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71.
典型工业半焦的孔隙分形结构分析 总被引:1,自引:0,他引:1
工业半焦是一种具有复杂的微观孔隙拓扑结构的多孔物质.基于分形理论,引入分形维数对工业半焦不规则孔隙结构的粗糙、复杂程度进行了定量表征和描述.选取具有典型煤种和工艺代表性的工业半焦样品,用孔隙度分析仪对其孔隙结构特征进行了测量,并利用其测量数据进行了分形维数的分析计算.计算结果表明,工业半焦的孔隙结构符合分形特征,在样品颗粒尺寸为2.36~3.35mm的测量条件下,样品的分形维数在2.7982~2.9154之间,其可决系数在0.9157~0.9614之间;样品的分形维数与煤种和半焦热解工艺过程均有一定的关系.通过对工业半焦分形维数的计算分析,可以更加全面准确地了解其孔隙结构特征,以期为分析评价其吸附和活化潜力、制定恰当的活化工艺提供更加可靠的依据. 相似文献
72.
73.
硫化物生物氧化脱硫技术研究现状 总被引:4,自引:0,他引:4
介绍了近年来国内外硫化物生物氧化为单质硫的各种脱硫技术.分析总结了硫化物生物氧化为单质硫工艺的各种影响因素,包括氧硫比、溶解氧浓度、硫化物浓度、化学氧化、微生物菌种、pH值、温度等因素.提出了生物氧化脱硫技术的发展前景.该技术将脱硫和单质硫的回收和为一体,是一种安全、低成本将含硫废液变废为宝的工艺技术. 相似文献
74.
贵州汞矿矿区不同位置土壤中总汞和甲基汞污染特征的研究 总被引:34,自引:7,他引:27
为了深入理解汞矿矿区土壤中总汞和甲基汞的污染特征,应用AAS、GC-CVAFS方法,分别对贵州万山、务川和滥木厂汞矿矿区不同位置土壤以及对照区土壤中的总汞(THg)和甲基汞(MeHg)进行了测定.结果表明,万山汞矿区土壤THg和MeHg含量范围分别为1.1~790 mg·kg-1和0.19~15μg·kg-1,务川汞矿区土壤THg和MeHg含量范围分别为0.33~317mg·kg-1和0.41~20μg·kg-1,滥木厂汞矿区土壤THg和MeHg含量范围分别为0.41~610 mg·kg-1和0.70~8.8μg·kg-1.对照区土壤汞含量明显低于矿区土壤,其THg和MeHg含量范围分别为0.14~1.2 mg·kg-1和0.09~0.23μg·kg-1;对照区土壤THg含量接近或稍高于全球背景土壤THg含量0.01~0.5 mg·kg-1.研究表明,汞矿区稻田土壤具有较强的汞甲基化能力,其MeHg含量明显高于菜地和旱田土壤;万山汞矿区土壤汞污染程度明显高于滥木厂和务川汞矿区土壤汞污染. 相似文献
75.
Trace Element Concentrations and Bioindicator Responses in Tree Swallows from Northwestern Minnesota 总被引:5,自引:0,他引:5
Custer CM Custer TW Warburton D Hoffman DJ Bickham JW Matson CW 《Environmental monitoring and assessment》2006,118(1-3):247-266
Extremely high concentrations of cadmium (3.5 μg/g dry wgt.) and elevated concentrations of chromium (>10 μg/g dry wgt.) and mercury (1.6 μg/g dry wgt.) were reported in waterbird tissues at Agassiz National Wildlife Refuge in northwestern Minnesota in 1994. Tree
swallows (Tachycineta bicolor) were studied during 1998–2001 at three drainages into the Refuge, two pools on the Refuge, and at a nearby reference location
to document whether high levels of contaminants were still present, and if so to quantify the source and severity of the contamination.
Trace elements were measured in tree swallow eggs, livers, and diet. Reproductive success and bioindicator responses were
monitored. In 2000, water was drawn down on Agassiz Pool, one of the main pools on the Refuge. This presented an opportunity
to evaluate the response of trace element concentrations in the diet and tissues of tree swallows after reflooding. High concentrations
of trace elements were not detected in swallow tissues, nor were there differences among locations. Less than 20% of swallow
samples had detectable concentrations of cadmium or chromium. Mercury concentrations were low and averaged <0.25 μg/g dry wgt. in swallow tissues. Trace elements, including mercury, did not increase in tree swallows following the 2000 drawdown
at Agassiz Pool. Hatching success and survival of nestlings to 12 days-of-age for tree swallows on the Refuge were similar
to the national average and consistent with background trace element concentrations. Bioindicator measurements were within
the normal ranges as well. 相似文献
76.
Obiri S Dodoo DK Okai-Sam F Essumang DK Adjorlolo-Gasokpoh A 《Environmental monitoring and assessment》2006,118(1-3):37-49
Food crops such as cassava, cocoyam and other tuber crops grown in mining communities uptake toxic or hazardous chemicals
such as arsenic, and cadmium, from the soil. Cassava is a stable food for Ghanaians. This study evaluated human health risk
from eating cassava grown in some mining communities in Ghana such as Bogoso, Prestea, Tarkwa and Tamso, which are important
mining towns in the Western Region of Ghana. The study evaluated cancer and non-cancer health effects from eating cassava
grown in the study areas in accordance with US Environmental Protection Agency’s Risk Assessment guidelines. The results of
the study revealed the following: cancer health risk for Tamso, 0.098 (RME – Reasonable Maximum Exposure) and 0.082 (CTE –
Central Tendency Exposure). This means that approximately 10 and 8 out of 100 resident adults are likely to suffer from cancer
related cases by RME and CTE parameters respectively. For Prestea, we have 0.010 and 0.12, which also means that approximately
1 out of 100 and 10 resident adults out of 100 are also likely to suffer from cancer related diseases by RME and CTE parameters.
The results of the study obtained were found to be above the acceptable cancer risk range of 1× 10−6 to 1× 10−4, i.e., 1 case of cancer out of 1 million or 100,000 people respectively. 相似文献
77.
Mean values of eight contaminants in Herring Gull (Larus argentatus) eggs were calculated for 15 Great Lakes sites for the 5 year period 1998–2002. The sites were ranked according to the concentrations of each of seven compounds relative to fish flesh criteria for the protection of piscivorous wildlife, and a single overall rank of contamination was calculated for each site. Based on this weighted ranking scheme, we found that sum PCBs, dioxin and DDE contributed the most (60.2, 30.5% and 8.5%, respectively) to the overall rankings. The weighted ranking scheme showed that eggs from Channel-Shelter Island (Saginaw Bay, Lake Huron), Strachan Island (St. Lawrence River) and Gull Island (northern Lake Michigan) ranked as the three most contaminated sites, while Agawa Rocks (eastern Lake Superior), Chantry Island (southern Lake Huron) and Port Colborne (eastern Lake Erie) ranked as the three least contaminated sites. Two of the three most contaminated sites are Areas of Concern; none of the three least contaminated sites are Areas of Concern. 相似文献
78.
Kim KH Mishra VK Kang CH Choi KC Kim YJ Kim DS Youn YH Lee JH 《Environmental monitoring and assessment》2006,121(1-3):379-397
In the present study, the distribution patterns of various metals were analyzed and compared using PM samples collected concurrently from three monitoring sites located in Korea (Seoul, Busan, and Jeju island) in December 2002. As these sites can represent metal pollution with different degrees of anthropogenic activities, their concentration levels were distinguished in a systematic manner in the order of Jeju, Busan, and Seoul. By comparing the present data sets with those measured previously from other locations in Korea and around the world, we attempted to diagnose the general status of elemental pollution on the Korean peninsula. Through an application of different statistical approaches, the major processes controlling elemental levels were assessed for each of the three study sites. The results indicated the importance of both crustal and anthropogenic sources in all sites with their relative roles varying significantly from each other. The results of the metal analysis data, when examined in relation to back trajectory analysis, confirmed that their concentration changes are affected quite sensitively with air mass movement patterns. The overall results of this study consistently indicated the contribution of a strong anthropogenic source area (e.g., China) to the observed metal concentration levels in the study area, but the strengths of such signals vary considerably across the Korean peninsula. 相似文献
79.
80.
实验采用DMA-80自动测汞仪直接测定土壤中的汞含量,详细介绍了土壤样品中汞分析条件的选择,方法在0.4—400ng范围内,线性良好,其检出限为0.2ug/kg。 相似文献