某生活垃圾卫生填埋场渗滤液的梯度分离与表征

目前,渗滤液中污染物的粒度分布及其在渗滤液污染控制中的作用日益受到关注。通过系列微滤膜(1.2μm及0.45μm)对某生活垃圾卫生填埋场渗滤液各处理单元的渗滤液进行梯度分离,发现悬浮物对COD、浊度的影响较大;COD主要在胶体态和可溶解态间分配,不同渗滤液中的分配情况不同;磷主要与胶体、悬浮物以各种形式结合而存在;细胶粒和溶解态等小分子对TN的贡献大;不同粒度物质对pH的影响不明显;总残渣在可溶态组分中所占比例较大。膜微滤处理渗滤液可以有效的去除一部分物质,使COD、TP、TN、浊度、电导率都有不同程度的降低,pH逐渐升高,但对总N、残渣的去除效果不好。     

碳源类型及进水量分配对CMICAO工艺脱氮除磷的影响

研究了分别以葡萄糖和乙酸钠为碳源时多点交替进水阶式A2/O(CMICAO)工艺氮磷的去除效果,以及在不同进水C/N比时各进水量分配对脱氮除磷效果的影响.结果表明,在相同的进水COD浓度下,乙酸钠比葡萄糖更适合作为碳源,更能提高脱氮除磷效率.以葡萄糖为碳源时,COD为200 mg/L、C/N比为5、缺氧池与厌氧池进水配比为1∶2时,出水COD、TN、氨氮和TP浓度分别为28.5、10.8、2.1和0.5 mg/L,均达到国家一级A排放标准.若采用葡萄糖作为碳源,投加量以使进水C/N比为5～7.5为宜,外加碳源时缺氧池与厌氧池进水分配比可统一采用1∶1.     

土壤镉处理对棉花镉吸收及分布规律的影响

用CdCl2将盆栽土壤Cd浓度处理为1mg／kg、5mg／kg、10mg／kg、20mg,／kg、30mg／kg种植棉花,研究棉花对镉的吸收及镉在棉花体内的分布规律。结果表明,当土壤镉浓度小于30mg／kg时,镉在棉花体内的分布呈现不同的规律。当土壤镉浓度小于5mg／kg时,镉主要分布在棉花的地上部;当土壤镉浓度大于20mg／kg时,镉主要分布在棉花的叶片、根、茎中,其中叶片的镉含量最高,棉絮镉含量最低。不同镉污染水平下,棉花的镉富集系数均小于1。当土壤镉污染浓度为5mg／kg时,棉花叶片的镉富集系数为0．76。在同一镉污染水平下,棉花叶片的镉转运系数最高。当土壤镉含量小于20mg／kg时,棉花茎、叶、棉絮的转运系数平均为4．63。     

Sexual difference in PCB congener distributions of burbot (Lota lota) from Lake Erie

Concentrations of 86 congeners of polychlorinated biphenyls (PCBs) were determined for 25 adult female and 25 adult male burbot (Lota lota) from Lake Erie. Significant differences in mean proportions of total PCB concentration between males and females ages 14–17 were found for 26 congeners. Males generally had higher mean proportions of hexachloro congeners, whereas females had higher mean proportions of more highly chlorinated congeners. In contrast, only four congeners exhibited differences between males and females ages 6–13 in mean proportions of total PCB. Therefore, the sexual difference in PCB congener distribution widened for older burbot. Males ages 14–17 also had higher proportions of certain hexachloro congeners than the other three demographic groups (males ages 6–13, females ages 6–13, and females ages 14–17) we examined. The reverse was true for more highly chlorinated congeners. The results supported a previous hypothesis that older male burbot spent a substantial amount of time feeding in the vicinity of mouths of rivers with sediment contaminated with PCBs. However, additional studies are needed to clarify and corroborate this apparent “hot spot” effect, such as seasonal movements, spatial distributions, and diet of burbot; and PCB congener distributions of various species of prey fishes captured at various locations throughout the eastern basin of Lake Erie and at different locations in the contaminated rivers.     

Hexabromocyclododecanes in limnic and marine organisms and terrestrial plants from Tianjin,China: Diastereomer- and enantiomer-specific profiles,biomagnification, and human exposure

To interpret the distribution of hexabromocyclododecanes (HBCDs) in various organisms, we measured the concentrations and diastereomer and enantiomer profiles of HBCDs in 21 different species of limnic and marine cohorts from Tianjin, China. The concentration ranges of HBCDs in limnic and marine organisms were 64.3–1111 ng g⁻¹ lw and 85.5–989 ng g⁻¹ lw, respectively. Living habitat and feeding habits had important impacts on HBCD diastereomer distribution. Most of the species appeared to preferentially select (+)-α-, (−)-β- and (−)-γ-HBCD. There is a tendency that the total and α-HBCDs were magnified as trophic level increased with trophic magnification factors (TMFs) around 2. The concentrations of HBCDs in the limnic and marine fishes were highest in the liver, followed by the gill, skin, and muscle. In terrestrial plants, the highest concentrations of HBCDs were observed in the leaf, followed by the root and the rhizosphere soil. Plants showed enantioselectivity for HBCD enantiomers, which varied with plant species and organs (leaf vs. root) of the same plant. Higher estimated daily intakes (EDIs) of HBCDs were observed from fish than from wheat.     

脱硫石膏粒径分布与脱水性能实验研究

脱硫石膏粒径分布是影响脱硫石膏浆液脱水性能的重要因素之一,以干法、湿法筛分和研磨破碎获得不同粒径分布的脱硫石膏,在相同的过滤条件下,对不同粒径分布脱硫石膏浆液脱水性能进行了研究,实验结果表明,当脱硫石膏粒径d50大于50μm且（d90-d10）小于100μm,真空过滤最大真空度不低于0．098MPa,过滤时间不少于2．5min,滤饼厚度不超过20mm时,石膏滤饼含水率可以降低到12％以下（最低可达10％）;d50在17μm为脱硫石膏在相同的过滤条件下能够实现真空脱水干燥的转折点;d50和（d90-d10）共同影响石膏脱水性能,d50小于20μm时,仅表现为d50的影响。     

成雅高速公路两侧大气颗粒物中重金属分布规律研究

本文以成雅高速公路为研究对象,采集公路两侧大气颗粒物样品,通过微波消解——火焰原子吸收法测定大气颗粒物中铅、镉、铜、锌的含量。研究表明,成雅公路两侧距路肩200m范围内大气颗粒物已受不同程度的铅、镉、铜、锌污染,其中重金属含量Pb〉Zn〉Cu〉Cd,并获得成雅高速公路两侧大气颗粒物中重金属污染的分布规律。     

城区天然气配气站噪声的产生及防治

城区天然气配气站噪声超标已成为供气部门亟待解决的难题,文章分析了配气站噪声污染现状,指出噪声产生原因主要为天然气流动,供气量增长使设备超负荷运行等7个方面。分别针对现有配气站和新建、改扩建站场提出降噪措施,指出设备在额定范围内运行、气体流速控制、工艺改造等是噪声控制的重要手段。并对城区天然气配气站噪声治理的进一步研究提出了建议。     

全工班呼吸性粉尘测定及防尘措施研究

针对呼吸性粉尘对矿井工人身体健康的危害,对煤矿综采工作面、综掘工作面、炮掘工作面等进行分工种个体性的全尘和呼尘监测,测定了各工作面粉尘(全尘和呼尘)的浓度、粉尘分散度和SiO2浓度。其结果表明:全工班呼吸性粉尘测定的方法更加真实可靠,更真实地反映了呼吸性粉尘对井下各操作工种的致病危害,测得的各工作面各工种的呼尘浓度均高于国家标准。通过数据的分析以及工人的建议,提出了一些新式的、有效的防尘措施来降低呼吸性粉尘对人体健康的危害。     

广东省杨村华侨柑桔场土壤微量元素含量与分布的研究

采集并分析全场不同母质形成的有代表性的土壤样本142个.研究结果表明,各类土壤全B、Mo、Zn和Mn含量的平均值均低于全国平均值,全量Cu平均值高于全国平均值.有效B、Mo、Zn和Mn含量的平均值均低于临界值,有效Cu的平均值稍高于临界值;但66.7％的土样有效Cu含量低于临界值.硼、钼、锌和锰严重缺乏,铜多数缺乏.全场各类土壤的微量元素含量差异较大,各类土壤微量元素的垂直和水平分布特征不尽相同,尤其是垂直分布差异明显.从土壤微量元素的全量与母质的关系来看,以玄武岩、紫色砂页岩母质形成的土壤全量较高,砂砾岩母质形成的土壤全量中等,砂页岩和冲积物母质形成的土壤全量较低.