Total recycling of CCA treated wood waste by low-temperature pyrolysis

A system to turn a potentially harmful stream of solid waste into a set of substreams with either commercial value or highly concentrated residual streams is presented. The waste which is considered is metal impregnated (in particular Chromated Copper Arsenate (CCA) treated) wood waste and timber, such as telephone poles, railway sleepers, timber from landscape and cooling towers, wooden silos, hop-poles, cable drums and wooden playground equipment. These waste streams sum up to several 100,000 tons of material per year currently to be dumped in every major country of the European Community (EC). Technologies need to be developed to reduce this CCA treated wood waste, such that all of the metals are contained in a marketable product stream, and the pyrolysis gases and/or pyrolysis liquid are used to their maximum potential with respect to energy recuperation. Pyrolysing the CCA treated wood waste may be a good solution to the growing disposal problem since low temperatures and no oxidising agents are used, which result in lower loss of metals compared to combustion. An experimental labscale pyrolysis system has been developed to study the influence of the pyrolysis temperature and the duration of the pyrolysis process on the release of metals and the mass reduction. The macrodistribution and microdistribution of the metals in the solid pyrolysis residue is studied using Inductively Coupled Plasma Mass Spectrometry (ICP–MS) and Scanning Electron Microscopy coupled with Energy Dispersive X-ray Analysis (SEM–EDXA). Furthermore, a complete mass balance is calculated over the pyrolysis system. Based on these results a semi-industrial pyrolysis system (pilot plant scale) has been developed consisting of three stages: grinding, packed bed pyrolysis and metal separation. Special types of equipment have been developed to carry out the three stages. A new grinding system has been developed, based on a crushing mechanism rather than a cutting mechanism. The crushed wood is introduced by means of a screw feeding system into a reaction column. In this pyrolysis reactor the wood is heated by subjecting it to a flow of hot gases. This causes an adiabatic pyrolysis, which results in volatilisation of the volatile compounds whereas the mineral compounds (containing the metals) remain entrapped in a coal-type residue which is very rich in carbon. The condensable compounds in the pyrolysis gas condense while leaving the reaction zone due to the inverse temperature gradient. The pyrolysis gas leaving the reactor is used as fuel for the hot gas generator. The charcoal which is extracted at the bottom of the reactor, is cooled, compressed, removed and stored, ready to feed the subsequent stage. A specially developed grinder is used to remove the metal particles from the charcoal and the separation between metal and charcoal particles is accomplished in a pneumatic centrifuge as a result of the difference in density. Using this system the ultimate waste is less than 3% of the initial wood mass. Results obtained with a semi-industrial scale prototype confirm the effectiveness of the process.     

SPATIAL AND TEMPORAL DYNAMICS OF WOOD IN HEADWATER STREAMS OF THE PACIFIC NORTHWEST1

This paper synthesizes information on the spatial and temporal dynamics of wood in small streams in the Pacific Northwest region of North America. The literature on this topic is somewhat confused due to a lack of an accepted definition of what constitutes “small” streams and what is the relative size of woody debris contained within the channel. This paper presents a matrix that defines woody debris relative to channel size and then discusses the components of a wood budget. Headwater streams are in close proximity to wood sources and, in steeplands, are often tightly constrained by steep hillslopes. Special consideration is given to ecosystem characteristics and to management practices that affect the wood dynamics in this context. Knowledge gaps and uncertainties that can be used to guide future research are identified. Very little is currently known about the role of mass wasting in wood recruitment and storage relative to other processes, such as bank erosion and mortality, in larger streams. Further, very little work has addressed the relative importance of different wood depletion processes, especially those associated with wood transport. The effect of other ecosystem variables on wood dynamics locally across a watershed (from valley bottom to mountaintop) and regionally across the landscape (from maritime to continental climates) is not addressed. Finally, the scientific community has only begun to deal with the effects of management practices on wood quantity, structure, and movement in small streams.     

木结构防火设计方法简介

木材是唯一可再生的主要工业材料,对环境最为友好,是人类历史中的一种重要的建筑材料;但作为一种生物材料,木材具有易燃性,要确保木结构安全,就得充分重视木结构的防火设计。我国传统建筑主要是木结构建筑,其防火问题在我国很早就引起了重视,首先回顾了传统的防火设计方法;然后介绍了1h火灾防护方法,并详细分析了国内外不同木结构体系防火的设计、研究和思路等;其次简要介绍了木材的化学阻燃方法;最后总结木结构各种防火设计方法,提出存在的问题和未来研究的方向。     

IPCC框架下木质林产品碳储核算研究进展:方法选择及关联利益

木质林产品的碳储功能可有效降低大气中二氧化碳的浓度,其碳储量核算已被纳入气候变化缔约国温室气体清单报告,各国基于CBDR原则对木质林产品的碳储计量及贸易流动核算方法学在国家层面的争议及协调,关系到未来在气候变化谈判中的减排责任分配及利益分享。本文首先概括了IPCC历次会议关联木质林产品碳储核算议题及谈判进程,纵向梳理了碳储计量问题的研究进展。其次,对比不同国家和地区关于核算方法的应用及争议,总结不同核算方法在各国间的适用情况及其关联利益。最后,从清单报告和国际贸易角度分析了生产法与储量变化法对林产品碳储计量的不同影响,归纳了不同角度下两种核算方法的适用属性。研究表明:1缔约国附件Ⅰ国家在第二协议期内报告本国木质林产品的碳储量及其变化,在假设本国木质林产品碳储贡献不为零时采用生产法核算碳储量,核算源于本国采伐木的产品碳收支已成为当前缔约国履行气候责任的基本要求;2从清单报告的角度,缔约国基于森林管理参考水平报告碳储量,生产法区别森林管理活动并核算源于可持续森林经营管理的木质林产品碳储量,符合报告的要求;3从国际贸易角度,对于中国等涉及林产品国际贸易的净进口国,储量变化法因考虑到进出口的碳计量,以储量变化法核算碳储量对中国等林产品贸易大国更具优势。     

马尾松酸雨危害与次期性害虫之间关系的研究

本文通过使用罩笼接虫、林中置木招引、模拟酸雨试验小区置木招引的研究方法,对马尾松次期性害虫进行了招引试验.结果表明,受酸雨危害和用酸水处理的试材与对照试材相比,均易遭小蠹、天牛、象虫等次期性害虫的入侵危害.试材平均每100cm~2表面积虫孔数分别高2.2—3,0.5—1.6,0.8—1.0个.     

A lidar-based assessment of riparian shade and large wood potential in the Skagit River watershed,WA

Wild salmon stocks in the Pacific Northwest are imperiled by a variety of declining habitat factors, including riparian shade and in-channel large wood. In this paper, a relatively simple lidar model of the riparian canopy was used along anadromous streams in the Skagit River watershed in western Washington State, United States, to delineate where riparian trees were most lacking, and where restoration efforts would have the greatest benefit in terms of shade and large wood recruitment potential. Within a 45-m riparian buffer, 61% of riparian zones were currently incapable of delivering large wood to the stream. Current potential for large wood recruitment is greatest adjacent to stream edges and falls off rapidly with distance from the channel. Approximately 99% of large wood recruitment potential lies within 45 m of the channel edge, and 50% of the wood potential is within 9 m. A hypothetical canopy model in which all trees mature to a 100-year height would provide 18% more shade distributed over the entire watershed, and 90% more shade in the tributaries. Most of the potential gains in improved shade and large wood contributions are in agricultural areas, as opposed to forestry or urban land uses. The shade and large wood models were constructed from widely available geographic information system tools and are readily transferable to other watersheds with similar characteristics. Model outputs are intended for use in planning restoration projects, as an input to stream temperature models, and to inform policy on restoration priorities and regulatory buffer widths.     

Toxic Metals in the Austrian Pine (Pinus Nigra) Bark in the Thrace Region, Turkey

Austrian pine (Pinus nigra) bark was collected in thirty-seven localities in the Thrace region, Turkey, for the determination of airborne toxic metal distribution. Five toxic metals, As, Cd, Cu, Pb, and Zn, were monitored using atomic absorption spectrometry. Distribution maps of toxic elements in the region were plotted according to Geographic Information System technology. In general, the concentrations of all investigated elements were not high in the region apart from the vicinity of big cities, Tekirdag, Istanbul and, close to Bulgarian border. However, the highest concentrations were not at pollution level. They have a similar distribution pattern throughout the region.     

In-stand scenic beauty of variable retention harvests and mature forests in the U.S. Pacific Northwest: The effects of basal area, density, retention pattern and down wood

Tensions between amenity- and timber-based economies in the U.S. and Canadian Pacific Northwest motivated a study of scenic beauty inside mature forests and timber harvests. A diverse sample of regional forests, measures of forest structure, and large, representative samples of photographs and public judges were employed to measure scenic beauty inside un-harvested mature and old-growth forests, and timber harvests. The latter varied systematically in down wood levels and retention level and pattern. Scenic beauty tended to be optimized at a basal area of 110–155 m³/ha and/or 700–900 trees/ha. Older forests and those with larger trees were perceived to be more beautiful. In harvests, greater retention levels, less down wood, and dispersed rather than aggregated retention patterns contributed to aesthetic improvements. Green-tree retention harvests offer considerable potential gains in perceived scenic beauty compared to perceived very ugly clearcuts, particularly at higher retention levels. These gains are more reliable from dispersed retention patterns. The silvicultural parameters studied change strength in affecting scenic beauty with changes in retention level. These interactions are explored in relation to a range of scenic quality objectives as an aid to planners, visual impact analysts, and silviculturists.     

木材在线性增长热流下着火的复合判据研究

为探索木材在热流变化时的着火特点并提出着火判据,通过试验研究了木材在线性增长热流条件下的自发着火性能,测定了泡桐、椿木、榆木和刺槐4种木材的点燃时间、木材表面的入射热流以及试样内部的温度.结果表明.当热流增长率大于等于0.199kw/(m~2·s)时,试验的所有木材均可以被点燃,点燃这些木材的临界热流增长率介于0.065～0.103 kw/(m~2·s).建立了木材着火的计算模型,计算得出木材自发着火时的表面温度约为500℃.根据试验和计算的结果提出了-结合表面温度和临界热流增长率的木材自发着火复合判据.     

高性能木材干燥测控系统的研制

在木制品生产行业中,木材干燥是木制品加工生产工序中的一个重要环节,而在木材干燥生产中突出的问题是木材变形、开裂、木材含水率不均匀和霉变、虫蛀等。针对上述问题,设计出以高性能AVR微控制器为核心,应用恒流源、高分子湿敏电容和动态补偿等技术的全自动木材干燥测控系统。实验结果表明,木材干燥测控系统能保证产品质量,提高生产效率,硬件可靠性高,有工程实用价值。