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21.
Christine Achten Fokko Tjark Beer Christian Stader Sigrid Grosse Brinkhaus 《Environmental Forensics》2015,16(1):42-50
If organic matter is burnt, the combustion of wood produces the highest amounts of polycyclic aromatic hydrocarbons (PAHs) compared with other fossil energy sources such as oil, coal, or gas. Emissions from wood combustion are increasingly of special interest due to the rising use of wood as a renewable energy source in residential heating in Europe. To the authors' knowledge, reproducible wood-specific PAH patterns in soot were identified for the first time by use of a sampling interval of only 5 min in this study. The short sampling interval was enabled by the very sensitive analytical method of gas chromatography–atmospheric pressure laser ionization–mass spectrometry (GC-APLI-MS) applied. The analysis of 40 PAH of soot from wood logs of spruce, pine, larch (softwood) and beech, birch, oak (hardwood), and wood pellets, as well as wood briquettes, showed 13.46–250.62 mg/kg for ∑40 PAH and 10.75–177.94 mg/kg for the U.S. Environmental Protection Agency PAH standard (without acenaphthylene and anthracene). Highest concentrations occurred in the samples from birch with bark, beech, and wood briquettes. Indeno[1,2,3-cd]pyrene, naphthalene, and alkylated naphthalenes were also detected. Significant concentrations of the very toxic dibenzopyrenes (up to 11.30 mg/kg) are reported. Softwood soot contained highest amounts of 2–4-ring PAH, followed by hardwood which is in accordance with the presence of highest amounts of abietic acid in softwood, a known precursor of retene and phenanthrene. PAH in soot from five spruce samples from different locations show a mean ∑40 PAH concentration of 13.46 mg/kg (n = 5, minimum 8.03, maximum 23.32 mg/kg, SD = 5.65) and exhibited a typical pattern that differed from all other wood soot samples. The distributions of alkylated naphthalenes of the spruce samples show a bell-shape distribution in contrast to the alkylated phenanthrenes/anthracenes of all samples (except the wood pellets), showing a slope distribution. The data indicate that wood-specific PAH patterns exist and under the applied conditions, spruce logs produced the least toxic soot. 相似文献
22.
23.
V.S. Yaliwal N.R. Banapurmath P.G. Tewari 《International Journal of Sustainable Engineering》2014,7(3):253-268
Renewable and alternative fuels have numerous advantages compared with fossil fuels, as they are renewable and biodegradable, and provide food and energy security and foreign exchange savings besides addressing environmental concerns and socio-economic issues. In this context, present work was carried out to investigate the feasibility of alternative and renewable fuels derived from biomass feedstock of different origin for engine applications. The present study was also extended to study the effect of producer gas composition derived from different biomass feedstock on the performance, combustion and emission characteristics of a single-cylinder, four-stroke, direct injection stationary diesel engine operated on a dual-fuel mode using Honge oil methyl ester (HOME) and producer gas induction. The performance of the engine was evaluated with a constant injection timing of 27° before top dead centre, an injection pressure of 205 bar for the diesel–producer gas combination and 230 bar for the HOME–producer gas combination and a compression ratio of 17.5. The results showed that the performance of the dual-fuel engine varies with the composition of the producer gas and depends on the type of biomass feedstock used in the gasifier. Experimental investigations on the dual-fuel engine showed that brake thermal efficiency values for the engine operated using HOME–producer gas derived from babul, neem and honge woods were found to be 17.2, 14.3 and 11.56% respectively, compared to 23.8% for diesel–producer gas operation at 80% load. However, the results showed better engine performance with lower exhaust emission levels for the operation of HOME–producer gas derived from the ordinary or babul wood compared with the operation of that derived from the neem and Honge woods. In view of this, present study reveals that use of alternative and renewable fuels for dual fuel engine can be considered as an immediate solution for the development of rural areas and emergency use in the event of severe diesel fuel shortage. 相似文献
24.
Erik Krznaric Jan H.L. Wevers Jaco Vangronsveld 《Environmental pollution (Barking, Essex : 1987)》2009,157(5):1581-1588
Soil metal pollution can trigger evolutionary adaptation in soil-borne organisms. An in vitro screening test showed cadmium adaptation in populations of Suillus luteus (L.: Fr.) Roussel, an ectomycorrhizal fungus of pine trees. Cadmium stress was subsequently investigated in Scots pine (Pinus sylvestris L.) seedlings inoculated with a Cd-tolerant S. luteus, isolated from a heavy metal contaminated site, and compared to plants inoculated with a Cd-sensitive isolate from a non-polluted area. A dose-response experiment with mycorrhizal pines showed better plant protection by a Cd-adapted fungus: more fungal biomass and a higher nutrient uptake at high Cd exposure. In addition, less Cd was transferred to aboveground plant parts. Because of the key role of the ectomycorrhizal symbiosis for tree fitness, the evolution of Cd tolerance in an ectomycorrhizal partner such as S. luteus can be of major importance for the establishment of pine forests on Cd-contaminated soils. 相似文献
25.
26.
Forest ecosystems may be actively managed toward heterogeneous stand structures to provide both economic (e.g., wood production
and carbon credits) and environmental benefits (e.g., invasive pest resistance). In order to facilitate wider adoption of
possibly more sustainable forest stand structures, defining growth expectations among alternative management scenarios is
crucial. To estimate the effect of tree size and spatial distributions on growth for forest structures commonly considered
in uneven-aged forest stand management, large (0.2 ha+) plots were established in 14 uneven-aged ponderosa pine stands in
eastern Montana. All study trees were stem-mapped and measured for diameter and 10-year sapwood and basal area increment.
A generalized growth model was developed to predict both total and merchantable 10-year basal area increment for nine hypothetical
stand structures [three diameter distributions (reverse-J, irregular, flat) × three spatial distributions (clumpy, partial
clumpy, uniform)]. Results indicate that the size and spatial distributions of individual trees have a considerable effect
on overall stand growth. The greatest total stand growth was in stands with reverse “J” shaped tree size distributions, while
the greatest merchantable stand growth was in stands with “flat” diameter distributions and uniform spatial distributions.
Through better comprehension of generalized uneven-aged stand growth dynamics, forest managers may better assess the effects
of alternative stand structures on stand growth while providing forest stand structures that may be more resilient in a changing
climate. 相似文献
27.
Mohammednoor Altarawneh Daniel Carrizo Artur Ziolkowski Eric M. Kennedy Bogdan Z. Dlugogorski John C. Mackie 《Chemosphere》2009,74(11):1435-1443
This article reports the computational and experimental results of the thermal decomposition of permethrin, a potential source of dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF). We have performed a quantum chemical analysis by applying density functional theory to obtain the decomposition pathways of permethrin and the formation mechanism of dibenzofuran. We have conducted the pyrolysis experiments in a tubular reactor and identified the pyrolysis products to demonstrate the agreement between the experimental measurements and quantum chemical calculations. The initiation of the decomposition of permethrin involves principally the aromatisation of permethrin into 3-phenoxyphenylacetic acid, 2-methylphenyl ester (J) and concomitant loss of 2HCl. This rearrangement is followed by the rupture of the O–CH2 linkage in J, with a rate constant derived from the quantum chemical results of 1 × 1015 exp(−68 kcal/mol/RT) s−1 for temperatures between 700 and 1300 K. This is confirmed by finding that the rate constant for unimolecular rearrangement of permethrin into J is 1.2 × 1012 exp(−53 kcal/mol/RT) s−1 over the same range of temperatures and exceeds the direct fission rate constant at all temperatures up to 850 ± 120 °C as well as by the experimental detection of J prior to the detection of the initial products incorporating diphenyl ether, 1-methyl-3-phenoxybenzene, 3-phenoxybenzaldehyde and 1-chloromethyl-3-phenoxybenzene. As the temperature increases, we observe a rise in secondary products formed directly or indirectly (via phenol/phenoxy) including aromatics (naphthalene), biphenyls (biphenyl, 4-methyl-1,1′-biphenyl) and dibenzofuran (DF). In particular, we discover by means of quantum chemistry a direct route from 2-phenoxyphenoxy to naphthalene. We detect no polychlorinated dibenzo-p-dioxins and dibenzofurans. Unlike the case of oxidative pyrolysis [Tame, N.W., Dlugogorski, B.Z., Kennedy, E.M., 2007b. Formation of dioxins in fires of arsenic-free treated wood: Role of organic preservatives. Environ. Sci. Technol. 41, 6425–6432] where significant yields of both PCDD and PCDF were obtained, under non-oxidative conditions the thermal decomposition of permethrin does not form appreciable amounts of PCDD or PCDF and the presence of oxygen (and/or a sizable radical pool) appears necessary for the formation of dibenzo-p-dioxin itself or PCDD/F from phenol/phenoxy. 相似文献
28.
Jianli Xiao Jun Zhu Senyu Chen Weibin Ruan Curtis Miller 《Journal of environmental science and health. Part. B》2013,48(6):749-757
Experiments were carried out in two steps to determine the effect of anaerobically digested swine manure on soybean cyst nematode (SCN) egg control. In the first step, liquid swine manure underwent anaerobic digestion to search for the best digestion time for both volatile fatty acids (VFA) and ammonium nitrogen (NH4 +) enrichment. The results showed that about 17 and 28 days of incubation were needed, respectively, to reach the maximal levels of VFA and NH4 + in the manure. In the second step, raw, VFA-enriched, and NH4 +-enriched manure were applied separately, at four different rates (25, 50, 100, and 200 mL/pot), to soil pots inoculated with nematode eggs in a greenhouse environment. Soil samples were collected 35 and 61 days after inoculation to determine the effect of such treated manure on SCN egg productivity. The data indicated that the SCN egg counts were inversely related to the manure application rates in a linear manner with correlation coefficients of 0.998, 0.967, and 0.900 for raw, NH4 +-enriched, and VFA-enriched manure for the 35-day samples. While no such relationships were found for the 61-day samples, implying that none of the treatments were still effective 61 days after application. At the four application rates, the VFA-enriched manure performed best in reducing SCN egg counts (by 18.1, 19.5, 34.3, and 18.6%) as compared to the raw manure treatment. In contrast, the NH4 +-enriched manure achieved mostly negative reductions. To achieve the best control of SCN egg growth, the VFA-enriched manure should be used and applied to soybean fields every 35 days. 相似文献
29.
R. Nogales C. Elvira E. Benítez R. Thompson M. Gomez 《Journal of environmental science and health. Part. B》2013,48(1):151-169
Abstract A laboratory study was conducted to examine the feasibility of vermicomposting dairy biosolids (dairy sludge), either alone or with either of the bulking agents ‐ cereal straw or wood shavings, using the epigeic earthworm ‐ Eisinea andrei. Earthworms added directly to these three substrates died within 48 hours. A system was developed to overcome the toxic effect of unprocessed dairy biosolids. The substrates were placed over a layer of vermicomposted sheep manure into which the earthworms were inoculated. Within two weeks, all earthworms were within the upper layer of substrate. Compared to sheep manure which is a favourable substrate for vermicomposting, the three substrates containing dairy biosolids were more effective in supporting earthworm growth and reproduction. The final products obtained after 63 days of vermicomposting had 39–53% less organic carbon than the initial substrates. Organic fractionation indicated that vermicomposting increased the stability of the materials to biological decomposition. The vermicomposts obtained from the three substrates with dairy biosolids had low heavy metal contents and electrical conductivities, and did not inhibit plant growth when compared with a commercial vermicompost in a bioassay. 相似文献
30.
We demonstrate an approach for evaluating the level of protection attained using a variety of forms and levels of past, current,
and proposed Air Quality Standards (AQSs). The U.S. Clean Air Act requires the establishment of ambient air quality standards
to protect health and public welfare. However, determination of attainment of these standards is based on ambient pollutant
concentrations rather than prevention of adverse effects. To determine if a given AQS protected against adverse effects on
vegetation, hourly ozone concentrations were adjusted to create exposure levels that “just attain” a given standard. These
exposures were used in combination with a physiologically-based tree growth model to account for the interactions of climate
and ozone. In the evaluation, we used ozone concentrations from two 6-year time periods from the San Bernardino Mountains
in California. There were clear differences in the level of vegetation protection achieved with the various AQSs. Based on
modeled plant growth, the most effective standards were the California 8-hr average maximum of 70 ppb and a seasonal, cumulative,
concentration-weighted index (SUM06), which if attained, resulted in annual growth reductions of 1% or less. Least effective
was the 1-hr maximum of 120 ppb which resulted in a 7% annual reduction. We conclude that combining climate, exposure scenarios,
and a process-based plant growth simulator was a useful approach for evaluating effectiveness of current or proposed air quality
standards, or evaluating the form and/or level of a standard based on preventing adverse growth effects. 相似文献