环境中丙烯酰胺检测方法和健康危害的研究进展

丙烯酰胺广泛应用于工业生产,是一种潜在的环境污染物。本文从丙烯酰胺的检测方法和健康危害2个方面总结了目前的研究进展。检测方法上,以高效液相色谱-质谱串联法(HPLC-MS/MS)最为常用,一些新技术也逐渐应用到分析中。健康危害方面,丙烯酰胺可引起实验生物的神经、生殖、遗传和发育等毒性和潜在致癌性。其毒性机理为:直接损坏神经元;使活性氧(ROS)积累导致氧化损伤;诱发基因位点突变,或与DNA形成加合物而致其损伤等。鉴于目前研究存在的问题,对以后的工作进行了展望:加强监管与治理工作,保护生态环境和人类健康;深入开展丙烯酰胺对生物体的毒性效应研究;加强我国环境中丙烯酰胺的跟踪监测工作;建立一种快捷的生物测试系统来评估水体(尤其是海洋环境)中丙烯酰胺的毒性风险。     

制氢装置重大危险源辨识

简要介绍了我国现行重大危险源辨识标准,并结合制氢装置实际对企业前期开展的重大危险源普查结论进行分析,提出辨识结论及监控建议.     

我国城市重大危险源管理探讨

目前我国城市安全问题严重,城市重大危险源的管理工作还比较落后,在认识到这些客观问题的基础上,探讨我国城市重大危险源管理问题和方法,以期预防和减少重大事故的发生,保障企业生产安全稳定地进行.     

A survey of rainstorms as weather hazards in southern Nigeria

This paper examines the role played by winds as a weather hazard in urban centres of southern Nigeria. It is observed that strong winds associated with rainstorms at the beginning of the rainy season are a threat to urban centres as they directly affect buildings and infrastructure. Wind hazards also have indirect social and economic consequences on the communities affected. Much of the damage done to buildings is as a result of inappropriate building designs that have not taken into consideration the wind environment. An inventory of reports of damage caused by winds during the first half of 1995 showed that different towns in eight states were affected. These incidences occurred mainly at the beginning of the rainy season when strong winds are associated with linesqualls. Although wind related hazards have not been adequately acknowledged as an environmental problem that needs to be properly addressed in Nigeria, as in the case of flooding, results have shown that it is a problem that requires government intervention in view of global climate change and consequent extreme weather events. Wind hazard awareness and preparedness as integral aspects of development policy and planning of the environment is therefore needed in West African countries where linesqualls are very significant rain producers.     

Integrating flood hazard into site selection of detention basins using spatial multi-criteria decision-making

This study presents an innovative approach for the integration of flood hazard into the site selection of detention basins. The site selection process is conducted by taking into account multiple criteria and disciplines. Hydraulic modeling results derived from stormwater management model are employed by Technique for the Order of Prioritization by Similarity to Ideal Solution (TOPSIS) to determine flood hazard score. The score generated by TOPSIS is used in a spatial multi-criteria decision-making site selection framework. Applying the framework, a suitability map is generated in which primary locations for detention basin placement are determined. The method is demonstrated through the case study of Darakeh River Catchment, which is located in northern Tehran, Iran. The presented framework can be easily utilized for site selection of other stormwater management techniques, such as low impact development and best management practices, due to its versatility.     

环境危险源分析方法与应用研究

针对具有环境污染隐患的一类危险源界定模糊的研究现状,在与一般危险源比较基础上,首次探讨了环境危险源的内涵和外延。系统梳理和总结了危险源分析方法,结合环境问题的特点提出了环境危险源分析方法建议。借鉴环境风险分析一般过程,首次明确提出环境危险源分析可按照"系统分析—概率分析—后果评价—风险表征"这4个步骤进行。环境危险源分析方法与应用研究对于提高环境危险源评价的科学性、降低环境危害事故发生的概率和危害程度具有重要的意义。     

太子河水系印染行业重点污染河段优先控制污染物的确定

通过对太子河水系印染行业重点污染河段-海城河三期水样的采集以及水样中有机污染物的检测分析,获取了48种有机污染物的平均浓度水平,其中浓度较高的是苯酚(28.18μg/L)、邻苯二甲酸二(2-乙基己基)酯(22.30μg/L)和苯乙酮(8.818μg/L)。结合流域的实际污染状况,采用"改进潜在危害指数法",对海城河检测出的有机污染物进行加权综合评分计算,按照综合分数值大小,对其进行排序,提出了44种优先控制污染物名单,其中包括酯和酞酸酯类7种、含氮杂环类7种、胺及苯胺类5种、氯苯类6种、硝基苯类5种、苯酚类7种、苯及其他取代苯类5种、多环芳烃类2种,大部分污染物与印染行业废水排放有着密切关系。     

Heavy metals in soils along unpaved roads in south west Cameroon: Contamination levels and health risks

Soils enriched with heavy metals from vehicular emission present a significant exposure route of heavy metals to individuals using unpaved roads. This study assessed the extent of Cd, Cr, Co, Cu, Ni, Pb and Zn contamination of soils along unpaved roads in Cameroon, and the health risks presented by incidental ingestion and dermal contact with the soils using metal contamination factor (CF) pollution load index, hazard quotients (HQ) and chronic hazard index (CHI). CF values obtained (0.9–12.2) indicate moderate to high contamination levels. HQ values for Cr, Cd and Pb exceeded the reference doses. Moderate health hazard exists for road users in the areas with intense anthropogenic activities and high average daily traffic (ADT) volume according to CHI values (1–4) obtained. The economy and quality of life in cities with unpaved roads could be threatened by health challenges resulting from long-term exposure to heavy metal derived from high ADT volumes.     

Assessment of health risk from organochlorine pesticides residues in high-fat spreadable foods produced in Poland

Currently, butter and margarine are food products attracting wide customer interest. Every day, consumers around the world buy these products for human consumption. Butter is obtained from milk fat, while margarine is derived from vegetable oils. The content of organochlorine pesticide (OCP) residues was examined in both types of these high fatty products. A gas chromatograph with MSD (HP 5973) detector was used for the determination of pesticides such as α-HCH, β-HCH, γ-HCH, DDT, DDD, DDE, aldrin, dieldrin, endrin, heptachlor and heptachlor epoxide. The examined products had diverse concentrations of the analyzed compounds. Visible was the division based on the origin of the product, which might be composed of animal or vegetable fats. The research has revealed the presence of OCP residues in all examined spreads. Quantities of organochlorine compounds did not pose an immediate danger to the consumers’ health. Human and environmental health risk assessment was carried out by the estimation of lifetime average daily dose (LADD) and non-carcinogenic health hazard quotient (HQ). Total estimated LADD ranged between 1.3 × 10^?5 and 3.1 × 10^?5 mg kg^?1 d^?1 for butter, and 1.9 × 10^?6 and 4.6 × 10^?6 mg kg^?1 d^?1 for margarine and mix spread. The HQ ranged between 1.1 × 10^?4 and 3.7 × 10^?4 for butter, and 1.4 × 10^?5 and 9.0 × 10^?6 for margarine and mix spread for adults. These estimated HQs were within the safe acceptable limits, indicating a negligible risk to the residents of the study area.     

Natural radioactivity levels in topsoil from the Pearl River Delta Zone, Guangdong, China

Concentrations of the natural radionuclides ²³⁸U, ²²⁶Ra, ²³²Th and ⁴⁰K have been measured by γ-ray spectrometry in 796 topsoil samples from the Pearl River Delta Zone (PRDZ) of Guangdong, China. The mean concentrations for ²³⁸U, ²²⁶Ra, ²³²Th and ⁴⁰K were found to be 140 ± 37 Bq kg⁻¹, 134 ± 41 Bq kg⁻¹, 187 ± 80 Bq kg⁻¹ and 680 ± 203 Bq kg⁻¹ dry mass, respectively. These values were all higher than the mean values in soil for China and the world. Outdoor air-absorbed dose rates, calculated from activity concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K, ranged from 86 to 237 nGy h⁻¹, with a mean value of 165 ± 46 nGy h⁻¹. The corresponding annual outdoor effective dose rate per person was estimated to be between 0.11 and 0.29 mSv y⁻¹, with a mean value of 0.20 ± 0.06 mSv y⁻¹, which was also higher than the world mean value of 0.07 mSv y⁻¹. The radium equivalent activity (Ra_eq) and the external hazard index (I_r) resulted from the natural radionuclides in soil, were also calculated and found to vary from 230 to 676 Bq kg⁻¹ and from 0.6 to 1.8, respectively. The Ra_eq and the I_r in all the investigated regions were up to 75% higher than the set limits of 370 Bq kg⁻¹ and 1.0, respectively.