采空区瓦斯涌出源位置对瓦斯分布影响的数值模拟

根据多孔介质渗流理论,利用Fluent软件,分别对采空区瓦斯在整个采空区均匀涌出、上邻近层及底板遗煤涌出2种情况下采空区瓦斯分布规律进行了数值模拟.结果表明:采空区瓦斯为上邻近层及底板遗煤处涌出时,沿走向方向,靠近上邻近层及底板处高体积分数瓦斯距离工作面较近;沿竖直方向,瓦斯体积分数分布呈钩状,靠近瓦斯涌出源处瓦斯体积分数最高;整个采空区均匀涌出时采空区瓦斯体积分数分布与上邻近层及底板遗煤涌出时有很大差别.因此,为了得到更符合实际情况的瓦斯分布规律,数值模拟时应按照现场实际的瓦斯涌出源位置建立模型.     

落石冲击作用下架设油气管道响应分析

针对影响油气管道安全运营的落石冲击问题,基于弹塑性力学、Cowper-Symonds本构模型和有限元方法,建立了球形落石冲击油气管道的计算模型,对管道动态响应过程进行了数值模拟。对冲击速度、落石半径、管道内压力和落石冲击位置进行了参数敏感性分析,研究了各参数对管道冲击变形的影响规律。结果表明:落石的冲击能量主要用于管道塑性变形;冲击过程中,落石与管道的接触区域由初始的椭圆斑逐渐变成了椭圆环;管道塑性变形随着冲击速度和落石半径的增大而增大,随内压和落石偏移度的增大而减小。该研究工作为油气管道的安全评价及防护工程的设计提供了参考依据,对保障油气安全运输具有重要的工程意义。     

回采工作面瓦斯涌出量遗传投影寻踪回归预测

为快速、准确预测回采工作面瓦斯涌出量,基于投影降维思想,建立一种遗传算法(GA)投影寻踪回归预测方法。选取煤层瓦斯原始含量、埋藏深度、煤层厚度、煤层倾角、工作面长度、推进速度、采出率、临近层瓦斯含量、临近层厚度、临近层层间距、岩层岩性、开采深度作为评价因子,对某矿15个学习样本进行训练,建立GA投影寻踪回归预测模型。利用该矿3个实测样本对模型进行检验,并与主成分分析和BP神经网络方法结果进行对比。研究表明:利用GA投影寻踪回归预测回采工作面瓦斯涌出量,平均误差为3.43%,最大误差为5.7%,精度优于其他2种方法。     

页岩气压裂作业人因失误结构化辨识方法研究

为提高页岩气压裂作业人因失误辨识结果的全面性和针对性,建立一种结构化的人因失误辨识方法。通过概括辨识阶段的作业流程,建立作业人员行为模型,概述作业人员的行为阶段。利用筛选出的引导词辨识行为阶段人因失误。将该方法应用于页岩气压裂过程的替液阶段。结果表明,用引导词能明确辨识方向,减少头脑风暴时间以及对专家知识的依赖;辨识过程的动态调整能改善认知可靠性,使更多人因失误模式(与传统CREAM方法相比)被辨识出来。     

基于LCA的北京市公交车节能及温室气体减排潜力分析

新能源公交车是未来城市公交行业节能及温室气体减排的重点发展方向.新能源公交车在行驶阶段具有良好的节能及温室气体减排效果,而汽车制造、能源生产等相关生命周期阶段的能耗及温室气体排放常被忽视,且目前新能源公交车的乘客运载功能相对较弱,可能对节能及温室气体减排的潜力造成较为显著的影响.因此,本文基于北京市公交车的运营特征,采用生命周期评价(LCA)方法,选择客运周转量作为功能单位,核算了天然气公交车、混合动力公交车和纯电动公交车等新能源公交车相对于柴油公交车的节能及温室气体减排效益.结果表明:发展新能源公交车对促进北京市公交行业及城市节能低碳发展具有积极的作用,但相对于基于运营里程的核算结果,本研究新能源公交车节能及温室气体减排潜力均较低,主要原因是新能源公交车的实际载客量相对较低;混合动力公交车和纯电动公交车在空调开启时的节能潜力与温室气体减排潜力均远低于天然气公交车;通过发展情景分析,建议北京市现阶段应优先发展天然气公交车,适当发展纯电动公交车和混合动力公交车,以减少北京市公交车的总体能耗,同时降低温室气体排放强度.     

QuEChERS: a sample preparation for extraction of carbaryl from rat feces

Carbamate compounds are an important group of cholinesterase inhibitors. There is a need for creating awareness regarding the risks of the inadequate carbamate use in the residential areas due to potential adverse human effects. Carbaryl is a commonly used pesticide worldwide. A simple, fast, and high-throughput method was developed employing liquid chromatography with fluorescence detector to determine carbaryl residues in rat feces. The extraction was performed by using a rapid, easy, cheap, effective, reliable, and safe (QuEChERS) method, using acetonitrile as the extracting solvent. The parameters for the performance of the extraction method were optimized, such as ratio of mass of sample per volume of extraction solvent, QuEChERS content, and cleanup columns. Linear response was obtained for all calibration curves (solvent and matrix-matched) over the established concentration range (5–500 μg/L) with a correlation coefficients higher than 0.999. The achieved recovery was 97.9% with relative standard deviation values of 1.1% (n = 4) at 167 μg/kg fortified concentration level and the limits of detection and quantification were 27.7 and 92.3 µg/kg, respectively.     

Experimental investigation of the efficiency of triple rinsing of agricultural containers regarding their characterization as non-hazardous wastes

The efficiency of water rinsing for removing fenthion from non-combustible used pesticide containers was investigated. Four hundred empty containers from four olive oil producing areas in Greece were studied. Following triple rinsing cleaning procedures, the amount of fenthion retained in the container ranged from 0.01% to 0.1% w/w of its initial concentration. Extraction was accomplished with acetone, and the extracts were analyzed with a capillary gas chromatographic system coupled with flame ionization detector. The results obtained showed that triple rinsing is an effective procedure for removing fenthion from used pesticide containers, since the remaining pesticide concentration was below the legislated threshold value. Consequently, the containers can be handled as non-hazardous solid wastes.     

管道中烟道气流动传热及酸凝结规律

针对注烟道气稠油热采中管道输送烟道气酸凝结问题,以连续性方程、能量方程和动量方程为基础建立了烟道气沿管道流动与传热计算模型,计算了烟道气沿管道的压力分布、温度分布和酸凝结点距离,分析了不同入口参数和烟道气成分对管道中烟道气的压力、温度、酸凝结点的影响。结果表明:SO3或水蒸汽含量增加时,烟道气酸凝结点温度提高,凝结点距离减小;入口烟道气压力提高,烟道气压降变小,温降不变,酸凝结点距离减小;入口烟温升高,压降和温降都增大,酸凝结点距离增大;保温层厚度增加,温降减小,酸凝结点距离增大。计算和分析结果表明:减少烟道气中SO3或水蒸汽含量可以有效地增大酸凝结点距离,减轻管道腐蚀问题。     

Hg0 removal from flue gas over different zeolites modified by FeCl3

The elemental mercury removal abilities of three different zeolites (NaA, NaX, HZSM-5) impregnated with iron (III) chloride were studied on alab-scale fixed-bed reactor. X-ray diffraction, nitrogen adsorption porosimetry, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and temperature programmed desorption (TPD) analy-ses were used to investigate the physicochemical properties. Results indicated that the pore structure and active chloride species on the surface of the samples are the key factors for physisorption and oxidation of Hg⁰, respectively. Relatively high surface area and micropore volume are beneficial to efficient mercury adsorption. The active Cl species generated on the surface of the samples were effective oxidants able to convert elemental mercury (Hg⁰) into oxidized mercury (Hg²⁺). The crystallization of NaCl due to the ion exchange effect during the impregnation of NaA and NaX reduced the number of active Cl species on the surface, and restricted the physisorption of Hg⁰. Therefore, the Hg⁰ removal efficiencies of the samples were inhibited. The TPD analysis revealed that the species of mercury on the surface of FeCl₃-HZSM-5 was mainly in the form of mercuric chloride(HgCl₂), while on FeCl₃-NaX and FeCl₃-NaA it was mainly mercuri coxide(HgO).     

Methane and nitrous oxide emissions from a subtropical coastal embayment (Moreton Bay, Australia)

Surface water methane (CH₄) and nitrous oxide (N₂O) concentrations and fluxes were investigated in two subtropical coastal embayments (Bramble Bay and Deception Bay, which are part of the greater Moreton Bay, Australia). Measurements were done at 23 stations in seven campaigns covering different seasons during 2010-2012. Water-air fluxes were estimated using the Thin Boundary Layer approach with a combination of wind and currents-based models for the estimation of the gas transfer velocities. The two bays were strong sources of both CH₄ and N₂O with no significant differences in the degree of saturation of both gases between them during all measurement campaigns. Both CH₄ and N₂O concentrations had strong temporal but minimal spatial variability in both bays. During the seven seasons, CH₄ varied between 500% and 4000% saturation while N₂O varied between 128 and 255% in the two bays. Average seasonal CH₄ fluxes for the two bays varied between 0.5 ± 0.2 and 6.0 ± 1.5 mg CH₄/(m²·day) while N₂O varied between 0.4 ± 0.1 and 1.6 ± 0.6 mg N₂O/(m²·day). Weighted emissions (t CO₂-e) were 63%-90% N₂O dominated implying that a reduction in N₂O inputs and/or nitrogen availability in the bays may significantly reduce the bays' greenhouse gas (GHG) budget. Emissions data for tropical and subtropical systems is still scarce. This work found subtropical bays to be significant aquatic sources of both CH₄ and N₂O and puts the estimated fluxes into the global context with measurements done from other climatic regions.