全文获取类型
收费全文 | 716篇 |
免费 | 58篇 |
国内免费 | 267篇 |
专业分类
安全科学 | 29篇 |
废物处理 | 31篇 |
环保管理 | 43篇 |
综合类 | 393篇 |
基础理论 | 257篇 |
污染及防治 | 205篇 |
评价与监测 | 70篇 |
社会与环境 | 12篇 |
灾害及防治 | 1篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 7篇 |
2021年 | 5篇 |
2020年 | 18篇 |
2019年 | 19篇 |
2018年 | 25篇 |
2017年 | 30篇 |
2016年 | 41篇 |
2015年 | 20篇 |
2014年 | 45篇 |
2013年 | 174篇 |
2012年 | 57篇 |
2011年 | 54篇 |
2010年 | 52篇 |
2009年 | 40篇 |
2008年 | 40篇 |
2007年 | 49篇 |
2006年 | 56篇 |
2005年 | 48篇 |
2004年 | 33篇 |
2003年 | 36篇 |
2002年 | 20篇 |
2001年 | 15篇 |
2000年 | 23篇 |
1999年 | 17篇 |
1998年 | 18篇 |
1997年 | 11篇 |
1996年 | 21篇 |
1995年 | 21篇 |
1994年 | 11篇 |
1993年 | 10篇 |
1992年 | 3篇 |
1991年 | 5篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1988年 | 1篇 |
1987年 | 4篇 |
1986年 | 3篇 |
1982年 | 1篇 |
排序方式: 共有1041条查询结果,搜索用时 15 毫秒
61.
以表面活性剂TritonX-100(TX-100)为洗脱剂,某有机氯农药(organochlorinepesticides,OCPs)污染场地土壤为对象,七氯、氯丹和灭蚁灵为目标污染物,研究微米Cu/Fe双金属对污染土壤洗脱液中OCPs的降解效果。考察了洗脱液中OCPs初始浓度、洗脱液pH值、微米零价铁加入量和cu负载量对Cu/Fe去除OCPs效果的影响。结果表明,微米Cu/Fe可以有效的去除土壤洗脱液中目标污染物。当微米零价铁加入量为1.0g(25g/L),cu负载量为1.0%,洗脱液pH值为6.89时,Cu/Fe对2号土壤洗脱液中七氯、γ-氯丹、α-氯丹和灭蚁灵的去除效果最好,去除率分别为100.0%、99.3%、80.8%和71.1%。洗脱液中OCPs初始浓度越低,微米零价铁加入量越大,Cu/Fe对OCPs去除率越高;偏酸性条件有利于Cu/Fe对γ-氯丹和灭蚁灵的去除,而α-氯丹在中性条件下去除效果最好;1号土壤和2号土壤洗脱液的最佳铜负载量分别为2.O%和1.0%。 相似文献
62.
63.
Chien-jung Tien Colin S. Chen 《Journal of environmental science and health. Part. B》2013,48(9):901-912
This study aimed to determine the toxicity of three organophosphorous pesticides, chlorpyrifos, terbufos and methamidophos, to three indigenous algal species isolated from local rivers and algal mixtures. The diatom Nitzschia sp. (0.30–1.68 mg L?1 of EC50 -the estimated concentration related to a 50% growth reduction) and the cyanobacteria Oscillatoria sp. (EC50 of 0.33–7.99 mg L?1) were sensitive to single pesticide treatment and the chlorophyta Chlorella sp. was the most tolerant (EC50 of 1.29–41.16 mg L?1). In treatment with the mixture of three pesticides, Chlorella sp. became the most sensitive alga. The antagonistic joint toxic effects on three indigenous algae and algal mixtures were found for most of the two pesticide mixtures. The results suggested that mixture of pesticides might induce the detoxification mechanisms more easily than the single pesticide. The synergistic interactions between terbufos and methamidophos to algal mixtures and between methamidophos and chlorpyrifos to Nitzschia sp. indicated methamidophos might act as a potential synergist. Differential sensitivity of three families of algae to these pesticides might result in changes in the algal community structures after river water has been contaminated with different pesticides, posing great ecological risk on the structure and functioning of the aquatic ecosystem. 相似文献
64.
Abstract The pH‐disappearance rate profiles were determined at ca. 25°C for 24 insecticides at 4 or 5 pH values over the range 4.5 to 8.0 in sterile phosphate buffers prepared in water‐ethanol (99: 1 v/v). Half‐lives measured at pH 8 were generally smaller than at lower pH values. Changes in half lives between pH 8.0 and 4.5 were largest (>1000x) for the aryl carbamates, carbofuran and carbaryl, the oxime carbamate, oxamyl, and the organophosphorus insecticide, trichlorfon. In contrast, half lives of phorate, terbufos, heptachlor, fensulfothion and aldicarb were affected only slightly by pH changes. Under the experimental conditions described half lives at pH8 varied from 1–2 days for trichlorfon and oxamyl to >1 year for fensulfothion and cyper‐methrin. Insecticide persistence on alumina (acid, neutral and basic), mineral soils amended with aluminum sulfate or calcium hydroxide to different pH values and four natural soils of different pH was examined. No correlation was observed between the measured pH of these solids and the rate of disappearance of selected insecticides applied to them. These observations demonstrate the difficulty of extrapolating the pH dependent disappearance behaviour observed in homogeneous solution to partially solid heterogeneous systems such as soil. 相似文献
65.
Marcela Rodrigues De Camargo Luís Fernando Barbisan Meire França Martinez Carla Adriene Da Silva Franchi João Lauro Viana De Camargo Ana Lúcia Tozzi Spinardi-Barbisan 《Journal of environmental science and health. Part. B》2013,48(7):607-613
The noxious effects of low or effective dose exposure to single or mixed pesticides on macrophage activity and the lymphohematopoietic organs were investigated. Male Wistar rats were orally exposed to dichlorvos, dicofol, endosulfan, dieldrin and permethrin, either as single or combined mixtures during a 28-day study containing eight groups: one group received a semipurified diet (non-treated); two groups received a semipurified diet containing low dose mixture (dieldrin 0.025 mg/kg, endosulfan, 0.6 mg/kg, dicofol 0.22 mg/kg, dichlorvos 0.23 mg/kg, permethrin 5 mg/kg) or an effective dose mixture (dichlorvos 2.3 mg/kg, dicofol 2.5 mg/kg, endosulfan 2.9 mg/kg, dieldrin 0.05 mg/kg and permethrin 25.0 mg/kg), respectively; the other five groups received a semipurified diet containing each single pesticide in effective doses. At sacrifice, the thymus, spleen, mesenteric lymph nodes, Payer's patches and bone marrow were removed for histological analysis. Peritoneal macrophages were obtained to determine the phagocytosis and spreading indexes and tumoral necrosis factor alpha (TNF-α), nitric oxide (NO) and H2O2 production. Exposure to pesticide mixtures did not alter the percentage of macrophage phagocytosis and spreading, TNF-α production or the NO and H2O2 release when compared to the non-treated group. Neither was there any apparent evidence that a pesticide mixture at low or effective doses altered the histological structure of the lymphohematopoietic organs. The findings indicate that short-term treatment with pesticide mixtures did not induce an apparent immunotoxic effect in male Wistar rats. 相似文献
66.
Skiff Lobaugh Frank Farrow Xiuhong Feng Andrew Ogram 《Journal of environmental science and health. Part. B》2013,48(3):459-471
Abstract The effects of the herbicide triclopyr (3,5,6‐trichloro‐2‐pyridinyloxyacetic acid) on the mineralization of 2,4‐D (2,4‐dichlorophenoyxacetic acid) in two soils which differed in their histories of prior exposure to the two herbicides were investigated. The relative effects of triclopyr on 2,4‐D mineralization and most probable numbers of 2,4‐D degraders were dependent upon the soil. Triclopyr was shown to increase 2,4‐D mineralization rates in a soil which had been exposed to both 2,4‐D and triclopyr, but decreased the mineralization rate of 2,4‐D and inhibited the increase of most probable numbers of 2,4‐D degraders in a soil that had not been directly exposed to either herbicide. 相似文献
67.
甲胺磷农药废水生化处理高效菌选育的研究 总被引:23,自引:1,他引:23
从用甲胺磷农药废水长期驯化的活污泥中,筛选得到两株降解甲胺磷农药废水中有机磷的高效菌,经鉴定一株为蜡样芽孢杆菌(Bacilluscereus)。另一株为嗜中温假单胞菌(Pseudomonasmesophilica)。确定了上述高效菌的最适生长条件和降解有机磷的能力,混合高效菌的有机磷去除率达99.7%。 相似文献
68.
69.
70.