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71.
72.
根据不同离子浓度、不同pH值的溶液中As在无定形氧化铝表面的吸附量,利用三种不同的表面络合模型计算As与无定形氧化铝表面络合反应的平衡常数,将计算得到的平衡常数模拟 As(Ⅲ)无定形在氧化铝表面各个络合物种的吸附百分比与 As(Ⅲ)的 X光吸收光谱边缘结构分析结果进行定性比较,表明计算结果与分析结果较为吻合.从而验证了此次计算得到的平衡常数是准确的. 相似文献
73.
采用响应面分析法对聚合氯化铝(PAC)与污泥生产的微生物絮凝剂复配处理涂料废水的过程进行了优化,设定的响应值为COD和色度去除率。实验分别拟合了关于COD去除率和色度去除率的二次模型,根据响应值的分布情况,确定涂料废水的最佳絮凝条件为微生物絮凝剂浓度47 mg/L,PAC浓度39 mg/L,pH为8.2,CaCl2浓度0.38 g/L,搅拌速度210 r/min。最佳絮凝条件下,微生物絮凝剂对涂料废水中COD和色度的去除率分别达到77.6%和68.9%。 相似文献
74.
75.
响应曲面法优化絮凝处理木薯淀粉废水 总被引:4,自引:1,他引:4
采用中心复合实验设计和响应面分析法研究复合絮凝剂聚合氯化铝锌(PAZC)和聚合氯化铝(PAC)混凝处理木薯淀粉废水,进行设计和分析,以溶液pH值和絮凝剂用量为考察因素,分别以COD、浊度去除率为考察指标,选用最佳优化数学模型描述考察指标和考察因素之间的数学关系,并以设定PAZC和PAC对COD去除率(65%),浊度去除率(90%)和SS去除率(90%)的目标值,通过等高线叠加图预测最优实验条件,得到PAZC投量为6.5 mg/L,pH为7.7时,COD去除率和浊度去除率分别达到最大为76.6%和99.9%;PAC投量为19.2 mg/L,pH为7.8时,COD去除率和浊度去除率最大值分别为64.4%和97.1%。经对最优条件进行验证,预测值与验证实验平均值接近。 相似文献
76.
Li R. Gao Dan. Xia Hai Z. Tian Hai J. Zhang Li D. Liu Yi W. Wang 《Journal of environmental science and health. Part. B》2013,48(5):322-330
Organochlorine pesticides (OCPs) were analyzed in 26 surface sediment samples from the Liaohe River basin, and the distributions of and potential environmental risks posed by OCPs in the basin were evaluated. Eighteen OCPs listed in the Stockholm Convention were determined using isotope-dilution gas chromatography–high resolution mass spectrometry. This is the first study of hexachlorobenzene (HCB) in the Liaohe River basin sediments. The total OCP concentrations were 0.39–68.06 ng g?1 dry weight. The total α-, β-, γ-, and δ-hexachlorocyclohexane (HCH), the total dichlorodiphenyltrichloroethane (DDT – p,p′-dichlorodiphenyldichloroethane (DDD), p,p′-dichlorodiphenyldichloroethylene (DDE), o,p'-DDT, and p,p′-DDT), and the HCB concentrations in the sediment samples were 0.1–28.48 ng g?1 (mean 4.01 ng g?1), 0.08–6.52 ng g?1 (mean 3.07 ng g?1), and 0.18–24.8 ng g?1 (mean 4.38 ng g?1), respectively. The HCB concentrations were higher than the concentrations of the other OCPs, and the HCHs and HCB together were the dominant OCPs. β-HCH was the most abundant HCH isomer. The concentrations of DDTs and other OCPs were relatively low, and the (DDE+DDD)/DDT ratios (>0.5) and DDD/DDE ratios (<1) indicated that no recent DDT inputs had occurred in the Liaohe River system. The main sources of HCHs were probably the historical production and agricultural use of HCH in the study area. The DDT and HCH concentrations were generally below or similar to the concentrations that have been found in other parts of the world. An ecotoxicological evaluation indicated that HCHs in surface sediments pose slight risks to human and ecological health in the Liaohe River basin. 相似文献
77.
Kostanjsek R Lapanje A Drobne D Perović S Perović A Zidar P Strus J Hollert H Karaman G 《Environmental science and pollution research international》2005,12(6):361-368
- Goal, Scope, Background. Lake Skadar is the largest lake in Balkan Peninsula, located on the Montenegro-Albanian border. The
unique features of the lake and wide range of endemic and rare or endangered plant and animal species resulted in the classification
of the Skadar as a wetland site of international significance. In spite of its importance the Lake is influenced by inflowing
waters from river Morača and other regional rivers contaminated by the industry, municipal and agricultural activities in
the area. Therefore, the Lake has been subject of various physical, chemical, biological and toxicological examinations. However,
community-level analyses are most relevant to assess the effect of stressors on aquatic ecosystems. In the present study bacterial
community structure among differently polluted sites of the lake was compared by genetic fingerprinting technique.
Methods Water and sediment samples were collected from five differently polluted sampling sites on the Lake Skadar in spring and
autumn of the same year. The bacterial community structure in the samples was characterized and compared by temporal temperature
gel electrophoresis (TTGE) analysis of polymerase chain reaction-amplified bacterial 16S rRNA genes.
Results and Discussion The TTGE analysis resulted in many distinguishable and reproducible band patterns, allowing reliable comparison of bacterial
communities among sampling sites. Results on the bacterial community structure revealed that three of the selected locations
can be considered as sites that have not shown any pollution degradation determined by our method, due to similar structure
of bacterial community in the sediment samples. On the other hand, significant shifts in bacterial community structure in
the mouth of the river Morača and Plavnica were shown. Since the results coincide with some of the bioassays and chemical
analysis performed previously, the changes in bacterial community structure are explained as an effect of antropogenic pollution
on the lake ecosystem by waters of river Morača and stream Plavnica.
Conclusion The TTGE has proven to be an efficient and reliable method to monitor bacterial dynamics and community shifts in aquatic
environment, especially in the sediments. Within the variety of environmental quality assessments the use of TTGE analyses
of bacterial community is strongly recommended, particularly as an initial investigation. However, in any conclusion on the
state of the environment, the TTGE results should be combined to some other biological, chemical and hydrological data.
Recommendation and Outlook Since prokaryotes are a crucial group of organisms in the biosphere, the ecosystem function studies are largely based on
bacterial communities. Therefore, bacterial community structure analysis should be a part of an integrated weight of evidence
approach in pollution assessment. In case of Triad approach, consisting of chemical analyses, bioassays, and community studies
in the field, the TTGE bacterial community structure analyses should be placed in the later Triad leg. In comparison to other
community studies, based on various biotic indices, the TTGE bacterial community analysis has proven to be very sensitive,
reliable and less time consuming. 相似文献
78.
79.
Mannino I Franco D Piccioni E Favero L Mattiuzzo E Zanetto G 《Environmental management》2008,41(1):118-129
A cost-effectiveness analysis was performed to evaluate the competitiveness of seminatural Free Water Surface (FWS) wetlands
compared to traditional wastewater-treatment plants. Six scenarios of the service costs of three FWS wetlands and three different
wastewater-treatment plants based on active sludge processes were compared. The six scenarios were all equally effective in
their wastewater-treatment capacity. The service costs were estimated using real accounting data from an experimental wetland
and by means of a market survey. Some assumptions had to be made to perform the analysis. A reference wastewater situation
was established to solve the problem of the different levels of dilution that characterize the inflow water of the different
systems; the land purchase cost was excluded from the analysis, considering the use of public land as shared social services,
and an equal life span for both seminatural and traditional wastewater-treatment plants was set. The results suggest that
seminatural systems are competitive with traditional biotechnological systems, with an average service cost improvement of
2.1-fold to 8-fold, according to the specific solution and discount rate. The main improvement factor was the lower maintenance
cost of the seminatural systems, due to the self-regulating, low artificial energy inputs and the absence of waste to be disposed.
In this work, only the waste-treatment capacity of wetlands was considered as a parameter for the economic competitiveness
analysis. Other goods/services and environmental benefits provided by FWS wetlands were not considered.
相似文献
Daniel FrancoEmail: |
80.
Various aquatic plant species are known to accumulate heavy metals through the process of bioaccumulation. World’s most troublesome
aquatic weed water hyacinth (Eichhornia crassipes) has been studied for its tendency to bio-accumulate and bio-magnify the heavy metal contaminants present in water bodies.
The chemical investigation of plant parts has shown that it accumulates heavy metals like lead (Pb), chromium (Cr), zinc (Zn),
manganese (Mn) and copper (Cu) to a large extent. Of all the heavy metals studied Pb, Zn and Mn tend to show greater affinity
towards bioaccumulation. The higher concentration of metal in the aquatic weed signifies the biomagnification that lead to
filtration of metallic ions from polluted water. The concept that E. crassipes can be used as a natural aquatic treatment system in the uptake of heavy metals is explored. 相似文献