天然气长输管道建设对生态环境的影响及防范措施

针对天然气长输管道建设影响面广、介质危险性大的特点,从对土地利用方式、土壤环境、林业生态系统、农业生态系统、野生动植物、景观、地质等方面分析施工期的环境影响。提出预防、减缓、植被恢复、管理、风险防范等方面的生态保护措施,特别给出了林地生态系统、农田生态系统、野生动物、土壤的具体保护措施;从加强环境管理、加强施工人员的环保意识、加强野生动物保护的宣传力度方面提出了针对性的管理措施。     

全程加热采样管和半程加热采样管对超净排放污染源颗粒物监测结果的影响

根据《煤电节能减排升级与改造行动计划》以及《国家环境保护"十三五"规划纲要》,我国燃煤电厂污染物排放浓度应达到现行燃气锅炉标准,现行颗粒物监测仪器需要进行更新。现在市面上有2种污染源颗粒物采样管可对改造后电厂进行颗粒物采样监测,采用平行实验法对这2种采样管所采集的颗粒物质量结果进行分析,同时使用验证实验分析2种采样管颗粒物采集质量结果产生差异的原因,并对如何提升燃煤电厂颗粒物监测的准确性提出建议。     

1960~2014年秦岭南北无霜期时空变化特征及对比分析

全球气候变暖背景下,自然生态环境敏感区农业热量资源的时空特征研究具有重要的现实意义。依据1960~2014年秦岭南北47个气象站数据,利用线性趋势、M-K检验和kriging插值法对无霜期时空变化进行分析。结果显示：从时间上看,秦岭南北无霜期随纬度增加而减少,初霜日和无霜期在年际波动中略有下降后快速上升,终霜日在波动中略有上升后快速下降。55年来无霜期呈显著的延长趋势且发生增多突变,秦岭以北、秦岭南坡、汉水流域和巴巫谷地的延长速率分别为0.400 6、0.280 4、0.396 1和0.407 5 d/a,突变年份分别为1999、2002、2001和1990年。从空间上看,无霜期平均值和标准差由南向北增加,80%站点初霜日推后、终霜日提前和无霜期延长。多数无霜期延长是初霜日推后与终霜日提前的共同影响。无霜期在28个站点呈波动变化,19个站点发生突变,突变时间多在1990s~2000s,2000s的突变区域面积最大且集中分布在东北部。分析结果可为气候变化对生态环境和农业生产布局的影响提供参考。     

Volatile organic compounds at swine facilities: A critical review

Volatile organic compounds (VOCs) are regulated aerial pollutants that have environmental and health concerns. Swine operations produce and emit a complex mixture of VOCs with a wide range of molecular weights and a variety of physicochemical properties. Significant progress has been made in this area since the first experiment on VOCs at a swine facility in the early 1960s. A total of 47 research institutions in 15 North American, European, and Asian countries contributed to an increasing number of scientific publications. Nearly half of the research papers were published by U.S. institutions.Investigated major VOC sources included air inside swine barns, in headspaces of manure storages and composts, in open atmosphere above swine wastewater, and surrounding swine farms. They also included liquid swine manure and wastewater, and dusts inside and outside swine barns. Most of the sample analyses have been focusing on identification of VOC compounds and their relationship with odors. More than 500 VOCs have been identified. About 60% and 10% of the studies contributed to the quantification of VOC concentrations and emissions, respectively. The largest numbers of VOC compounds with reported concentrations in a single experimental study were 82 in air, 36 in manure, and 34 in dust samples.The relatively abundant VOC compounds that were quantified in at least two independent studies included acetic acid, butanoic acid (butyric acid), dimethyl disulfide, dimethyl sulfide, iso-valeric, p-cresol, propionic acid, skatole, trimethyl amine, and valeric acid in air. They included acetic acid, p-cresol, iso-butyric acid, butyric acid, indole, phenol, propionic acid, iso-valeric acid, and skatole in manure. In dust samples, they were acetic acid, propionic acid, butyric acid, valeric acid, p-cresol, hexanal, and decanal. Swine facility VOCs were preferentially bound to smaller-size dusts.Identification and quantification of VOCs were restricted by using instruments based on gas Chromatography (GC) and liquid chromatography (LC) with different detectors most of which require time-consuming procedures to obtain results. Various methodologies and technologies in sampling, sample preparation, and sample analysis have been used. Only four publications reported using GC based analyzers and PTR-MS (proton-transfer-reaction mass spectrometry) that allowed continuous VOC measurement. Because of this, the majority of experimental studies were only performed on limited numbers of air, manure, or dust samples. Many aerial VOCs had concentrations that were too low to be identified by the GC peaks.Although VOCs emitted from swine facilities have environmental concerns, only a few studies investigated VOC emission rates, which ranged from 3.0 to 176.5 mg d⁻¹ kg⁻¹ pig at swine finishing barns and from 2.3 to 45.2 g d⁻¹ m⁻² at manure storages. Similar to the other pollutants, spatial and temporal variations of aerial VOC concentrations and emissions existed and were significantly affected by manure management systems, barn structural designs, and ventilation rates.Scientific research in this area has been mainly driven by odor nuisance, instead of environment or health concerns. Compared with other aerial pollutants in animal agriculture, the current scientific knowledge about VOCs at swine facilities is still very limited and far from sufficient to develop reliable emission factors.     

超临界锅炉受热面管内氧化皮的防治措施研究

目前,超临界锅炉受热面管内氧化皮生成、脱落的防治一直是国内外安全生产的技术难题。针对锅炉受热面管内氧化皮的生成、脱落的成因及其造成的安全隐患进行了详细分析,并结合多年的生产实践经验,配合实例介绍了相应的防治措施,对同类电厂超临界锅炉受热面管内氧化皮的处理提供了一定参考。     

基于ARIO模型的汶川地震灾后恢复重建期模拟

基于区域投入产出模型(ARIO),以一个月为时间步长,模拟了汶川地震后四川省各部门产出和需求随重建进程的变化过程。模拟结果表明:汶川地震的完全恢复重建大致需要近9年的时间,灾后36个月时,四川省的当地总产出能力将超过灾前水平。在重建模拟的基础上,评估了灾后实施不同风险管理策略的潜在效益,若最大生产能力在灾后3个月内能够加速达到灾前的150%,则与无加速重建相比,恢复重建期至少可以缩短3年半,证明了灾后加大人力和物力投入对于缩短恢复重建期的作用。提出的重建期模拟方法可以为缩短重建期、合理分配抗灾救灾资源的灾害管理提供技术支撑。     

Comparisons of ambient air particulates concentrations (TSP,PM2.5) and dry depositions during smog and non-smog periods at Luliao,Shalu District sampling site

The concentrations of ambient total suspended particulates (TSP) and PM_2.5, and the dry depositions at a sample site at Luliao Junior High School (Luliao) in central Taiwan were measured during smog and non-smog days between December 2017 and July 2018. The results are compared to those obtained during non-smog periods in the years 2015–2017. The mean TSP and PM_2.5 concentrations and dry deposition flux were 72.41?±?26.40, 41.88?±?23.51?μg/m³, and 797.57?±?731.46?μg/m² min, respectively, on the smog days. The mean TSP and PM_2.5 concentrations and dry deposition flux on the non-smog days were 56.39?±?18.08, 34.81?±?12.59?μg/m³ and 468.93?±?600.57?μg/m² min, respectively. The mean TSP concentration in the smog period was 28% greater than that in the non-smog period, and the mean PM_2.5 concentration was 20% higher. The mean dry deposition flux in the smog period was 70% higher than that in the non-smog period at Luliao. The PM_2.5 concentrations exceeded the standards set by the Taiwan EPA (35?μg/m³ daily, and 15?μg/m³ annually). Therefore, the TSP and PM_2.5 concentrations and dry deposition must be reduced in central Taiwan on smog days. In addition, atmospheric TSP and PM_2.5 concentrations at various sampling sites were compared, and those herein were not higher than those measured in other countries. Finally, apart from the local traffic emissions, during smog periods, the other pollution source originated from the transportation process of traffic pollutants emitted in the northwest side of Taiwan.     

微波加热及真空集成再生活性炭

吸附法油气回收技术中,吸附剂的再生是一个难点和研究重点。微波加热再生作为一种新技术,受到人们的广泛关注。运用正交实验,研究了微波功率、辐照时间、活性炭量和真空度对吸附了汽油油气的富活性炭的再生率和损耗率的影响,发现影响顺序为微波功率〉辐照时间〉活性炭量〉真空度。综合考虑各方面因素,得出实验的最优方案为微波功率300W、辐照时间240s、活性炭量4g、真空度O．06MPa。还研究了活性炭多次吸附一再生后平衡吸附率和表面结构的变化。结果表明,微波和真空法对活性炭的表面结构影响不大,有利于活性炭的多次循环利用。综合比较真空再生法、真空和加热再生法、微波和真空再生法的再生效果,结果表明,微波和真空再生法稳定性较好。     

预掘回撤通道末采围岩破坏机制研究

为保证工作面安全高效回撤,通过理论分析及现场观测法,研究综采工作面末采期间回撤通道围岩应力分布及破坏特征,提出垛架支撑力控制顶板围岩破坏机制及方法,得到垛架最小支撑力计算方法.结果表明:回撤通道围岩集中应力与工作面前方支承压力逐步叠加,导致剩余煤柱由两侧向中部逐渐破坏,当两侧破坏区连通时,煤柱上方直接顶跨距增加为原来的...     

柱后衍生离子色谱法测定土壤和沉积物中的六价铬

采用加热回流提取、柱后衍生离子色谱法分离土壤和沉积物中的六价铬,使用紫外可见检测器进行测定。选用7种土壤和沉积物的实际样品,依次讨论了氢氧化钠-碳酸钠溶液、碳酸氢钠溶液、氢氧化钠-氯化钾溶液、离子色谱碱性淋洗液4种不同提取剂对六价铬的提取效率,以及超声提取、水浴振荡提取和恒温磁力搅拌冷凝回流3种提取方式的提取效果;研究了10～60 min、25～190℃条件下的最佳提取时间和加热温度;分析了不同提取剂体积和称样量比值条件下六价铬标土的测定量,并探究了提取液的保存条件。优化后的前处理条件：称取2.5 g筛分后的土壤或沉积物样品,加入25 mL NaOH/Na₂CO₃提取剂,在恒温磁力搅拌冷凝回流装置上于120℃加热回流60 min,离心后用0.22μm滤膜过滤,用柱后衍生离子色谱紫外检测装置进行测定。相比目前常用的分光光度法、原子吸收法等测定土壤中六价铬方法,柱后衍生离子色谱法特异性强,降低了差减法或其他前处理技术测定六价铬时所引入的误差,且不受提取液色度、浊度等影响。方法检出限可达0.002 mg/kg,灵敏度高,操作简便,抗干扰能力强,对于...