CeCl3和CeO2对松木屑的催化热解作用研究

以松木屑为研究对象,分别负载CeCl₃和CeO₂两种催化剂,制备松木屑原位催化热解原料,探究不同添加比例的CeCl₃和CeO₂两种催化剂在不同热解温度下对松木屑热解产物的产率和气体组分的影响。结果表明:在CeCl₃和CeO₂两种催化剂的催化作用下均能使热解气和焦炭产率增加、焦油产率减小,且随着两种催化剂添加比例的增加,松木屑热解产物的产率和气体组分均有所变化;在650℃的热解温度下,与无催化剂相比,当CeCl₃添加比为10.0%时焦油产率降低至53.05%,下降了11.70%,当CeCl₃添加比为7.5%时热解气产率达到最大值18.58%,当CeCl₃添加比为10.0%时焦炭产率为26.85%,增加了7.48%,热解气H₂和CO₂组分的百分比含量显著增加;当CeO₂添加比为7.5%时焦油产率达到最小值59.95%,下降了4.80%,当CeO₂添加比为10.0%时热解气产率增加了2.39%,当CeO₂添加比为10.0%时焦炭产率相对较大值为21.66%,增加了2.29%,各热解气组分的百分比含量变化较小;在原位催化热解中,CeCl₃催化剂的催化效果优于CeO₂催化剂。     

Managing Forests for Increased Regional Water Yield in the Southeastern U.S. Coastal Plain

With growing populations fueling increased groundwater abstraction and forecasts of greater water scarcity in the southeastern United States, identifying land management strategies that enhance water availability will be vital to maintaining hydrologic resources and protecting natural systems. Management of forested uplands for lower basal area, currently a priority for habitat improvement on public lands, may also increase water yield through decreased evapotranspiration (ET). To explore this hypothesis, we synthesized studies of precipitation and ET in coastal plain pine stands to develop a statistical model of water yield as a function of management strategy, stand structure, and ecosystem water use. This model allowed us to estimate changes in water yield in response to varying management strategies across spatial scales from the individual stand to a regional watershed. Results suggest that slash pine stands managed at lower basal areas can have up to 64% more cumulative water yield over a 25‐year rotation compared to systems managed for high‐density timber production, with the greatest increases in stands also managed for recurrent understory fire. Although there are important uncertainties in the magnitude of additional water yield and its final destination (i.e., surface water bodies vs. groundwater), this analysis highlights the potential for management activities on public and private timber lands to partially offset increasing demand on surface and groundwater resources.     

Changes in Species Diversity of Rove Beetles (Coleoptera,Staphylinidae) Depending on the Age of Pine Plantations in Central Belarus

Trends of changes in species richness and dominance in staphylinid communities depending on the age of pine plantations have been analyzed. The species richness of these communities is high in the plantations of age classes 1 and 2 (11 and 28 years, respectively) but decreases in the plantations of age class 3 (60 years). The highest and lowest indices of species diversity are observed in the plantations of age classes 2 and 3, respectively. Four groups of rove beetles have been distinguished by the criterion of their dominance in pine plantations of different ages.__________Translated from Ekologiya, No. 4, 2005, pp. 306–313.Original Russian Text Copyright © 2005 by Derunkov.     

Variation in the Anatomical Characters of Needles and Their Resistance to Technogenic and Climatic Stress in Scotch Pine

Russian Journal of Ecology -     

Influence of Metals on Lindane Adsorption onto Pine Bark

Some persistent pesticides, as organochlorines, are not efficiently removed from usual wastewater treatment plants, unless a tertiary treatment, commonly activated carbon adsorption, is applied. The downside of this practice rests on its high regeneration costs. This fact motivated the research for alternative processes involving the use of natural materials. Pine bark was used in this work, to remove lindane from contaminated waters. The adsorptive capabilities of this material were studied (equilibrium time, adsorption model and saturation of the adsorbent) and the interference of some metals (iron, cadmium, copper, nickel and lead) was also investigated. Results showed an excellent efficiency of adsorption (average 80,65%) and that the presence of the studied metals did not affect both efficiency and the model of the adsorption, within the range of the concentration of the pesticide studied.     

Spatial distribution of coarse woody debris in pine forests of the Marii El Transvolga region

The spatial distribution of coarse woody debris in pine forests has been studied in the Transvolga region of the Marii El Republic. For this purpose, 30 test plots have been established in pine (Pinus sylvestris) stands of the study region. The results are indicative of a tendency toward the spatial grouping (clustering) of woody debris by fractions, decomposition classes, and stocks along with increase in stand age.     

西大别山百战坪黄山松径向生长对气候因子的响应

研究基于标准的树轮年代学研究方法（样芯经固定、晾干、打磨、交叉定年、测量和标准化等处理）,首次建立了大别山西部的黄柏山百战坪的黄山松树轮宽度标准年表。研究发现,黄山松宽度年表有较高的信噪比SNR和样本解释总量EPS,表明树轮宽度年表中含有较多的气候信息,适合做树轮气候学研究。树轮宽度年表与气象因子关系的研究结果显示,黄山松树轮宽度与上一年10月、12月及当年的5月至9月的气温（包括月均最高气温、月均温和月均最低气温）呈较高的负相关,且在上一年的12月和当年7月月均最高气温和月均温的限制作用较强,而上一年10月月均温限制作用最大,这表明上一年生长季末和当年生长季中的高温通过对水分的影响限制黄山松的生长。树轮指数与当年2月、4月至7月的月降水及月相对湿度（6月份除外）均呈较高正相关,说明在进入生长期前后充足水分对黄山松生长有促进作用,但当降水或相对湿度过大时（如上年8月与当年6月）对黄山松生长就起到一定的限制作用。本研究结果填补了大别山西段树木年轮研究的空白,为该区域树木年轮气候重建研究提供参考和基础数据,也为黄柏山自然保护区今后的森林培育和森林管理提供了一定的理论依据。     

鼎湖山马尾松林凋落物分解对凋落物输入变化的响应

为了了解我国南方森林常见的人为干扰（凋落物收取）活动对生态系统养分循环的影响,研究了鼎湖山马尾松林3种主要树种凋落物分解及其养分释放对凋落物输入量变化的响应。这3种树种分别为马尾松（Pinus massoniana）、荷木（Schimasuperba）和锥栗（Castanopsis chinensis）。凋落物输入量变化分别为凋落物去除（L-）、加倍（L＋）和对照（L）3种处理,每种处理25个重复。经过18个月的处理试验,凋落物分解速率及其养分释放随树种、分解阶段和凋落物处理不同而异。荷木、马尾松和锥栗分解物平均残留率分别为0.46±0.01、0.42±0.01、0.40±0.02,其中,荷木与锥栗、马尾松差异性显著。不同处理间的凋落物分解速率差异显著,加倍、对照和去除处理样地凋落物的平均残留率分别为0.51±0.08、0.53±0.09和0.55±0.08。凋落物加倍处理促进了凋落物分解过程中C的释放,而去除凋落物处理则抑制了N、P的释放。以上结果表明,凋落物收取活动不仅直接带走凋落物中的大量养分,而且抑制了凋落物分解及其养分释放。     

SO2暴露方式与油松生长的关系

苗龄为87d的油松(Pinus tabulaeformis Carr.)于2002-07-01～08-29在3个处理组进行SO₂暴露实验60昼夜,处理1和处理2在24h中SO₂浓度分别为0.1 mg·m^-3和0.2 mg·m^-3,处理3每日6h SO₂浓度为0.5 mg·m^-3,18h SO2浓度为0.1mg·m^-3.经SO₂暴露后,处理1油松针叶气孔保卫细胞、针叶颜色未见异常;叶绿素含量、类胡萝卜素含量、光合速率、蒸腾速率、单株干重、相对生长速率与对照组无显著差异;但针叶含硫量比对照增加17%,从针叶渗出的钾离子量比对照增加22%.处理2油松气孔保卫细胞、针叶颜色未见异常;叶绿素含量、光合速率、蒸腾速率与对照组无显著差异;类胡萝卜素含量下降5%,针叶含硫量增加92%,从针叶渗出的钾离子量比对照增加67%,单株干重下降4.5%,相对生长速率下降0.6mg·(g·d)^-1.处理3油松气孔保卫细胞、针叶颜色发现异常;叶绿素含量与对照组相似,但类胡萝卜素含量下降21%,含硫量增加104%,从针叶渗出的钾离子量比对照增加89%,光合速率下降5%,蒸腾速率增加8%,单株干重下降7.6%,相对生长速率下降1.3mg·(g·d)^-1.     

南京紫金山马尾松树轮δ13C对气候变化响应敏感性的研究

树木年轮宽度指标在气候重建中发挥了重要的作用,可是在温暖湿润的地区,利用树木年轮宽度重建古气候遇到了困难。因此寻找其他代用指标就成为一项急迫而重要的任务。一些研究发现,树轮稳定碳同位素可以发挥重要的作用。但是,是否所有的树种的树轮碳同位素对气候的响应都同样的敏感,还需要通过大量的研究分析工作来验证。为了了解温暖湿润的亚热带季风区马尾松树轮δ13C对气候响应的敏感性,选取了南京紫金山的两个马尾松树盘,进行了树轮δ13C的分析,建立了1939~2002和1955~2002年两个树轮δ13C变化序列。与降水、温度、相对湿度、光照时数、风速等气候指标进行了相关分析。结果表明：（1）马尾松树轮δ13C对于气候的响应是敏感的,可以作为气候变化的代用指标;（2）坡向对于马尾松树轮δ13C对气候的响应敏感性也有一定的影响,树轮δ13C平均值西南坡比东南坡高,西南坡比东南坡对月平均最低和最高温度的响应更敏感;（3）紫金山马尾松树轮δ13C与该地区生长季（尤其是夏、秋季）的月平均气温、月平均最高气温和日照时数呈正相关,而与月平均最低气温、降水量、空气相对湿度呈负相关