全文获取类型
收费全文 | 15102篇 |
免费 | 1671篇 |
国内免费 | 6904篇 |
专业分类
安全科学 | 2236篇 |
废物处理 | 542篇 |
环保管理 | 1699篇 |
综合类 | 11863篇 |
基础理论 | 2720篇 |
环境理论 | 9篇 |
污染及防治 | 2412篇 |
评价与监测 | 1298篇 |
社会与环境 | 600篇 |
灾害及防治 | 298篇 |
出版年
2024年 | 69篇 |
2023年 | 478篇 |
2022年 | 718篇 |
2021年 | 792篇 |
2020年 | 801篇 |
2019年 | 815篇 |
2018年 | 711篇 |
2017年 | 752篇 |
2016年 | 902篇 |
2015年 | 965篇 |
2014年 | 956篇 |
2013年 | 1594篇 |
2012年 | 1467篇 |
2011年 | 1618篇 |
2010年 | 1087篇 |
2009年 | 1325篇 |
2008年 | 985篇 |
2007年 | 1196篇 |
2006年 | 1139篇 |
2005年 | 883篇 |
2004年 | 711篇 |
2003年 | 611篇 |
2002年 | 495篇 |
2001年 | 411篇 |
2000年 | 381篇 |
1999年 | 297篇 |
1998年 | 258篇 |
1997年 | 223篇 |
1996年 | 195篇 |
1995年 | 194篇 |
1994年 | 121篇 |
1993年 | 120篇 |
1992年 | 96篇 |
1991年 | 41篇 |
1990年 | 44篇 |
1989年 | 28篇 |
1988年 | 23篇 |
1987年 | 15篇 |
1986年 | 15篇 |
1985年 | 8篇 |
1984年 | 12篇 |
1983年 | 18篇 |
1982年 | 20篇 |
1981年 | 13篇 |
1980年 | 11篇 |
1978年 | 6篇 |
1975年 | 4篇 |
1973年 | 5篇 |
1972年 | 5篇 |
1971年 | 33篇 |
排序方式: 共有10000条查询结果,搜索用时 531 毫秒
821.
Many release problems involve two-phase releases of hazardous materials of superheated liquids with high energy into the atmosphere. Such accidents are accompanied by violent phase transition and form catastrophic flashing jets. In this work, experimental and theoretical analyses were conducted to investigate dynamic characteristics of flashing jet morphology and their dependence on pressure-decay dynamics under different storage pressures, superheats, and nozzle diameters. Flashing jet morphology and angle throughout two-phase releases were captured by a high-speed camera, and the corresponding source pressure in the superheated liquid tank was measured simultaneously. Results show that three typical phases, expansion, stabilization, and decay, are characterized throughout two-phase release based on the evolution of flashing jet morphology. The jet initially expands gradually due to the enhancement of phase transition intensity, and then keeps stable when the intensity reaches its maximum, and terminally decays rapidly due to the depletion of superheated liquid. Phase transition intensity at the nozzle exit is mainly controlled by the pressure-decay dynamics. Bubbles nucleation inception sites gradually move upstream of the nozzle during the pressure decay process increasing the phase transition intensity. The increase of storage pressure, superheat and nozzle diameter promotes the mechanical and thermodynamic effects on the jet breakup. The significant increase of mechanical and thermodynamic effects effectively accelerates droplets evaporation and further affects flashing jet morphology. 相似文献
822.
Aluminum powder was always chosen as an additive to improve the explosive performance. In this work, experiments were performed to investigate the lower flammability limit (LFL) of volatile liquid fuel-aluminum powder mixtures using a 20 L closed spherical stainless steel vessel at a temperature of 20 °C (293 K) and 40 °C (313 K). The volatile liquid fuels tested in the work were diethyl ether (DEE), epoxypropane (PO), n-pentane and n-hexane. DEE, PO and n-pentane are in the liquid phase at room temperature and can easily transition to the gas phase at 40 °C (313 K). Through a series of experiments carried out, it was found that the change in phase would affect the interaction between the components. Aluminum powder always has an inhibitory effect on the flammability of the mixtures when it is mixed with gas-phase fuels. The inhibition effect was most obvious when the aluminum powder concentration reached 200 g/m3. While the interaction between aluminum powder and liquid-phase volatile fuels was promotion and was influenced by the component proportion and the type of the volatile fuels. 相似文献
823.
In recent years, significant progress has been made to ensure that process industries are among the safest workplaces in the world. However, with the increasing complexity of existing technologies and new problems brought about by emerging technologies, a strong need still exists to study the fundamentals of process safety and predict possible scenarios. This is attained by conducting the corresponding consequence modeling and risk assessments. As a result of the continuous advancement of Computational Fluid Dynamics (CFD) tools and exponentially increased computation capabilities along with better understandings of the underlying physics, CFD simulations have been applied widely in the areas of process safety and loss prevention to gain new insights, improve existing models, and assess new hazardous scenarios. In this review, 126 papers from 2010 to 2020 have been included in order to systematically categorize and summarize recent applications of CFD for fires, explosions, dispersions of flammable and toxic materials from accidental releases, incident investigations and reconstructions, and other areas of process safety. The advantages of CFD modeling are discussed and the future of CFD applications in this research area is outlined. 相似文献
824.
Robert A. Montgomery Madeline Carr Charlie R. Booher Abigail M. Pointer Brendan M. Mitchell Natalie Smith Keegan Calnan Georgina M. Montgomery Mordecai Ogada Daniel B. Kramer 《Conservation biology》2020,34(4):915-924
In November 1928, Theodore Jr. and Kermit Roosevelt led an expedition to China with the expressed purpose of being the first Westerners to kill the giant panda (Ailuropoda melanoleuca). The expedition lasted 8 months and resulted in the brothers shooting a giant panda in the mountains of Sichuan Province. Given the concurrent attention in the popular press describing this celebrated expedition, the giant panda was poised to be trophy hunted much like other large mammals around the world. Today, however, the killing of giant pandas, even for the generation of conservation revenue, is unthinkable for reasons related to the species itself and the context, in time and space, in which the species was popularized in the West. We found that the giant panda's status as a conservation symbol, exceptional charisma and gentle disposition, rarity, value as a nonconsumptive ecotourism attraction, and endemism are integral to the explanation of why the species is not trophy hunted. We compared these intrinsic and extrinsic characteristics with 20 of the most common trophy-hunted mammals to determine whether the principles applying to giant pandas are generalizable to other species. Although certain characteristics of the 20 trophy-hunted mammals aligned with the giant panda, many did not. Charisma, economic value, and endemism, in particular, were comparatively unique to the giant panda. Our analysis suggests that, at present, exceptional characteristics may be necessary for certain mammals to be excepted from trophy hunting. However, because discourse relating to the role of trophy hunting in supporting conservation outcomes is dynamic in both science and society, we suspect these valuations will also change in future. 相似文献
825.
为了解全氟辛烷磺酸盐(perfluorooctane sulfonate, PFOS)暴露对半滑舌鳎(Cynoglossus semilaevis)免疫功能的影响,在实验室条件下,运用RT-PCR方法分析了PFOS暴露对半滑舌鳎热休克蛋白hsp70、hsp90、C型凝集素(c-type lectin)和细胞色素c氧化酶(cytochrome c oxidase, cox)等4种免疫相关基因表达水平的影响。实验测定了上述4种基因在半滑舌鳎肝、鳃、肠及肌肉4种不同组织中随时间(0、24 h、48 h、96 h和7 d)的表达变化情况。结果表明,在4种组织中,hsp70基因的表达与对照相比为上调,其中,肝组织hsp70基因的表达量显著高于其他各组织,且表达高峰值的出现也早于其他各组织;hsp90基因在肝和鳃组织中表达量随时间不同而波动,在肠组织中表达上调,在肌肉中表达显著下调;c-type lectin基因表达量与对照组相比表达显著下调或无明显差异;cox基因在肝组织和肠组织中表达下调,在鳃和肌肉中表达上调。上述研究结果表明,PFOS能引起免疫相关基因的表达变化,对半滑舌鳎具有潜在的免疫毒性。肝组织中各免疫基因对PFOS胁迫的响应高于其他组织。本研究可为阐明全氟辛烷磺酸盐对半滑舌鳎的免疫毒性提供基础数据。 相似文献
826.
Zihao Li Yang Geng Lei Ma Xiaoyin Chen Junhua Li Huazhen Chang Johannes W. Schwank 《Frontiers of Environmental Science & Engineering》2020,14(4):65
827.
Yapeng Song Hui Gong Jianbing Wang Fengmin Chang Kaijun Wang 《Frontiers of Environmental Science & Engineering》2020,14(4):64
828.
Zhen Bi Deqing Wanyan Xiang Li Yong Huang 《Frontiers of Environmental Science & Engineering》2020,14(3):38
829.
Chaojin Jiang Xiaoqian Jiang Lixun Zhang Yuntao Guan 《Frontiers of Environmental Science & Engineering》2020,14(3):47
830.
An Ding Yingxue Zhao Huu Hao Ngo Langming Bai Guibai Li Heng Liang Nanqi Ren Jun Nan 《Frontiers of Environmental Science & Engineering》2020,14(6):96