全文获取类型
收费全文 | 272篇 |
免费 | 44篇 |
国内免费 | 246篇 |
专业分类
安全科学 | 35篇 |
废物处理 | 11篇 |
环保管理 | 16篇 |
综合类 | 278篇 |
基础理论 | 109篇 |
污染及防治 | 102篇 |
评价与监测 | 5篇 |
社会与环境 | 6篇 |
出版年
2023年 | 8篇 |
2022年 | 13篇 |
2021年 | 20篇 |
2020年 | 15篇 |
2019年 | 13篇 |
2018年 | 27篇 |
2017年 | 36篇 |
2016年 | 35篇 |
2015年 | 29篇 |
2014年 | 33篇 |
2013年 | 62篇 |
2012年 | 24篇 |
2011年 | 23篇 |
2010年 | 22篇 |
2009年 | 21篇 |
2008年 | 21篇 |
2007年 | 27篇 |
2006年 | 13篇 |
2005年 | 18篇 |
2004年 | 19篇 |
2003年 | 11篇 |
2002年 | 7篇 |
2001年 | 14篇 |
2000年 | 3篇 |
1999年 | 6篇 |
1998年 | 5篇 |
1997年 | 4篇 |
1996年 | 5篇 |
1995年 | 6篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1991年 | 6篇 |
1990年 | 2篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
排序方式: 共有562条查询结果,搜索用时 78 毫秒
91.
The inhibitory efficiency of anionic copolymers and the effect of the biocides sodium hypochlorite, glutaraldehyde, and tris(hydroxymethyl)nitromethane on the precipitation behavior of calcium fluoride (CaF2) were studied. The efficiency of polymeric inhibitors was traced from conductivity measurements by using half-life (t1/2) method. X-ray diffraction parameters have been measured for calcium fluoride scale minerals. An anionic copolymer (K-798) acts as one of the best inhibitors for the precipitation process of the calcium fluoride in water as compared to K-775. It is assigned to the fact that the copolymer (K-798) contains both sulfonic acid and sulfonated styrene groups while the polymer (K-775) having only the sulfonic acid group. It was further observed that the biocides have no appreciable effect on the performance of the anionic polymeric inhibitors. 相似文献
92.
过氧化氢酶活性及活性抑制的紫外分光光度测定 总被引:66,自引:3,他引:66
在体内实验条件下,测定了鲤鱼肝脏过氧化氢酶的活性。实验结果表明,过氧化氢酶的紫外分光光度法是可靠的,活性抑制结果表明,对-二硝基苯对鲤鱼肝脏过氧化氢酶无有明显的抑制作用。鲤鱼肝脏过氧化氢酶可作为一项指标用于生态毒理学研究。 相似文献
93.
酸化土壤中铝及其植物毒性 总被引:33,自引:1,他引:33
本文综述了(1)影响土壤酸化的因素和铝的活化过程;(2)铝对植物的毒害症状,植物对铝的相对抗性以及铝的形态与植物毒性的关系;(3)影响铝毒性的外界因素如磷、钙和有机质;(4)铝的毒性机理,铝可能作用于生物膜、钙调素、DNA和ATP。最后提出了一些铝质土壤的改良措施。 相似文献
94.
95.
96.
Oxidation inhibition of sulfite in dual alkali FGD system 总被引:1,自引:0,他引:1
MO Jian-song WU Zhong-biao CHENG Chang-jie GUAN Bao-hong ZHAO Wei-rong 《环境科学学报(英文版)》2007,19(2):226-231
A laboratory-scale well-mixed thermostatic reactor with continuously blasting air was used to investigate the oxidation inhibition of sulfite in dual alkali flue gas desulfurization (FGD) system. The effects of operating parameters such as pH value and catalyst concentration on the oxidation were studied. Sodium thiosulfate was used in the system, and was found that it significantly inhabited the sulfite oxidation. In the absence of catalyst, sodium thiosulfate at 12.67 mmol/L had an inhibition efficiency of approximately 98%. While in the presence of catalyst, sodium thiosulfate at 26.72 mmol/L had an inhibition efficiency less than 85.0%. The oxidation reaction order of sulfite in the sodium thiosulfate was determined to be -1.90 and 4).55 in the absence and presence of the catalyst, respectively. Apparent activation energy of oxidation inhibition was calculated to be 53.9 kJ/mol. Pilot tests showed that the consumption rate of thiosulfate agreed well with the laboratory-scale experimental results. 相似文献
97.
采用化学抑制法,研究了不同曝气量下污水生物处理过程中N2O的释放源.结果表明,缺氧段中, N2O的主要释放源为硝酸盐异化成氨反应,而反硝化反应消耗N2O.好氧段中N2O释放源受曝气量的影响很大,当曝气量适中时(65L/h), N2O释放源主要为硝化细菌反硝化作用;而当曝气量偏高(105L/h)或偏低(25L/h)时,同步硝化-反硝化反应是主要的N2O释放源.同时硝化细菌反硝化反应也能够产生少量N2O. 相似文献
98.
硫酸铵和尿素对废物焚烧过程中多种途径生成氯苯类的抑制作用 总被引:1,自引:0,他引:1
氯苯类(CBz)是废弃物焚烧等过程中产生二英的前驱物,也被认为是实现二英在线检测的良好指示物,同时五氯苯(PeCBz)和六氯苯(HxCBz)也是持久性有机污染物(POPs).但氯苯在废物焚烧过程中的排放和控制尚没有受到足够重视,为此开展了模拟焚烧过程中硫酸铵和尿素对3种氯苯合成途径的抑制作用研究,包括飞灰合成,1,2-二氯代苯(1,2-DiCBz)转化高氯代苯等过程.结果表明,硫酸铵和尿素对氯苯的3种合成途径均有抑制作用,如1%尿素与废物混合焚烧对四氯苯、五氯苯和六氯苯的抑制效率分别达到了66.8%、57.4%和50.4%.比较硫酸铵和尿素对3种过程的抑制作用,认为尿素对氯苯具有更稳定的抑制能力. 相似文献
99.
100.
Phytotoxicity assessment of phenanthrene, pyrene and their mixtures by a soil-based seedling emergence test 总被引:1,自引:2,他引:1
Seedling emergence tests were conducted in a meadow brown soil using five plant species ( i. e., Chinese cabbage, green onion, tomato, turnip and wheat) to determine the phytotoxicity of phenanthrene, pyrene and their mixtures. The soil was amended with up to 1000mg/kg soil of phenanthrene or 600 mg/kg soil of pyrene. Seedling emergence and root growth were measured. The results indicated that root elongation was more sensitive than seedling emergence. Root length decreased with increasing phenanthrene or pyrene concentrations(p≤0.05). Phenanthrene was more phytotoxic than pyrene. The lowest observable adverse effect concentration(LOAEC) was 10mg/kg for phenanthrene when tested with green onion, and 50mg/kg for pyrene when tested with wheat. Among the five species, wheat was found to be the most sensitive. When amended jointly at or below their respective LOAEC, phenanthrene and pyrene produced a synergistic toxic effect. 相似文献