V2O5/CeO2催化剂用于低温NH3-SCR的性能研究

采用浸渍法制备了系列V2O5/CeO2催化剂,用于低温NH3选择性催化还原(NH3-SCR)NO.同时,考察了催化剂中V2O5负载量和煅烧温度对催化活性的影响,并运用SEM,BET和XRD物理化学技术对催化剂进行了表征.结果表明,V2O5/CeO2催化剂对模拟烟气中的NO转化呈现出较高的活性,但是V2O5负载量和催化剂的催化活性并不呈线性递增的关系.当V2O5负载量超过10%时,催化剂的催化活性开始下降.随着煅烧温度的升高,由于钒酸铈的生成,催化剂的催化活性下降.400℃为最佳煅烧温度.     

侧流化学磷回收强化生物除磷的模拟预测与试验验证

为了强化污水中生物除磷作用,本研究通过模拟预测与实验室试验验证了厌氧上清液侧流化学磷沉淀与回收对强化生物除磷的促进作用.模拟预测与试验结果表明,在进水COD/P=37.5工况下,当侧流比增加至30%时,通过化学磷沉淀（调节pH＞9.0）可使出水中TP浓度从碳源抑制时的＜6.0 mg·L-1（以P计）下降至≤1.0 mg·L-1（以P计）,同时可回收进水中P负荷的64%.经验证与校正后的TUD数学模型模拟预测有着与试验结果近乎一致的效果.因此,数学模拟技术完全有可能取代中间试验过程而直接将小试结果放大至工程应用.     

一起氯碱厂化学品泄漏事故原因浅析

通过对一起储罐破裂导致的化学品泄漏事故原因分析,说明了次氯酸钠与盐酸是禁忌物质,建议设计、评价人员应全面深刻理解国家有关安全标准和设计规范,正确设计;生产使用单位接受事故教训,防止同类事故重演。     

采油厂化验室危险因素及对策

针对采油厂化验室的特点,对其存在的危险有害因素,从火灾爆炸、中毒、腐蚀、触电、机械伤害、人员、储存场所等方面进行了较为系统的分析,并提出了相应的对策措施。     

Assessment of the effect of technical and management characteristics on the frequency of release from piping: An application to a gas storage facility

The assessment of the frequencies of release from piping due to losses of containment is an essential step in the preparing Safety Reports, drawn up as required by the so-called “Seveso” Directive. These are usually calculated starting from the frequencies of random rupture included in international databases and are not plant-specific, furthermore, the quantification of the effect of the safety management system of the facility is not easy. A simple and flexible approach quantifying technical and management characteristics of the plant has been proposed by Milazzo and co-workers in 2010; it is based on the modification of the frequency taken from literature, through the use of the percentages of failure causes actually possible in that plant, and the judgment about their management. The data about the failure causes are taken from the literature and modified by using corrective factors to adapt them to the industrial context. To make possible the application of the method to a large number of major-hazard industry types, some aspects of the approach needed to be improved; these have been identified during a development project coordinated by RINA Consulting, on behalf of Saipem, with the collaboration of the University of Messina. The improvement of the approach focused on two main points, the development of a method to calculate the corrective factors for the failure causes associated with corrosion and erosion phenomena and the strengthening of the methodology for the formulation of the judgment about the safety management. This paper illustrates the fully improved method, as well as an application to a typical gas storage plant.     

浸渍液pH值对V-Mo/Ti脱硝催化剂性能的影响研究

为提升V-Mo/Ti催化剂的脱硝性能,在催化剂制备过程中调节浸渍工艺参数,制备了一系列不同浸渍液pH值的催化剂,采用XRD、N2-吸附脱附、拉曼光谱、UV-Vis、H2-TPR、NH3-TPD等手段对催化剂进行表征,考察了pH值的变化对催化剂物理化学性能的影响,采用固定床微型反应器对催化剂的脱硝性能进行评价。结果表明,降低浸渍液pH值,可以抑制催化剂上VOx物种的聚合,提升催化剂的还原性能,有利于提升催化剂的脱硝效率,降低脱硝反应过程中N2O生成量。同时,浸渍液pH值的变化,也会影响催化剂的酸性性能。当浸渍液pH值低于3.64时,催化剂酸性性能显著降低,造成催化剂脱硝性能降低;当浸渍液pH值控制在3.64时,催化剂的还原性能和酸性性能匹配较好,从而显示了较高的脱硝性能。     

多源数据支持下城市火灾风险评估及规划响应

为探析城市火灾风险的空间格局特征,提出科学的火灾防控体系,以合肥市为研究对象,基于火灾风险兴趣点(POI)数据、NPP/VIIRS夜间灯光影像数据、消防站与道路信息等多源数据,运用SAVEE模型和迭代方程评估城市火灾风险,并引入区位-配置(L-A)模型,从不同目标情境优化消防站点布局。研究表明:火灾高风险区主要集中于合肥市二环以内的建成区,尤其是老城区、合肥西站片区、政务区、科学城和东部新中心等区域;现有48座消防站对研究区内的POI覆盖效果较好,覆盖率为86.76%,而对NPP/VIIRS覆盖效果一般,覆盖率仅为55.94%,覆盖率在合肥市东北部、西北部和南部部分地区仍有不足;基于最大化覆盖模型,规划新增44座消防站,明显提升5 min响应时间的覆盖率,可进一步夯实城市消防安全。     

The Effects of Irrigation and Climate on the High Plains Aquifer: A County‐Level Econometric Analysis

The High Plains Aquifer (HPA) underlies parts of eight states and 208 counties in the central area of the United States (U.S.). This region produces more than 9% of U.S. crops sales and relies on the aquifer for irrigation. However, these withdrawals have diminished the stock of water in the aquifer. In this paper, we investigate the aggregate county‐level effect on the HPA of groundwater withdrawal for irrigation, of climate variables, and of energy price changes. We merge economic theory and hydrological characteristics to jointly estimate equations describing irrigation behavior and a generalized water balance equation for the HPA. Our simple water balance model predicts, at average values for irrigation and precipitation, an HPA‐wide average decrease in the groundwater table of 0.47 feet per year, compared to 0.48 feet per year observed on average across the HPA during this 1985–2005 period. The observed distribution and predicted change across counties is in the (?3.22, 1.59) and (?2.24, 0.60) feet per year range, respectively. The estimated impact of irrigation is to decrease the water table by an average of 1.24 feet per year, whereas rainfall recharges the level by an average of 0.76 feet per year. Relative to the past several decades, if groundwater use is unconstrained, groundwater depletion would increase 50% in a scenario where precipitation falls by 25% and the number of degree days above 36°C doubles. Editor’s note : This paper is part of the featured series on Optimizing Ogallala Aquifer Water Use to Sustain Food Systems. See the February 2019 issue for the introduction and background to the series.     

Changes in Hydrology of the Ganges Delta of Bangladesh and Corresponding Impacts on Water Resources

The Ganges Delta in Bangladesh is an example of water‐related catastrophes in a major rural river basin where limitations in quantity, quality, and timing of available water are producing disastrous conditions. Water availability limitations are modifying the hydrologic characteristics especially when water allocation is controlled from the upstream Farakka Barrage. This study presents the changes and consequences in the hydrologic regime due to climate‐ and human‐induced stresses. Flow duration curves (FDCs), rainfall elasticity, and temperature sensitivity were used to assess the pre‐ and post‐barrage water flow patterns. Hydrologic and climate indices were computed to provide insight on hydro‐climatic variability and trend. Significant increases in temperature, evapotranspiration, hot days, heating, and cooling degree days indicate the region is heading toward a warmer climate. Moreover, increase in high‐intensity rainfall of short duration is making the region prone to extreme floods. FDCs depict a large reduction in river flows between pre‐ and post‐barrage periods, resulting in lower water storage capacity. The reduction in freshwater flow increased the extent and intensity of salinity intrusion. This freshwater scarcity is reducing livelihood options considerably and indirectly forcing population migration from the delta region. Understanding the causes and directions of hydrologic changes is essential to formulate improve water resources management in the region.     

Climate and Land Use Effects on Hydrologic Processes in a Primarily Rain‐Fed,Agricultural Watershed

Anticipating changes in hydrologic variables is essential for making socioeconomic water resource decisions. This study aims to assess the potential impact of land use and climate change on the hydrologic processes of a primarily rain‐fed, agriculturally based watershed in Missouri. A detailed evaluation was performed using the Soil and Water Assessment Tool for the near future (2020–2039) and mid‐century (2040–2059). Land use scenarios were mapped using the Conversion of Land Use and its Effects model. Ensemble results, based on 19 climate models, indicated a temperature increase of about 1.0°C in near future and 2.0°C in mid‐century. Combined climate and land use change scenarios showed distinct annual and seasonal hydrologic variations. Annual precipitation was projected to increase from 6% to 7%, which resulted in 14% more spring days with soil water content equal to or exceeding field capacity in mid‐century. However, summer precipitation was projected to decrease, a critical factor for crop growth. Higher temperatures led to increased potential evapotranspiration during the growing season. Combined with changes in precipitation patterns, this resulted in an increased need for irrigation by 38 mm representing a 10% increase in total irrigation water use. Analysis from multiple land use scenarios indicated converting agriculture to forest land can potentially mitigate the effects of climate change on streamflow, thus ensuring future water availability.