基于被动采样技术的水体中有机锡污染筛查取证研究

将三油酸甘油酯-醋酸纤维素复合膜(TECAM)用作被动采样器,开展水体中一甲基锡(MMT)、二甲基锡(DMT)、一丁基锡(MBT)、二丁基锡(DBT)、三丁基锡(TBT)、二苯基锡(DPhT)和三苯基锡(TPhT)等7种有机锡氯化物的富集实验,膜样品经甲醇/醋酸溶液提取、乙基化衍生和正己烷萃取等前处理后,用气相色谱-质谱法(GC-MS)进行定性和定量检测,得到水体中痕量有机锡污染的相关指纹信息。结果表明,7种目标化合物均可在TECAM膜上富集,48 h后均可达到平衡状态;有机锡富集能力差异较大,其TECAM膜/水分配系数(log KTECAM)与其辛醇-水分配系数(log Kow)呈现显著正相关性(r=0.97, n=7)。甲基锡富集能力较低,但可定性筛查;而苯基锡和丁基锡等5种目标化合物在TECAM膜上的被动采样速率在0.06～0.16 L·g~(-1)·d~(-1)范围变化,经反演所得其在水体中的时间加权平均浓度与传统的主动采样法所得浓度没有显著差异(P0.05)。因此,基于TECAM被动采样技术可以实现水体中极性范围较广的痕量有机锡污染筛查取证。     

On the random placement hypothesis

A traditional method of summarizing spatial distribution of species is the observed species-area curve. Often the observed species-area curve is surprisingly close to the expected species-area curve under the hypothesis of random placement of individuals. This has been used as evidence supporting the hypothesis. In this paper, we argue that using the observed species-area curve to test the general random placement hypothesis is highly inefficient. We present a testing method based on the classical ² test for over-dispersion which is not only more efficient but also applicable to situations where complete abundance information are unavailable. We also discuss three alternatives of the hypothesis. The focus of this paper is on these and other general issues relevant to communities of different types. No applications are included in this paper.     

硫化氢气体快速检测方法研究

研究了快速监测硫化氢气体的新方法——硫化氢被动式检气管方法。该法是基于气体分子扩散(Fick)定律和化学吸收原理,将检气管内的海棉载体涂渍上对硫化氢有特效的显色剂(缓冲液G和醋酸铅)。测定时,硫化氢通过检气管端口扩散进入管内,在经过载体时,与载体上的显色剂发生反应,从而产生明显的颜色变化(浅黄色变成棕黑色)。检气管显色长度的平方与硫化氢质量浓度及采样时间的乘积在50~1500mg·m-3范围内成线性关系,从而快速监测环境中硫化氢的时间加权平均质量浓度。该检气管集采样与分析为一体,可快速测定硫化氢气体的质量浓度。与传统的采样分析方法比较,该检气管结构简单,操作方便,不受被测环境的空间大小、有无电源等影响;携带方便,利于外出测定和大面积布点测定。经过应用实验表明,该检气管具有较高的灵敏度,达到设计要求。     

被动采样法测定环境空气中的二氧化氮

用被动采样方法吸收空气中的ＮＯ２，经实验室和野外实验证明，该方法测得的ＮＯ２浓度对渗透管发生的ＮＯ２浓度的相关系数为０．９９９５。用七个相同的采样器在相同时间、相同地点测得的ＮＯ２浓度的相对标准偏差为３．６％。当ＮＯ２浓度为５０μｇ／ｍ＾３左右时，采样周期可长达一个月。该方法可用于大气环境中１０μｇ／ｍ＾３ＮＯ２日平均浓度的测定。     

被动吸烟对儿童呼吸健康的影响

指导了１９９３～１９９６年兰州、重庆、武汉和广州４个城市８所小学进行家庭被动吸烟调查结果。结果表明，在７～１２岁儿童７９７７人中，受被动吸烟暴露的儿童６３４２人占调查总人数的７９．５％；受被动吸烟暴露儿童吸附系统的１０种疾病和症状发生率明显高于不受暴露影响的儿童，其中有８种病症的比数比（ＯＲ）范围在１．２７～１．６７，住院率的ＯＲ值为１．２８；受被动吸烟暴露儿童呼吸系统病症发生率也随家庭成员每天吸     

Rating the Aggressivity of Australian Passenger Vehicles Towards Other Vehicle Occupants and Unprotected Road Users

Two measures of aggressivity of Australian passenger vehicles have been developed. The first measures the aggressivity to occupants of other cars. This type of aggressivity rating is based on two-car crashes between passenger vehicles and measures the injury risk each make/model in the collisions poses to the drivers of the other vehicles. The second measures aggressivity to unprotected road users. These aggressivity ratings reflect the threat of severe injury to pedestrians, bicyclists and motorcyclists by die make/model of vehicle colliding with them. This analysis was based on nearly 102,000 drivers involved in tow-away crashes with the makes/models which were the focus of the study and on nearly 22,000 injured pedestrians, bicyclists, and motorcyclists. The results suggest that crasbworthiness and aggressivity are two different aspects of a vehicle's safety performance, with good performance on one dimension not necessarily being associated with good performance on the other.     

随机地震激励下相邻隔震结构被动控制研究

利用隔震结构和非隔震结构间的相互作用来减小地震作用下的结构响应,考虑地震激励的随机性,基于Clough-Penzien谱模型,推导了相邻结构随机响应的拓展状态方程,采用两种优化控制目标,分析得到了相邻隔震结构体系间连接控制装置的控制参数与结构随机响应的关系及其对控制效果的影响,并分别从地震响应时程和振动累计能量时程角度研究了相应地多自由度相邻隔震结构复合被动控制体系,在不同优化准则及不同控制方案下,结构体系的减震控制效果。研究结果表明,相邻隔震结构复合被动控制体系,可以获得较好的减震控制效果,阻尼系数在减震控制中起主要作用,但存在最优取值,并不是越大越好;采用以左、右子结构振动总能量最小为优化准则,在顶层+中间层安装控制装置的控制方案,可以有效地减小相邻结构的地震响应,得到的控制效果较好。     

The effects of passive leadership on workplace incivility

In this article, we examine the effects of passive leadership on workplace incivility across two studies. Study 1 examines passive leadership–incivility relationships in a sample of employee–supervisor dyads, and Study 2 examines these relationships in a sample of employee–coworker dyads. Results from these studies suggest that passive leadership has a significant direct effect on behavioral incivility and an indirect effect through experienced incivility. Moreover, our results suggest that the relationship between experienced incivility and behavioral incivility is conditional on the level of passive leadership, such that the effect of experienced incivility on behavioral incivility is stronger at higher levels of passive leadership. Copyright © 2014 John Wiley & Sons, Ltd.