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91.
简要分析化验室采样过程中存在的问题,并就如何对石化化验室采样过程实行HSE管理提出一些具体的管理办法。 相似文献
92.
综合近年来国内文献,概述了气相色谱法在我国土壤、生物等试样中有机污染物,多组份有机污染物及农药监测方面的应用。 相似文献
93.
本文将亚硝酸根在酸性介质中氧化亚铁氰化钾为铁氰化钾和鲁米诺-铁氰化钾-尿酸化学发光反应偶合一起,建立了一种间接测定亚硝酸根的新方法.讨论了酸度、反应物浓度、干扰离子等因素的影响.方法的检出限为5.0×l0-9g/mL,对环境水样样品进行了平行测定(n=11),其相对标准偏差为1.9~3.3%,线性范围为l.0×l0-7~1.0×l0-5g/mL,回收率为94.45~105.5%.方法简便,易于操作,并具有较高的灵敏度和选择性,结果令人满意. 相似文献
94.
半渗透膜采样技术在有机污染物分析中的应用 总被引:1,自引:0,他引:1
SPMD对亲脂性有机污染物具有富集倍数高(105),样品前处理简单,易于保存、携带,重现性好等特点。有可能成为一种新的相对标准监测方法。可用于研究有机污染物在空气、生物、污水处理、海水、沉积物河水、迁移规律以及水动力学模型的工具,进而可直接研究有机污染物有关的生态毒理实验。 相似文献
95.
The Ontario Ministry of Environment (MOE) recently participated in a joint Canadian/U.S. program to monitor the behavior and environmental impact of prescribed fires. Air, soil and ash samples were collected at the burn sites and analyzed for chlorinated dibenzo-p-dioxins (CDD) and dibenzofurans (CDF). Preliminary results indicated that larger air sample volumes were required. 相似文献
96.
本文介绍一个简单而灵敏的催化分光光度法,用于测定环境样品中微量碘,本法系基于亚硝酸根存在时微量碘离子催化还原硫氰酸铁络含物,并以分光光度计测量该红色络合物的减弱强度,在一定温度时,该络合物的分解速度正比于磺的含量.在给定的实验条件下,磺离子的浓度在0.001-0.024毫克/升之间服从比尔定律. 本法已成功地应用于天然水、土壤、海底泥和海生物中微量磺的测定,结果良好. 相似文献
97.
秦建成 《长江流域资源与环境》2005,18(5):489
样本稀疏地区空间插值法对区域化变量的精准管理具有重要意义。基于ArcGIS 90,在分析土壤属性空间分布特征的基础上,提出并构建了基于不同土壤类型的土壤特性空间预测模拟模型,对比了传统方法与改进方法空间插值精度,实现了数值插值在复杂地理环境区域的应用,得到以下结论:(1)基于经度、纬度、海拔高度及坡度等地理因子的土壤基础环境因子的空间预测模拟模型,突破以往只能描述土壤属性在水平方向变化的局限,较客观、合理地反映土壤属性随地理位置及海拔高度的立体变化特征;(2)基于不同土壤类型回归模型来增加样本点以推断评价指标在无取样地区的分布状况的处理方式具有一定的数学理论支撑,有效降低了插值误差,提高了评价精度,使评价结果更加接近现实。 相似文献
98.
《毒物与环境化学》2012,94(3-6):190-203
AbstractCarbon-coated magnetic nanoparticles were modified with cationic surfactant and used for the dispersive solid phase extraction of chlorophenols from aqueous samples. Surfactant adsorbed on the surface of the nanoparticles resulted in mixed hemimicelles for high extraction efficiency of chlorophenols. Under optimized conditions, calibration curves were linear from 0.5–20?mg L?1 for analytes with limit of detection between 0.2 and 0.4?mg L?1. The method was applied to extraction of chlorophenols from tap water, well water and industrial effluent. Recoveries were in the range of 94.0–99.4%, suggesting that sample matrix had little effect on the yields of extraction. 相似文献
99.
Intratracheal instillation of 51CrCl3 in anaesthetized rabbits resulted in partial absorption. In blood, the absorbed material was entirely confined to the plasma compartment. Only trace amounts were deposited in liver and kidney. By contrast, after similar application of Na, 51CrO4 the bulk of blood radioactivity was present in red blood cells (RBC). Substantial deposition occurred in liver and kidneys. It is concluded that Cr(VI) may enter the body unreduced via the lung and is partially deposited in cells over a prolonged period of time. Since chromium was accumulated in liver after administration of Cr(VI) we investigated the intracellular disposition of Cr(VI) in the isolated perfused liver. No significant sex differences in chromium distribution were observed. At the end of the experiments (1 h), 60% of the applied dose (312μg Cr/liver) was located in the cytosol, whilst 14% was in the mitochondria, 9% in the microsomal pellet and 2% was associated with the nuclei. Gel chromatography of the cytosolic compartment showed that the overwhelming part of chromium was eluted in fractions with an apparent molecular weight of 6,000 dalton. These fractions exhibited absorption maxima at 410nm and 548nm. It is concluded, that cytosolic reduction might be the main intracellular redox pathway for chromates. This view was confirmed by monitoring the reaction of Cr(VI) with GSH in vitro. GSH reduced Cr(VI) without further cofactors under formation of GSH‐chromium complexes, which possibly represent major intermediates in the metabolism of Cr(VI). 相似文献
100.
Uzma Maqbool Anwar-Ul-Haq M. Jamil Qureshi 《Journal of environmental science and health. Part. B》2013,48(3):224-230
In-house developed ELISA was standardized to monitor atrazine residues in different environmental samples. The standard curve was linear, indicating an increase in log concentration with decrease in absorbance (%B/B0 = 1.075–0.042 Log C; r = ?0.966). The middle of the test was at 75 ng/L and the lowest detection limit at 4 ng/L. ELISA significantly correlated with the high performance liquid chromatography (HPLC) (r = 0.990). Internal validation showed good accuracy and precision. Maximum atrazine residues were present in Jehlum River water/sediments and maize/sugarcane plant roots. Most of the food samples were found to be contaminated. ELISA required less clean-up steps than HPLC, but showed matrix effect in soil/colored extracts. 相似文献