its previous stages within the water cycle as well. This means that, while water particles flow from upstream to downstream, water values ‘flow’ in exactly the opposite direction. The value of water in a certain place is equal to its value in situ plus an accumulated value derived from downstream. This value-flow concept is elaborated for the Zambezi basin. It is found that water produces the smallest direct economic benefits in the upper part of the Zambezi basin. However, water flows in this part of the basin − due to their upstream location − have the highest indirect values. Return flows from the water-using sectors are particularly valuable in the upstream sub-basins. The analysis shows that the value per unit of river water increases if we go from downstream to upstream. Another finding of the study is that percolation of rainwater is generally more valuable than surface runoff. Finally, a plan to export water from the river Zambezi to South Africa is evaluated in terms of its opportunity costs. The results of this study show that the value-flow concept offers the possibility of accounting for the cyclic nature of water when estimating its value. It is stressed, however, that for the current study many crude assumptions had to be made, so that the exact numbers presented should be regarded with extreme caution. Further research is necessary to provide more precise and validated estimates. This revised version was published online in July 2006 with corrections to the Cover Date.     

城市污水处理厂剩余污泥热值测定方法优化研究

目前的城市污水处理厂剩余污泥热值的测定主要参考煤热值的测定方法。根据污泥的特性,对热值测定过程中污泥的干燥方式、助燃剂的影响和热值校正计算3个方面进行了优化研究。结果表明,冷冻干燥(-50℃)能够避免污泥有机物的挥发,从而精确地测定剩余污泥的热值;对于有机物含量较高的污泥(VS/TS>0.57),不添加助燃剂也能准确测定污泥的热值;通过测定氧弹洗液中硫酸和硝酸的含量来计算热值校正,从而准确得到污泥的热值。