Fluoride distibution and the effect of some ions along Alexandria coastal Mediterranean seawater of Egypt

The coastal seawater of Mediterranean of Alexandria receives large amount of discharged waters containing industrial wastes, sewage, and agricultural and domestic drainage. Fluoride and some parameters were(chemical and physical) determined. The data gave indication that the content and the amount of the discharged water largely affect the chemical composition of the coastal water. Stepwise regression analysis was highly significant and the model was very fruitful, where the observed and calculated values were mostly concordant. This may indicated that there was a relation between fluoride content in coastal seawater and its content in the discharged water.     

砖瓦厂含氟废气的治理

通过实验选取了一种固氟剂添加到砖坯中后，砖块的存氟率为９１０％，烟道气总氟排放降低率为７６７８％。连续五年的生物检测试验，没有发生任何家蚕氟中毒现象。固氟剂的应用为砖厂含氟废气的治理提供了一条新的途径     

危险废物特性比较研究

介绍了中国、美国及欧盟等国家和地区危险废物危险特性的定义及其鉴别指标体系。通过对三者的优缺点比较,分析了我国定义危险特性存在的问题．提出了我国危险废物特性制定建议。     

含氟废水的净化技术研究

对含氟废水处理技术的研究进行了介绍，讨论了各自的作用机理及其在含氟废水处理中的应用。为工程设计和生产工艺提出了一些有益的建议。在此基础上对含氟废水处理的发展趋势做了分析和展望。     

荧光光谱法研究丙酮与牛血清白蛋白的相互作用特征

在模拟动物体生理条件和不同温度下,用荧光光谱、三维荧光光谱、同步荧光光谱、紫外可见吸收光谱法等研究了丙酮(ACET)与牛血清白蛋白(BSA)的相互作用,证实了丙酮有很强的猝灭BSA荧光强度的能力.分别用Sterr-Volmer方程、Lineweaver-Burk双倒数方程和热力学方程等分析和处理试验数据,得到了它们相互作用的生成常数KLV(平均值为7.073×106L·mol-1)、热力学参数(△Hθ、△Gθ和△Sθ的平均值分别为-3.982kJ·mol-1、-26.51 kJ·mol-1和73.31J·K-1)和结合位点数(平均值为1.266)等.这为研究ACET对BSA构象的影响、ACET的毒理效应和生物学效应提供了重要信息.     

环境空气氟化物测定(LTP法)的不确定度评估

评估用电极法测定环境空气中氟化物的不确定度在环境监测分析中是一个复杂和繁琐的事.本文通过建立电极法测定环境空气氟化物的数学模型,以一个LTP法实例详述如何分析和计算得出测量扩展不确定度的结果,对于实际工作有很好的参考作用.     

磷肥厂副产氟硅酸利用的新方法

以磷肥厂副产氟硅酸为原料 ,加上碳酸钠 ,在适宜的工艺条件下反应 ,制取符合GB42 93— 84一级品的氟化钠和符合GB10 5 71— 89的白炭黑。该工艺具有原料易得、能耗低、成本低、投资省、无污染、经济效益好等优点     

重庆南山马尾松林衰亡与大气污染关系的讨论

重庆市南郊的南山是一个风景区,有林地约二万七千余亩,主要是马尾松林(Pinusmassoniana Lamb.),自八十年代起明显出现衰亡现象,目前约有85％马尾松植株受到不同程度的伤害,死亡率达35％左右.马尾松出现的症状是针尖坏死,针叶提早脱落,针长变短,树冠稀疏,枝条枯死,径向生长变弱等.     

Effect of sorbed and desorbed Zn(Ⅱ) on the growth of a green alga (Chlorella pyrenoidosa)

Toxic effect of Zn(Ⅱ)on a green alga(ChloreUa pyrenoidosa)in the presence of sepiolite and kaolinite was investigated.The Zn-free clays were found to have a negative impact on the growth of C.pyrenoidosa in comparison with control samples(without adding any clay or Zn(Ⅱ)).When Zn(Ⅱ)was added,the algae in the presence of clays could be better survived than the control samples,which was actually caused by a decrease in Zn(Ⅱ)concentration in the solution owing to the adsorption of Zn(Ⅱ)on the clays.When the solution system was diluted,the growth of algae could be further inhibited as compared to that in a system which had the same initial Zn(Ⅱ)concentration as in the diluted system.This in fact resulted from desorption of Zn(Ⅱ)from the zinc-contaminated clays,although the effect varied according to the different desorption capabilities of sepiolite and kaolinite.Therefore the adsorption and desorption processes of Zn(Ⅱ)played an important part in its toxicity,and adsorption and desorption of pollutants on soils/sediments should be well considered in natural eco-environmental systems before their risk of toxicity to aquatic organisms was assessed objectively.     

酸性高浓度含氟废水处理技术

介绍了对某化工厂排放的酸性高浓度含氟废水进行处理的试验，采用石灰中和沉淀，氯化钙（或聚丙烯酰胺）二级絮凝沉淀，砂滤工艺进行处理，操作控制条件如下：pH为8－9，Ca^2 与F^-的摩尔比为3．0，聚丙烯酰胺投加量为2mg/L，沉淀时间为1h，处理工程运行后的验收监测结果表明，出水中的残氟浓度可以达到国家规定的一级排放标准，且系统运行稳定，工艺简便。