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391.
当前土壤中污染物人体可给性的体外模拟测试方法主要依据西方人群的胃肠环境制定,为建立能够客观表征土壤中污染物在我国人群胃肠消化环境中的人体可给性测试方法,以铅(Pb)污染土样为对象,采用《中华人民共和国药典:一部》(简称“《药典》”)中记载的我国人群胃肠液组分配置模拟胃肠消化液,对采自广西壮族自治区、辽宁省和湖南省的13个土样中Pb的人体可给性进行研究.结果表明:供试土样中Pb在胃消化阶段的人体可给性平均值为51.9%(范围为0.4%~86.1%),显著高于其在肠消化阶段的人体可给性平均值0.6%(范围为0.002 5%~3.1%),与采用国际上常用的UBM(Unified Bioaccessibility Model)方法的测试结果无明显差异,表明我国《药典》中推荐的胃肠液组分能够用于开展土样中Pb的人体可给性测试.研究显示,模拟胃液的pH是影响土样中Pb在胃消化阶段人体可给性测试结果的关键因素,测试过程中pH宜维持在1.0左右,而且,可将《药典》推荐的模拟胃液组分进一步优化为HCl和去离子水,以降低测试成本;模拟肠液应严格按《药典》推荐的组分进行配置,测试体系的pH宜维持在8.0左右. 相似文献
392.
为摸清土壤氟异常对生态环境的影响,利用贵州省多目标区域地球化学调查(1:250 000)项目成果,对贵阳中心区土壤氟的地球化学特征进行了深入研究,并采用全氟指数法对土壤环境质量及其生态环境效应进行初步评价.结果表明:①贵阳中心区土壤氟含量较高,表层、深层土壤氟含量平均值分别为1 143、1 438 mg/kg,且空间分布变化较大;氟含量随土层深度的增加而升高. ②不同类型土壤中氟含量变化较大,其中紫色土中含量(1 306 mg/kg)最高,水稻土次之,石灰土、粗骨土、黄壤等差别较小,其含量范围在1 099~1 167 mg/kg之间. ③土壤氟含量与其母岩呈显著正相关性,且土壤中氟含量较母岩更高,表明风化成土过程中存在一定富集,土壤氟与成土母岩之间具有一定继承性. ④土壤氟环境质量评价结果表明,研究区土壤存在局部氟污染(异常),污染区、警戒区、安全区和清洁区所占比例分别为13.6%、62.2%、19.2%和5.0%. ⑤生态环境效应初步调查结果显示,局部土壤受氟污染区的油菜和稻谷样品中氟含量范围分别为1.86~2.68和10.40~13.50 mg/kg,同时地下水也受到一定程度的氟污染.因此,贵阳中心区土壤氟含量较高,局部土壤已受到氟污染,可能会对农产品质量、饮水安全及人体健康产生一定影响,建议政府部门及科研工作者予以高度重视. 相似文献
393.
This paper examinee the role of the medical delegate of the ICRC. Part I outlines the diseases and conditions found during a survey of three Nicaraguan rural prisoner of war camps. This information should enable medical delegates to formulate better plans for the treatment of prisoners in future. Part II suggests an alternative health care system which relies on the use of medical kits and manuals In the hands of medical auxiliaries. Dividing responsibility in this way would leave the medical delegate free to perform tasks which make more use of his more sophisticated skills. 相似文献
394.
通过对目前全世界元古宙———寒武纪地层中的浮游植物 (疑源类 )的统计 ,发现在新元古代晚期和早、中寒武世相对较短的时间间隔内发生了一系列的微体植物 (疑源类 )辐射和绝灭事件。而这些辐射和绝灭事件又与早期后生生物的辐射、绝灭都有密切的镜像关系。通过对古海洋的δ13 C、87Sr/ 86Sr研究 ,发现元古宙—寒武纪浮游植物 (疑源类 )的辐射演化、绝灭作用与古海洋环境变化有着密切的关系 ,即生物辐射时期 ,δ13 C、 87Sr/ 86Sr呈现高异常 ;生物绝灭时期 ,δ13 C、87Sr/ 86Sr呈现低异常 ;冰期δ13 C呈现明显的负异常。 相似文献
395.
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398.
James L. Robinson Celeste A. Journey 《Journal of the American Water Resources Association》2004,40(4):851-861
ABSTRACT: Ground water samples were collected from 30 wells located in, or directly down gradient from, recharge areas of the Eutaw aquifer in Montgomery, Alabama. The major ion content of the water evolves from calcium‐sodium‐chloride‐dominated type in the recharge area to calcium‐bicarbonate‐dominated type in the confined portion of the aquifer. Ground water in the recharge area was under saturated with respect to aluminosilicate and carbonate minerals. Ground water in the confined portion of the aquifer was at equilibrium levels for calcite and potassium feldspar. Dissolved oxygen and nitrite‐plus‐nitrate concentrations decreased as ground water age increased; pH, iron, and sulfate concentrations increased as ground water age increased. Aluminum, copper, and zinc concentrations decreased as ground water age and pH increased. These relations indicate that nitrate, aluminum, copper, and zinc are removed from solution as water moves from recharge areas to the confined areas of the Eutaw aquifer. The natural evolution of ground water quality, which typically increases the pH and decreases the dissolved oxygen content, may be an important limiting factor to the migration of nitrogen based compounds and metals. 相似文献
399.
Bain D. C. Tau Strand L. Gustafsson J. P. Melkerud P.-A. Fraser A. R. 《Water, Air, & Soil Pollution: Focus》2003,3(4):29-47
The chemistry, mineralogy and morphology of two soil profiles developed on till material of granitic and gneissic composition in south-western Sweden were studied in relation to podzolization processes. These soils were used for treatments with lime and wood ash. The profiles do not show characteristic Podzol morphology but qualify as Spodosols under Soil Taxonomy criteria and are probably typical for the coniferous forest soils of south-western Sweden. Podzolization features are clear but less well expressed than in classic Podzols. The distribution of major elements shows podzolization features with accumulation of sesquioxides in the B horizons and depletion in the eluvial horizons. Quartz and feldspars dominate the bulk soils reflecting the clear relationship between the composition of the soil and the underlying bedrock. Low amounts of clay contain an interlayered vermiculitic phase as the main phyllosilicate in which the degree of interlayering, known to be pH dependent, varies with depth and is at a maximum in the Bhs horizon. In the B horizons there are small but significant amounts of imogolite-type material which affect the adsorption of sulphate. 相似文献
400.
In poorly buffered areas acidification may occur for two reasons: through atmospheric deposition of acidifying substances and – in mining districts – through pyrite weathering. These different sources of acidity lead to distinct clearly geochemistry in lakes and rivers. In general, the geochemistry is the major determinant for the planktonic composition of the acidified water bodies, whereas the nutrient status mainly determines the level of biomass. A number of acidic mining lakes in Eastern Germany have to be neutralized to meet the water quality goals of the European Union Directives and to overcome the ecological degradation. This neutralization process is limnologically a short-term maturation of lakes, which permits biological succession to overcome two different geochemical buffer systems. First, the iron buffer system characterizes an initial state, when colonization starts: there is low organismic diversity and productivity, clear net heterotrophy in most cases. Organic carbon that serves as fuel for the food web derives mainly from allochthonous sources. In the second, less acidic state aluminum is the buffer. This state is found exceptionally among the hard water mining lakes, often as a result of deposition of acidifying substances onto soft water systems. Colonization in aluminum-buffered lakes is more complex and controlled by the sensitivity of the organisms towards both, protons and inorganic reactive aluminum species. In soft-water systems, calcium may act as antidote against acid and aluminum; however, this function is lost in hard water post mining lakes of similar proton concentrations. Nutrient limitations may occur, but these do not usually control qualitative and quantitative plankton composition. In these lakes, total pelagic biomass is controlled by the bioavailability of nutrients, particularly phosphorus. 相似文献