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671.
利用联醇装置废催化剂生产氯化亚铜和氧化锌 总被引:4,自引:0,他引:4
叙述了用化肥厂联产甲醇装置的废催化剂生产氯化亚铜和氧化锌的原理、工艺流程和工艺条件,氯化亚铜和氧化锌的收率分别达到95%和92%. 相似文献
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用氧化镁为原料进行烟气脱硫并回收硫酸,脱硫效率达97%,仅补充8%的氧化镁,其余的镁循环使用,脱下的硫制成硫酸产品。介绍了技术原理、工艺说明、设备及工艺参数、技术特点等,对回收硫酸和氧化镁循环使用等综合利用技术经济进行了分析。该方法充分利用氧化镁的资源优势,具有技术成熟、流程短、脱硫效率高、运行费用低、无二次污染、脱硫剂消耗少等优点,经济效益显著,有较好的推广利用前景。 相似文献
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氧化锌法处理低浓度SO_2烟气的模拟实验研究 总被引:3,自引:0,他引:3
文中介绍了氧化锌法脱硫的基本原理,总结了国内外研究及应用现状,同时详细叙述了模拟实验采用的流程、主要仪器,着重分析了不同SO2浓度下的吸收率以及亚硫酸锌的氧化率与氧化时间、浆液温度的关系,提出了实验过程中发现的问题及可采取的措施,为后期中试以及工业化应用提供了设计依据。 相似文献
678.
采用酸浸法处理高硅铁尾矿,制备工业原料Fe2O3和SiO2微粉.最佳工艺条件为:反应温度100℃,反应时间90 min,铁尾矿中位粒径6.19 μm,盐酸体积分数60%.在上述最佳条件下,制备的SiO2产率(所得产品中SiO2的质量占原铁尾矿中SiO2质量的比例,下同)达98.2%,品质达到YB/T 115-2004《... 相似文献
679.
A comparison of CaOs produced by calcining two types of hydrated lime and calcium carbonate was made for decomposition of trichloroethylene and in-situ dry sorption of the decomposed Cl-products using a lab-scale gas flow type tubular packed bed reactor. About 20 mg of CaO sample was mixed with about 2 g of Al2O3 particles and packed in the reactor and allowed to react with a flowing standard gas containing 500 ppm of C2HCl3 (N2 balance) at 673 and 873 K, under the condition that the reaction of CaO with C2HCl3 might be completed within a few hours.It was found that no thermal decomposition of C2HCl3 at or below 673 K was observed in a reactor packed only with Al2O3 particles. However, a considerable amount of decomposition of C2HCl3 was obtained in a reactor packed with CaO and Al2O3, even at 673 K. For 1 mol of CaO prepared by calcining highly reactive Ca(OH)2 at 673 K, decomposition of 0.42 mol of C2HCl3 and in-situ absorption product of 0.53 mol of CaCl2 were obtained. At 873 K, about 46% of C2HCl3 was thermally decomposed. The total amount of C2HCl3 decomposed in CaO-Al2O3 particle bed at 873 K became nearly twice larger than that at 673 K. For 1 mol of CaO prepared by calcining highly reactive Ca(OH)2 at 873 K, decomposition of 0.59 mol of C2HCl3 and in-situ absorption product of 0.67 mol of CaCl2 were obtained. Small amounts of C2Cl2, C2Cl4, CCl4, etc. were detected during decomposition of C2HCl3 at 673 and 873 K.It was recognized that the data on decomposition of C2HCl3 as well as in-situ dry sorption of Cl-products in CaO particle bed were correlated with specific surface area of the CaO employed. 相似文献
680.
Pleijel H 《Environmental pollution (Barking, Essex : 1987)》2011,159(4):897-902
This study considered effects of reduced [O3] on wheat yield. Open-top chamber charcoal filtered air treatments were compared with non-filtered treatments for field-grown wheat. 30 experiments meeting requirements were found, representing nine countries in North America, Europe and Asia. 26 experiments reported improved yield and 4 experiments reduced yield by filtration, a significant positive effect. Average yield improvement was 9%. Average daytime [O3] was reduced by filtration from 35 to 13 nmol mol−1. Filtration efficiency was 63% for O3 and 56% for SO2. For NOx it was observed that NO2 was reduced and NO increased by filtration. Thus, filters convert NO2 to NO. Most experiments reported low or very low [SO2] and [NOx]. Thus, O3 can be concluded to be the main phytotoxic component in the experiments. Elevated [NO2] was observed in one experiment. The conclusion is that current [O3] over large parts of the world adversely affect wheat yield. 相似文献