Residues and dissipation of the pesticide emamectin benzoate under Egyptian field condition: a case study

A simple, rapid analytical procedure for the quantification of emamectin benzoate in tomato was developed using high performance liquid chromatography with fluorescence detector (HPLC-FLD). Emamectin benzoate residues were extracted from tomato samples with n-hexane:ethyl acetate (1:1, v/v). The method involved derivatization using trifluoroacetic anhydride and 1-methylimidazole, prior to analysis by HPLC-FLD. Limit of quantification of this method was found to be 0.01 mg/kg, while limit of detection was 0.005 mg/kg. The dissipation of emamectin benzoate on tomato was studied, and half-life (t_1/2) was estimated in a field study carried out at three different locations. Emamectin benzoate was sprayed on tomato at recommended dosage. Samples of tomato were collected at 0, 1, 3, 7, 10, and 15 days after treatment. The t_1/2 of emamectin benzoate when applied at the recommended doses in tomato was approximately 2.5 days. The residue of emamectin benzoate reached below the maximal residue limit (MRL) 10 days after spraying at the tested dosage. Hence, a safe pre-harvest interval of 10 days is suggested before harvesting of tomato. This study would also be helpful for the Egypt government to establish the MRL of emamectin benzoate in tomatoes and provide guidance on the proper and safe use of this insecticide.     

Metal removal with two biochars made from municipal organic waste: adsorptive characterization and surface complexation modeling

The adsorptive characteristics of biochar produced from garden green waste (S-char) and a mixture of food waste and garden green waste (FS-char) were investigated. Adsorption of Cu²⁺, Zn²⁺, and Mn²⁺ onto the two biochars reached equilibrium within 48 hours. The metal adsorption was effectively described by the pseudo-second-order kinetic and Freundlich isotherm models which suggest heterogeneous chemisorption. The initial solution pH influenced adsorption of Zn²⁺ and Mn²⁺ but not of Cu²⁺. Simulation via a surface complexation model showed that the fraction of XOCu⁺ adsorbed onto biochar was increased with increasing pH until it reached the adsorption maximum at pH 8.5, while the endpoint for the maximum of XOMn⁺ was higher than pH 12.     

Directions for hazardous waste storage and final disposal of treated hazardous waste (THW) in Austria

Austria produces about 700,000 tons of hazardous waste a year. Approximately 8% are sent to the incinerating facility EBS near Vienna. Approximately 60% THW (treated hazardous wastes) are finally disposed of. An unknown amount is sent to foreign countries for storage and landfilling.

By order of the Ministry of Agriculture and the Ministry of Public Health our institute elaborates guidelines for designing and operating final disposal hazardous waste facilities.

This paper deals with the fundamental aspects and the present state of these guidelines.     

MESIP∗: Modelling environmental scenarios in ponds

MESIP is a fugacity model which can predict the fate of organic hydrophobic chemicals in aquatic ecosystems. In this paper a short introduction to the mathematical model is presented together with a more detailed listing of the required input data. Comparison of the calculated and measured fate of a fluorescent whitening compound in an artificial outdoor pond is shown     

Industrial ecology flows of agriculture and food industry in Finland: utilizing by-products and wastes

Although half of the administrative units in China are said to have implemented their local Agenda 21, the promotion of sustainable communities is not pervasive. In this paper, we adopted a relatively untried mode of analysis and a socio-economic context to illustrate the potentials and failures of China's grassroots local government bodies in achieving sustainable waste management. Our study shows that, among the three main functions of sustainable waste management (ensuring environmental hygiene, provision of recycling logistics and changing the consumption pattern of the local community) for local governments, grassroots local government bodies in mainland China are only able to do the minimum, i.e. ensuring environmental hygiene and handling complaints. One of the reasons for the failure is that, despite the emphasis on capacity building in China's Agenda 21, the reality is that no action is taken to empower grassroots local government. Despite the high profile accorded by the Chinese central government to motivating local governments to formulate their own Agenda 21, local sustainability and waste management performance have little relevance to the appraisal systems of these government agents.     

冶金行业环境污染物的特征与监测技术综述

冶金行业是国民经济重要的基础原材料工业,在其制造体系中大量的物质、产品流、废弃物、能量转换过程、多形式的排放过程都对环境造成不同层次和程度上的影响。针对不同工艺产生的污染物特征及主要污染物的种类,综述了环境监测运用的各类监测技术、监测方法,为环境管理、污染源控制、环境规划等提供科学依据。     

Empirical analysis on the influence of the Shaanxi fruit industry on regional food security

As part of its development policy to relieve rural poverty in west China, the Chinese government has introduced measures such as agricultural tax exemptions, agricultural subsidies, and scientific, technological and restructuring improvements to agriculture. Following these actions, farmers’ incomes have increased greatly and the economy in poor areas of west China has seen rapid improvements. However, agricultural restructuring, infrastructure construction and ecological restoration projects have reduced the area of land under arable farming, restricting opportunities for increasing total grain yield. Regional food security is therefore threatened and an imbalance between economic development and food security is created. Shaanxi is a representative province in west China where agricultural restructuring has resulted in large areas of arable land being converted into orchards that produce higher economic returns. This study randomly surveyed 1430 farm households in three counties in the apple-producing region of Shaanxi Province (Luochuan, Changwu and Baishui). The standard of living and household income of farmers in the fruit production areas were higher than in grain-producing areas, thus discouraging grain production. Land under agriculture in the counties studied comprised 59% orchards and 39% arable, with 2% under other uses. Per capita, 204.3 kg of grain was produced, 51% of that required for self-sufficiency. Other staple foods produced amounted to only 13.9% of that needed for self-sufficiency. As a result, nearly half of the grain needed by the community was purchased from outside, resulting in very poor regional food security. Clearly, fruit production in this region seriously affects regional food security. Coordination of relationships between rural economic development and regional food security is key for sustainable development of the regional agriculture and economy of west China.     

Towards a sustainable future: a holistic inquiry of waste management behaviors of Singapore households

ABSTRACT

In 2018, Singapore produced a 7.7 million tonnes of waste, which is a significant amount of waste for a small nation-state. In line with the Sustainable Development Goal (SDGs) targets 11.6 and 12.5 of the 2030 Agenda, which addresses cities’ waste generation and management impacts, we ask the question of why Singapore households are not more proactively engaged in waste minimization, despite the presence of local waste minimization public campaigns. This study is the first known study to comparatively apply and test three major theories – social psychological, social-structural, and sociocultural theories, to explain household waste management behavior in Singapore. A national survey followed by regression analysis of 303 households was conducted. In our findings, we firstly describe current trends in household waste management behaviors. Secondly, we compared each applied theory’s ability to predict households’: (1) reuse and (2) recycling of a variety of household items; and (3) recycling frequency. We obtained partial evidence supporting the role of future-orientedness and environmental identity on householders’ variety reuse and recycling. Social-structural (age cohort x income, education) and situational variables (the convenience thesis), also predicted various waste minimization behaviors. Finally, householders’ knowledge of what is recyclable affected all forms of waste minimization behaviors. In view of the study’s findings, we propose a need for targeted planning and policy interventions for different segments of the Singapore population, and different short- and longer-term measures to initiate and achieve sustained household waste minimization.     

森林净生态系统生产力及其生物影响因子研究进展

在全球大气二氧化碳浓度上升的背景下,陆地生态系统碳循环及碳汇功能研究得到了广泛的关注,日益成为今后的政治和外交的重大议题之一.净生态系统生产力(net ecosystem production, NEP)是生态系统光合固定的碳与生态系统呼吸损失的碳之间的差值;或者为生态系统净的碳积累速率.NEP 的研究整合生态系统地上和地下部分,把生态系统碳循环的影响因子有机地联系了起来.当NEP为正值时,说明生态系统为碳汇,NEP为负值则表明生态系统为碳源.随着植物和土壤相互联系及其对生态系统过程研究的深入,NEP已经成为生态系统碳循环研究的核心概念之一.以森林NEP为出发点,综述了国内外的最近的 NEP 研究进展,分析了 NEP 研究的科学意义;探讨了植物群落组成/生物多样性、土壤微生物群落、大型/土壤动物和人为的管理或干扰等生物因子对NEP的影响.根据综述研究提出未来研究应在:(1)土壤生物过程、土壤食物网及其与地上部分植物/动物相互作用对NEP的影响;(2)自然林生物多样性的竞争/共存机制与生态系统碳吸存稳定性;(3)人工林固碳潜力和不同植物功能群(灌草层)对生态系统碳动态影响等方面加强,以期为全面认识生物因子对森林生态系统系统固碳现状、机制和潜力提供理论基础.     

A fresh perspective on food safety in Canada: risk communication,public involvement,and the impact of the 2008 listeriosis outbreak

While the listeriosis outbreak of 2008 brought attention to food safety decision making in Canada, little of that attention was placed on public involvement and risk communication. With a primary focus on Health Canada (HC) and the Canadian Food Inspection Agency (CFIA), this article describes the state of microbial-related public involvement and risk communication undertakings and suggests ways in which improvements can be made. The findings show that public involvement and risk communication activities have been strengthened since the outbreak, but they have become neither dialogical nor highly participatory. HC engages with experts to a far greater extent than with the lay public and it has fallen short in fulfilling its stated commitment to openness and transparency. Furthermore, both HC's and the CFIA's approach to risk communication has been overly general, has failed to provide opportunities for dialogue with vulnerable and more general groups with whom it is communicating and is not rooted in foodborne surveillance data. Public involvement in food safety governance would be improved if HC provided the lay public with a seat on advisory committees and improved its public involvement reporting methods. HC and the CFIA could also make risk communication improvements by creating opportunities for dialogue between officials and the general public, and by exploring alternative risk communication vehicles, such as food labels.