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61.
Deema Mohamed Ali Okdeh;Ibrahim Aziz Sakr;Tareq ARRAJ ARRAJ; 《环境质量管理》2024,34(1):e22175
The unreasonable use of agrochemicals and various human activities in the environment of Al-Sin Lake basin may cause pollution to water, especially with widely used organophosphate pesticides, which have an effect on the human nervous system. This research sought to determine concentrations of dichlorvos of the synthetic organophosphate pesticide in the waters of the environment surrounding Al-Sin Lake in the Syrian coastal area. A questionnaire form was dispensed to the local residents in the region, to determine the status of the studied area. Ground and surface water samples were collected from several locations surrounding the Lake. The first site is surrounded by greenhouses and a citrus orchard. The second is the Surit spring. The third site includes greenhouses. The fourth site represents surface water (Lake Surit). The study lasted for seven consecutive months from December until June 2020–2021, samples were taken once a month. Various parameters (pH, EC, TDS, and PO4−3) were measured. Dichlorvos was extracted from the samples using solvents (hexane-acetone) to be ready for analysis using high-performance liquid chromatography. The results showed the presence of dichlorvos residues in the studied water samples, with average concentrations ranging between 0.2 and 1.3 µg.L−1, which were higher than the recommended value for individual pesticide in water (0.1 µg.L−1) as recommended by the European Union. Observations of dichlorvos concentration indicated some increase at lower pH. Consequently, contamination of ground and surface waters with dichlorvos was observed in the studied sites, because of its frequent use and its high solubility in water. This unregulated use of dichlorvos can pose a matter of public health concern. 相似文献
62.
Jack E. McKee 《Journal of the American Water Resources Association》1971,7(4):740-749
ABSTRACT There are several possible ways in which wastewater from municipalities may be reclaimed and reused so as to minimize the need for imported water in North Central Texas. The rationale for reuse is enhanced by the fact that new water quality requirements in the Trinity River system will necessitate a very high degree of treatment at municipal sewage plants, just for discharge to surface streams. The largest potential market for municipal effluent is the steam-electric power industry. Within the next decade the generating capacity for electric power in North Central Texas will have to be more than doubled to meet increasing demand. Adequate supplies of condenser cooling water for such expansion will be difficult to obtain and assure. New large power stations might advantageously be located adjacent to municipal wastewater treatment plants, to utilize effluent as make-up water for cooling towers. Experience elsewhere has shown that well-treated wastewater can be used for cooling tower make-up with a minimum of trouble, with a considerable saving in overall cost, and with conservation of pristine water for other uses. 相似文献
63.
Guillermo Cabrera Miguel A. Marino 《Journal of the American Water Resources Association》1976,12(2):317-335
ABSTRACT. Transient, two-dimensional solutions are developed which describe the movement and distribution of a conservative substance in a stream-aquifer system. The solutions are obtained by solving sequentially the groundwater flow and mass transport equations. A variational approach in conjunction with the finite element method is used to solve the groundwater flow equation. Galerkin's approach coupled with the finite element method is used to solve the mass transport equation. Linear approximated triangular elements and a centered scheme of numerical integration are employed to calculate the hydraulic head distribution and the concentration of solute in the flow region. The linear approximation used to define the concentration function within each element is not appropriate for cases involving steep concentration gradients. For such cases, higher order approximations are necessary to assure the continuity of gradients across interelemental boundaries. Numerical examples that illustrate the applicability of the model are presented. 相似文献
64.
Mark R. Williams Anthony R. Buda Herschel A. Elliott Kamini Singha James Hamlett 《Journal of the American Water Resources Association》2015,51(4):883-897
Riparian seeps have been recognized for their contributions to stream flow in headwater catchments, but there is limited data on how seeps affect stream water quality. The objective of this study was to examine the effect of seeps on the variability of stream NO3‐N concentrations in FD36 and RS, two agricultural catchments in Pennsylvania. Stream samples were collected at 10‐m intervals over reaches of 550 (FD36) and 490 m (RS) on 21 occasions between April 2009 and January 2012. Semi‐variogram analysis was used to quantify longitudinal patterns in stream NO3‐N concentration. Seep water was collected at 14 sites in FD36 and 7 in RS, but the number of flowing seeps depended on antecedent conditions. Seep NO3‐N concentrations were variable (0.1‐29.5 mg/l) and were often greater downslope of cropped fields compared to other land uses. During base flow, longitudinal variability in stream NO3‐N concentrations increased as the number of flowing seeps increased. The influence of seeps on the variability of stream NO3‐N concentrations was less during storm flow compared to the variability of base flow NO3‐N concentrations. However, 24 h after a storm in FD36, an increase in the number of flowing seeps and decreasing streamflow resulted in the greatest longitudinal variability in stream NO3‐N concentrations recorded. Results indicate seeps are important areas of NO3‐N delivery to streams where targeted adoption of mitigation measures may substantially improve stream water quality. 相似文献
65.
乙醇在地下水硝酸盐原位去除中的可利用性 总被引:1,自引:0,他引:1
由于地下水中溶解氧的约束与电子供体的缺乏,地下水硝酸盐污染的原位修复十分困难。论文通过实验室微元体、砂柱和含水砂槽实验研究,发现:乙醇作为电子供体,容易被普遍存在的反硝化菌利用,同时导致硝酸盐被快速去除,且没有亚硝酸盐积累;含水介质中的溶解氧对该过程影响是短暂的,有限的溶解氧被率先利用后,硝酸盐去除速率明显加快;乙醇不会被含水介质吸附,迁移能力强,其羽状体中溶解氧与硝酸盐通常是低浓度的,甚至是缺失的。用乙醇作为电子供体,促进地下水硝酸盐原位修复,投注简便,不要外来微生物接种,具有很强的可利用潜力。 相似文献
66.
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68.
以过硫酸钠(Na2S2O8)为氧化剂,柠檬酸(CA)螯合Fe(Ⅱ)溶液作为活化剂,建立箱体模型模拟场地三氯乙烯(TCE)污染土壤的原位化学氧化修复.结果表明,经CA螯合Fe(Ⅱ)活化的Na2S2O8能较好的修复TCE污染土壤,持续氧化27 d后TCE浓度降到10 mg·kg-1以下;采用抽出氧化、循环再用的方式,地下水TCE浓度到45 d时降到21.4 μg·L-1.同时,氧化过程中过硫酸钠会产生SO42-,使土壤和地下水的pH降低;土壤有机质含量下降约10.1%. 相似文献
69.
Gary K. Speiran 《Journal of the American Water Resources Association》2010,46(2):246-260
Speiran, Gary K., 2010. Effects of Groundwater-Flow Paths on Nitrate Concentrations Across Two Riparian Forest Corridors. Journal of the American Water Resources Association (JAWRA) 46(2):246-260. DOI: 10.1111/j.1752-1688.2010.00427.x Abstract: Groundwater levels, apparent age, and chemistry from field sites and groundwater-flow modeling of hypothetical aquifers collectively indicate that groundwater-flow paths contribute to differences in nitrate concentrations across riparian corridors. At sites in Virginia (one coastal and one Piedmont), lowland forested wetlands separate upland fields from nearby surface waters (an estuary and a stream). At the coastal site, nitrate concentrations near the water table decreased from more than 10 mg/l beneath fields to 2 mg/l beneath a riparian forest buffer because recharge through the buffer forced water with concentrations greater than 5 mg/l to flow deeper beneath the buffer. Diurnal changes in groundwater levels up to 0.25 meters at the coastal site reflect flow from the water table into unsaturated soil where roots remove water and nitrate dissolved in it. Decreases in aquifer thickness caused by declines in the water table and decreases in horizontal hydraulic gradients from the uplands to the wetlands indicate that more than 95% of the groundwater discharged to the wetlands. Such discharge through organic soil can reduce nitrate concentrations by denitrification. Model simulations are consistent with field results, showing downward flow approaching toe slopes and surface waters to which groundwater discharges. These effects show the importance of buffer placement over use of fixed-width, streamside buffers to control nitrate concentrations. 相似文献
70.
Endocrine disrupting chemical(EDC) pollution in river-based artificial groundwater recharge using reclaimed municipal wastewater poses a potential threat to groundwater-based drinking water supplies in Beijing, China. Lab-scale leaching column experiments simulating recharge were conducted to study the adsorption, biodegradation, and transport characteristics of three selected EDCs: 17β-estradiol(E2), 17α-ethinylestradiol(EE2) and bisphenol A(BPA). The three recharge columns were operated under the conditions of continual sterilization recharge(CSR), continual recharge(CR), and wetting and drying alternative recharge(WDAR). The results showed that the attenuation effect of the EDCs was in the order of WDAR CR CSR system and E2 EE2 BPA, which followed first-order kinetics. The EDC attenuation rate constants were 0.0783, 0.0505, and 0.0479 m-1 for E2, EE2 and BPA in the CR system, respectively. The removal rates of E2, EE2, and BPA in the CR system were 98%, 96% and 92%, which mainly depended on biodegradation and were affected by water temperature.In the CR system, the concentrations of BPA, EE2, and E2 in soil were 4, 6 and 10 times higher than in the WDAR system, respectively. According to the DGGE fingerprints, the bacterial community in the bottom layer was more diverse than in the upper layer, which was related to the EDC concentrations in the water-soil system. The dominant group was found to be proteobacteria, including Betaproteobacteria and Alphaproteobacteria, suggesting that these microbes might play an important role in EDC degradation. 相似文献