酸阻滞法处理含酸及其相应盐的废液

本文主要介绍在含酸及其相应盐的废液中分离酸和盐的一种方法。将含酸及其相应盐的废液，通过装有强碱性阴离子交换树脂柱，其中的酸受到阻滞，而相应的盐能顺利通过，然后用水洗脱，则流出的是含酸的溶液，使酸和相应的盐得到了分离。经ＦｅＳＯ４－Ｈ２ＳＯ４和ＺｎＳＯ４－Ｈ２ＳＯ４两组废液的试验，均能使酸和金属得到回收。分离后的废水，可达标排放，废液得到了处理。酸阻滞法简单易行，易于投产使用，不受规模大小的限制。     

长江上游典型区域丰枯转换期水资源变化分析

针对长江上游金沙江下游区域近几年6月和10月出现的较剧烈的水资源丰枯转换现象,以2018年金沙江下游来水过程作为研究案例,考虑金沙江下游流域来水组成及水利工程建设情况,从区间流量分析及上游水库群调蓄影响分析两方面开展了研究工作。研究结果表明:金沙江下游流域丰枯转换主要影响因素为三堆子流量变化,三堆子至溪洛渡区间流量变化影响较小。在6月,上游水库群调蓄对金沙江下游流域丰枯转换影响较大,10月影响相对较小。相关研究成果可为溪洛渡-向家坝梯级水库调度计划制订及实际调度工作提供参考。     

Clustering of aerosols in atmospheric turbulent flow

A mechanism of formation of small-scale inhomogeneities in spatial distributions of aerosols and droplets associated with clustering instability in the atmospheric turbulent flow is discussed. The particle clustering is a consequence of a spontaneous breakdown of their homogeneous space distribution due to the clustering instability, and is caused by a combined effect of the particle inertia and a finite correlation time of the turbulent velocity field. In this paper a theoretical approach proposed in Elperin et al. (2002) Phys Rev E 66:036302 is further developed and applied to investigate the mechanisms of formation of small-scale aerosol inhomogeneities in the atmospheric turbulent flow. The theory of the particle clustering instability is extended to the case when the particle Stokes time is larger than the Kolmogorov time scale, but is much smaller than the correlation time at the integral scale of turbulence. We determined the criterion of the clustering instability for the Stokes number larger than 1. We discussed applications of the analyzed effects to the dynamics of aerosols and droplets in the atmospheric turbulent flow.     

NONLINEAR MODELING AND PREDICTION OF A RIVER FLOW SYSTEM1

ABSTRACT: Model estimation and prediction of a river flow system are investigated using nonlinear system identification techniques. We demonstrate how the dynamics of the system, rainfall, and river flow can be modeled using NARMAX (Nonlinear Autoregressive Moving Average with eXogenuous input) models. The parameters of the model are estimated using an orthogonal least squares algorithm with intelligent structure detection. The identification of the nonlinear model is described to represent the relationship between local rainfall and river flow at Enoree station (inputs) and river flow at Whitmire (output) for a river flow system in South Carolina.     

RUNOFF RESPONSE FROM TWO RECLAIMED WATERSHEDS1

ABSTRACT: Detailed studies of the surface hydrology of reclaimed surface-mined watersheds for both rainfall and snowmelt events are non-existent for central Alberta yet this information is crucial for design of runoff conveyance and storage structures. A study was initiated in 1992 with principal objectives of quantifying surface runoff for both summer rainfall and spring snowmelt events and identifying the dominant flow processes occurring in two reclaimed watersheds. Snowmelt accounted for 86 and 100% of annual watershed runoff in 1993 and 1994, respectively. The highest instantaneous peak flow was recorded during a summer rainfall event with a return period of greater than 50 years. Infiltration-excess overland flow was identified as the dominant flow process occurring within the Sandy Subsoil Watershed, whereas saturation overland flow was the principal runoff process occurring within the West Watershed.     

ESTIMATING THE Q100 IN BRITISH COLUMBIA: A PRACTICAL PROBLEM IN FOREST HYDROLOGY1

ABSTRACT. Estimates of peak flows, with specified return periods, are needed in practice for the design of works that affect streams in forested areas. In the province of British Columbia (B.C.), Canada, the new Forest Practices Code specifies the 100-year instantaneous peak flow (Q100) for the design of bridges and culverts for stream crossings under forest roads; and many practitioners are engaged in making such estimates. The state of the art is still quite primitive, very similar to the state of urban hydrology 30 years ago, when popular estimating techniques were used with little consideration given to their applicability. Urban hydrology then evolved on a much more scientific basis, such that within about a 10-year period, standard approaches to design were developed. Forest hydrology should follow the same pattern, at least as far as estimating design flows is concerned. Popular present day design procedures include the rational method and other empirical approaches based on rainfall data, as use of the standard flood frequency approach is limited by the paucity of relevant flow data. Estimating procedures based on peak streamflow measurements and statistics are likely to evolve, and these will include distinctions for rain, snowmelt, and rain on snow floods. Guidelines will also be developed for selecting and applying appropriate procedures for particular areas.     

世界煤炭资源流动的时空格局及成因分析

基于1990-2016年的统计数据,采用场理论研究世界煤炭资源流动的时空格局变化及其成因,揭示近30年来世界煤炭资源的流动状态及其演变过程。研究结果显示：（1）2016年世界煤炭的输出总量达12.25亿t,比1990年增加了10.13亿t,年均增长6.98%,其中澳大利亚、印尼和俄罗斯等是主要的煤炭输出国,印度、日本、中国和韩国是主要的煤炭输入国;（2）以场理论的位势、流场分布、流动迹线角度分析,世界煤炭资源的流动以北美洲、中南美洲和非洲为源流场,以欧洲及欧亚大陆、中东和亚太为汇流场,在澳大利亚—东亚、印尼—东亚/印度之间形成主要运输航线;（3）资源空间分布、供需匹配程度、空间距离、市场因素和国家政策等是煤炭资源流动的主要动因。研究发现：虽然中国煤炭储量丰富,但是煤炭消费数量庞大,仅可维持72年,必须重视煤炭的进口和储备工作。该研究对于中国科学制定产业政策具有重要价值。     

高流速海水中舰艇常用材料腐蚀实验研究

介绍了舰艇常用材料在海水环境动态高流速条件下自然电位、自然腐蚀率、电偶腐蚀等多方面的腐蚀实验方法及实验结果,得出了舰艇常用系列材料在动态海水中的腐蚀基本数据以及变化规律,为在舰船设计中材料的选择及腐蚀防护方案的制定提供参考。     

Effects of degree of water saturation on dispersivity and immobile water in sandy soil columns

Three natural nonaggregated soil samples, with similar grain-size distributions, have been used to determine the dispersive behavior of porous media under steady, saturated and unsaturated flow conditions. Tritium was used as a tracer and was found to have no sorption on the solid matrix. Generated breakthrough curves (BTCs) for the unsaturated experiments were symmetrical with no evidence of tailing. The unsaturated experiments for two of the soils were adequately described by considering all the water in the pore volume as mobile. However, about 10% of the pore water, independent of the degree of saturation, was found to be immobile in the case of the third soil during unsaturated flow. For this soil, there was no mass transfer between the two water regions, indicating that the immobile water is essentially isolated from the flowing water fraction. For all three soils, dispersivity under unsaturated conditions was found to be higher, independent of the degree of water saturation, than the value determined for the saturated experiments. This is inconsistent with what would be expected from the simple bundle-of-capillary-tubes model and does not agree well with a more sophisticated conceptualization of the porous medium. The data, however, clearly indicate a wider range in pore-water velocities when these soils are desaturated.     

Influence of hydrogeochemical processes on zero-valent iron reactive barrier performance: a field investigation

Geochemical and mineralogical changes were evaluated at a field Fe0-PRB at the Oak Ridge Y-12 site concerning operation performance during the treatment of U in high NO3- groundwater. In the 5-year study period, the Fe0 remained reactive as shown in pore-water monitoring data, where increases in pH and the removal of certain ionic species persisted. However, coring revealed varying degrees of cementation. After 3.8-year treatment, porosity reduction of up to 41.7% was obtained from mineralogical analysis on core samples collected at the upgradient gravel-Fe0 interface. Elsewhere, Fe0 filings were loose with some cementation. Fe0 corrosion and pore volume reduction at this site are more severe due to the presence of NO3- at a high level. Tracer tests indicate that hydraulic performance deteriorated: the flow distribution was heterogeneous and under the influence of interfacial cementation a large portion of water was diverted around the Fe0 and transported outside the PRB. Based on the equilibrium reductions of NO3- and SO4(2-) by Fe0 and mineral precipitation, geochemical modeling predicted a maximum of 49% porosity loss for 5 years of operation. Additionally, modeling showed a spatial distribution of mineral precipitate volumes, with the maximum advancing from the interface toward downgradient with time. This study suggests that water quality monitoring, coupled with hydraulic monitoring and geochemical modeling, can provide a low-cost method for assessing PRB performance.