土壤原位覆盖对底泥的修复作用研究

在高度厌氧底泥和富营养化水体构成的模拟生态系统中,采用土壤和硅藻土进行原位覆盖,研究了覆盖技术对水．沉积物界面微环境的改善作用和不同覆盖材料对苦草生长的影响。这2种底质覆盖后,表层底泥氧化还原电位（Eh）分别提高了48．37％和46．77％,底层水体的溶解氧消耗降低,水体中的总氮（TN）和总磷（TP）含量降低;与对照箱体的苦草死亡相比,经过土壤和硅藻土覆盖的箱体中苦草正常萌发、定植和生长;硅藻土箱体苦草的生物量、叶绿素和根茎比均高于土壤覆盖箱体。因此,原位覆盖能有效改善底层水体和表层底泥的氧化还原环境,隔绝污染底泥和延缓营养盐释放,为沉水植物种子萌发和幼苗生长提供有利的生境条件。     

LCA of local strategies for energy recovery from waste in England, applied to a large municipal flow

An intense waste management (WM) planning activity is currently undergoing in England to build the infrastructure necessary to treat residual wastes, increase recycling levels and the recovery of energy from waste. From the analyses of local WM strategic and planning documents we have identified the emerging of three different energy recovery strategies: established combustion of residual waste; pre-treatment of residual waste and energy recovery from Solid Recovered Fuel in a dedicated plant, usually assumed to be a gasifier; pre-treatment of residual waste and reliance on the market to accept the ‘fuel from waste’ so produced. Each energy recovery strategy will result in a different solution in terms of the technology selected; moreover, on the basis of the favoured solution, the total number, scale and location of thermal treatment plants built in England will dramatically change. To support the evaluation and comparison of these three WM strategy in terms of global environmental impacts, energy recovery possibilities and performance with respect to changing ‘fuel from waste’ market conditions, the LCA comparison of eight alternative WM scenarios for a real case study dealing with a large flow of municipal wastes was performed with the modelling tool WRATE. The large flow of waste modelled allowed to formulate and assess realistic alternative WM scenarios and to design infrastructural systems which are likely to correspond to those submitted for approval to the local authorities. The results show that all alternative scenarios contribute to saving abiotic resources and reducing global warming potential. Particularly relevant to the current English debate, the performance of a scenario was shown to depend not from the thermal treatment technology but from a combination of parameters, among which most relevant are the efficiency of energy recovery processes (both electricity and heat) and the calorific value of residual waste and pre-treated material. The contribution and relative importance of recycling and treatment/recovery processes change with the impact category. The lack of reprocessing plants in the area of the case study has shown the relevance of transport distances for recyclate material in reducing the efficiency of a WM system. Highly relevant to the current English WM infrastructural debate, these results for the first time highlight the risk of a significant reduction in the energy that could be recovered by local WM strategies relying only on the market to dispose of the ‘fuel from waste’ in a non dedicated plant in the case that the SRF had to be sent to landfill for lack of treatment capacity.     

基于天气分型的北京地区雷电潜势预报预警系统

对1997-2006年457个雷暴过程的环流形势进行对比分析,将北京地区的雷暴天气分为东北低涡低槽、贝蒙低涡低槽、西来槽等11种雷暴天气型;利用南郊观象台(54511站)的探空资料计算对流有效位能、抬升指数和相对风暴螺旋度等33个对流参数,通过与北京地区SAFAIR3000获取的闪电定位资料进行统计分析,提取BCAPE、BLI、MDCI、BIC、KNEW和SWISS等6个对流参数作为北京地区潜势预报参数;采用事件概率回归(REEP)方法,利用获取的6个对流参数作为变量,形成了11种雷暴天气型下的潜势预报方法。利用WRF模式的预报场,建立适用于北京地区3～36 h雷电潜势预报系统。个例实验结果表明其具有较好准确性。由于该系统建立过程中使用了高分辨率探测资料和中尺度模式的输出结果,实现了雷电潜势预报由点到面,由粗到细的突破,对北京地区雷电预警预报具有一定的应用价值。     

南水北调中线工程水源区蒸散发计算方法比较及影响因素分析

以南水北调中线工程水源区为研究区域,采用1961~2007年9个气象站点气象观测数据和黄家港水文站实测径流资料,以FAO彭曼蒙特斯公式和水文模拟法为标准分别对多种潜在蒸散发计算方法和实际蒸散发计算方法进行比较研究,并分析了陆面蒸散发的影响因素。研究表明：南水北调中线工程水源区存在“蒸发悖论”现象,Priestley Taylor公式计算结果偏大,但与FAO 彭曼蒙特斯公式存在良好的相关关系,在气象资料较少时可以考虑建立相关方程进行推求。傅抱璞公式与水文模拟法计算结果较为接近,相关关系最优。潜在蒸散发与平均温度、气温日较差、实际水汽压、降雨量、风速、净太阳辐射、日照时数呈正相关,而实际蒸散发与平均温度、气温日较差、实际水汽压、降雨量、净太阳辐射、日照时数呈正相关,与风速呈负相关。净太阳辐射是影响陆面蒸散发的核心因素     

焦化废水处理过程外排污泥中重金属形态特征及其潜在环境风险

焦化废水处理过程所排放污泥中重金属的含量及化学形态是否构成环境风险将直接影响污泥处置方法的选择,为此,实验采用BCR顺序提取法分析了焦化废水处理站外排污泥中重金属(Cd、Hg、Pb、Cr、As、Ni、Zn、Cu和Mn)的形态特征,并采用地累积指数(Igeo)和潜在生态危害指数(RI)评价了重金属对土壤的潜在环境风险。研究结果表明:除Ni主要以可氧化态存在外,焦化废水外排污泥中其他几种重金属元素主要存在于残渣态,重金属元素的含量低于《城镇污水处理厂污染物排放标准(GB18918—2002)》中的控制限值;与城市污泥相比,焦化废水外排污泥具有低Pb、Cr、Zn、Cu含量,而高Cd、Hg、Mn含量的特点;基于Igeo和RI的评价结果,Cd和Hg是外排污泥中具有一定环境风险的元素,需要考虑其下游去向。焦化废水处理外排污泥中主要存在残渣态重金属成分,不表现为很高的环境风险,其处置应重点考虑其中有机污染物特别是POPs。     

天津市典型河网区沉积物中重金属分布及生态风险评价

选择天津市典型河网区为研究对象,分析了沉积物中6种重金属(Cr、Cu、Mn、Ni、Pb和Zn)的分布特征,并采用富集系数法和潜在生态危害指数法分析了重金属的来源,进而评价了其生态风险。结果表明,表层沉积物中Cr、Cu、Mn、Ni、Pb和Zn的平均含量分别是58.18、23.52、524.60、22.93、25.24和49.51 mg/kg,其中Cr、Mn和Ni含量均低于天津市土壤背景值,而Cu、Pb和Zn含量在部分样点高于背景值;在垂直分布上,沉积物中Cr和Ni的含量相对稳定,而Cu、Mn、Pb和Zn的含量从底层到表层均先增加后降低。重金属富集系数(EF)分析显示,河网区表层沉积物中Cu和Zn在个别样点以及Pb在近一半样点存在人为输入过程(EF1.5),与接纳上游及区域的生活污水、农田退水有关,而Cr、Mn和Ni均来自自然源。重金属综合潜在生态危害指数(RI)评价表明,整个河网区表层沉积物为轻微生态危害水平,对区域的水环境质量不构成威胁。     

催化铁与生物法耦合除磷工艺特性

为了研究催化铁与生物耦合后对生物除磷特性的影响,实验采用人工配水用厌氧／好氧间歇流式富集培养聚磷微生物。对比发现,催化铁与生物耦合组中厌氧末段ORP降低了约60mV,pH值小幅度的上升（≤0．3）,整个培养过程中铁离子的浓度开始快速增加,之后趋于稳定（约40mgFe／gMLSS）。对好氧末段污泥SVI值比较发现,耦合工艺污泥沉降性能得到改善。除磷曲线比较发现,耦合组中厌氧末段磷的释放量下降,而好氧阶段磷的吸收速率增加;胞内聚合物提取表明,耦合组厌氧末段聚磷菌细胞内PHA含量有提高,好氧末段糖原含量有下降。磷形态提取分析表明,耦合组好氧末段污泥中无机态PO3 4-- P含量更高。低浓度铁离子可以起到与生物耦合同步除磷的目的,本工艺长期运行未发现耦合体系中催化铁对除磷的抑制作用。     

催化铁与生物法耦合除磷工艺特性简

为了研究催化铁与生物耦合后对生物除磷特性的影响,实验采用人工配水用厌氧/好氧间歇流式富集培养聚磷微生物。对比发现,催化铁与生物耦合组中厌氧末段ORP降低了约60 mV,pH值小幅度的上升（≤0.3）,整个培养过程中铁离子的浓度开始快速增加,之后趋于稳定（约40 mg Fe/g MLSS）。对好氧末段污泥SVI值比较发现,耦合工艺污泥沉降性能得到改善。除磷曲线比较发现,耦合组中厌氧末段磷的释放量下降,而好氧阶段磷的吸收速率增加;胞内聚合物提取表明,耦合组厌氧末段聚磷菌细胞内PHA含量有提高,好氧末段糖原含量有下降。磷形态提取分析表明,耦合组好氧末段污泥中无机态PO^3-₄-P含量更高。低浓度铁离子可以起到与生物耦合同步除磷的目的,本工艺长期运行未发现耦合体系中催化铁对除磷的抑制作用。     

Certainty and uncertainty in understanding global warming

Global warming has greatly concerned the whole world.Owing to the limitation we currently have,it is still difficult to completely understand the mechanism and physical science of climate change.Now both certainty and uncertainty coexist in the understanding of climate warming.This paper aims to summarize certainties and uncertainties in climate-warming studies,which focus on seven key problems related to human activities,namely,global warming,atmospheric concentrations of greenhouse gases,relationship between greenhouse gas emissions and climate warming,climate models,future climate change,2?warming threshold and tipping point in the Earth's system.We should comprehensively take into account the level of certainty and uncertainty in our understanding of climate change while adapting to and mitigating global warming and adjusting our industrial structures accordingly.This would allow us to respond to change with certainty,while avoiding the risks associated with uncertainty.     

电除尘器内 MHD 数值理论研究及模拟计算分析

磁流体力学偏微分方程组（ MHD）描述了导电流体在电磁场中运动状态,借助CFD软件,应用MHD模型计算分析放电极电位分布及颗粒运动轨迹特性,结果表明：空间电荷效应对电位分布有明显的加强作用;粒径越大,颗粒荷电量越多,受空间电场力作用越明显;湍流对颗粒运动轨迹影响不容忽视。