亚洲地区环境监测实验室精度调查

为了解亚洲各国环境监测实验室监测分析数据的精度现状,提高实验室的监测技术水平,同时为了编制“亚洲地区环境监测实验室精度管理手册”提供依据,日本JICA（日本国际协力团）在亚洲开展了精度调查工作。文章报导了我国有关的33个环境监测实验室参加该精度调查的内容,和本次精度调查的结果及影响数据质量的因素分析,并与亚洲其它国家精度调查结果进行了比较。     

惯性系统飞行试验精度检验方法

目的针对传统工具误差分离方法得到的分离结果不够准确可信的问题,提出了一种利用等效误差实现对惯性系统精度判定的方法。方法首先基于主成分分析,定义等效误差,等效误差具有独立、无偏的性质。然后提出基于等效误差的假设检验判断惯性系统精度是否合格的方法。结果算例表明采用该方法可以实现惯性系统精度的可信判断。结论该方法解决了以往方法误差大,分析结论可信度不高的问题。     

Influence of disability type on upper-limb motor skills

This study was carried out in order to determine the effect of physical disability (paraplegia) and sensory disability (deafness) on motor skills of the upper limbs. Studies were distinguished by two parameters: the nature of the control curve (sine or random) and the magnitude of the isometric force exerted on the lever (10?N, 20?N, 40?N, 80?N). A comparison of the quality of manual force control in a visual detection task among groups of people with sensory disability (deaf), people with physical disability (paraplegic) and people without disability showed differences among those groups. Values of force above 20?N create conditions of lower quality of control and of direction of force exertion outside the body. At the same time, the study proved that people with some types of disability can perform certain work tasks as effectively as people without disability.     

流动注射在线UV消解测定环境水体中的总氮研究

采用San++流动分析仪在线UV消解测定环境水体中的总氮,样品浓度在0.00~5.0 mg/L与峰高有良好的线性关系(r=0.999 6)。进行了标准样品考核和实际水样的流动注射法和国标方法的比对分析。实验结果表明:采用流动注射在线消解测定水中TN,其标样测定值均在保证值范围内,相对标准偏差小于3%;两种方法测定实际水样的结果无显著性差异且具有很好的一致性,加标回收实验的回收率在90.0%~97.7%之间,能满足地表水及排放废水中TN监测要求。     

The Precision of Precipitation Chemistry Measurements in the Canadian Air and Precipitation Monitoring Network (CAPMoN)

Precision estimates are presented for precipitation chemistry and depth measurements made by the Canadian Air and Precipitation Monitoring Network (CAPMoN). The estimates were made for daily measurements of ion concentration and precipitation depth as well as for weekly, 28-day, seasonal and annual precipitation-weighted mean concentrations and depths. The data on which the estimates are based were collected from collocated samplers at five CAPMoN sites during the period 1985 to 1993. The data pairs from the collocated samplers were used to calculate the between-instrument error defined as 1/2 times the difference between the paired sample concentrations (or depths). For all of the ion concentrations and depths, the between-sampler errors were found not to be normally distributed, but the normality of the distributions improved with the length of the (volume-weighting) time period considered. A set of quantitative measures of overall network precision were derived in absolute (mg L^-1) and relative (%) units. These included the Modified Median Absolute Deviation (M.MAD), the P90% probability values and the Coefficient of Variation (CoV). The latter, defined as the percent ratio of the M.MAD to the median concentration (or depth), represents the relative precision at the center of the error and concentration (and depth) distributions. Based on the CoV values, the relative precision of the CAPMoN measurements was very high (better than 4%) for SO ₄ ^2- , NO ₃ ^- , pH, H⁺, NH ₄ ⁺ , sample depth and standard gauge depth, and not as high (between 10 and <35%) for Cl^-, Na⁺, Ca²⁺, Mg²⁺, and K⁺. The ions with the lowest median concentrations had the poorest relative precision since so many of the concentrations were at or near the analytical detection limit. Except for the sample and standard gauge depths, both the absolute and relative precision improved with the length of the precipitation-weighting period. Detailed statistical testing established that the precision of the daily measurements is dependent on a number of factors, the most dominant being sample depth and concentration, i.e., the absolute precision improves with increasing sample depth and decreasing concentration. The strength of these relationships diminished with the length of the precipitation-weighting period being considered. Laboratory-related sources of imprecision were found to account for less than 4% of the overall daily measurement imprecision for most species, while field-related sources of imprecision accounted for the balance. Specialized plots are shown which allow data users to estimate the absolute and relative precision at any concentration and depth value.     

环境土壤标准物质的研究与制备

用高铝陶瓷球磨加工在１２０℃下烘干３０ｈ的风砂土、黑土和暗棕壤土壤样品。用Ｘ－射线荧光光谱法等分析样品中Ｃｕ,Ｆ３,Ｔｉ等元素,做均匀度检验,结果表明样品均匀。定值分析采用ＮＡ、ＩＣＰ－ＭＳ等１８种不同原理的分析技术。在１年多时间里,用Ｘ－射线荧光光谱法做稳定性实验,表明样品稳定。在ＩＢＭ计算机上处理获取的全部数据。用Ｇｒｕｂｂｓ、多重比较Ｓ法等剔除离群值,求出最佳估计值。以最佳估计值按定值原则确     

基于微震监测技术在矿山安全管理中的应用研究

在井下巷道工程设计多个微震监测系统传感器站网空间布置方案,地震信号由传感器采集并进行前置放大,传至井下数据交换中心,经A/D转化后的数字信号再经由光缆传至地表监测控制中心相连的计算机,利用监测数据对矿山地震活动及岩爆与地压活动进行分析研究、实时的监测和预报.应用该微震监测技术对冬瓜山铜矿的事件定位精度和系统灵敏度的分析,对人工震源定位及定位精度进行的验证实验以及对冬瓜山矿区井下各种振动波形进行的识别和分析,取得了很好的效果.微震监测系统的建立对于推动我国矿山地压灾害监测和安全管理水平具有重要参考意义.     

Adequacy of Visually Classified Particle Count Statistics From Regional Stream Habitat Surveys1

Abstract: Streamlined sampling procedures must be used to achieve a sufficient sample size with limited resources in studies undertaken to evaluate habitat status and potential management‐related habitat degradation at a regional scale. At the same time, these sampling procedures must achieve sufficient precision to answer science and policy‐relevant questions with an acceptable and statistically quantifiable level of uncertainty. In this paper, we examine precision and sources of error in streambed substrate characterization using data from the Environmental Monitoring and Assessment Program (EMAP) of the U.S. Environmental Protection Agency, which uses a modified “pebble count” method in which particle sizes are visually estimated rather than measured. While the coarse (2?) size classes used in EMAP have little effect on the precision of estimated geometric mean (D_gm) or median (D₅₀) particle diameter, variable classification bias among observers can contribute as much as 0.3?, or about 15‐20%, to the root‐mean‐square error (RMSE) of D_gm or D₅₀ estimates. D_gm and D₅₀ estimates based on EMAP data are nearly equal when fine sediments (<2 mm) are excluded, but otherwise can differ by up to a factor of 2 or more, with D_gm < D₅₀ for gravel‐bed streams. The RMSE of reach‐scale particle size estimates based on visually classified particle count data from EMAP surveys, including variability associated with reoccupying unmarked sample reaches during revisits, is up to five to seven times higher than that reported for traditional measured pebble counts by multiple observers at a plot scale. Nonetheless, a variance partitioning analysis shows that the ratio of among site to revisit variance for several EMAP substrate metrics exceeds 8 for many potential regions of interest, suggesting that the data have adequate precision to be useful in regional assessments of channel morphology, habitat quality, or ecological condition.     

基于超声脉冲法的火灾损伤后混凝土裂纹深度检测

检测或诊断裂纹深度是火灾后混凝土结构受损综合评判的重要依据。开发一种专用的火灾后混凝土裂纹深度检测仪器,是一项填补国内该领域空白的重要研究课题。在研讨和分析超声脉冲法检测混凝土表面损伤裂纹深度的单面平测法、逐层穿透法和损伤层厚度判定3种测试方法的基础上,笔者设计开发了一种超声测试诊断仪,采用高精度计时电路、传感器驱动电路和自动增益电路,提高了仪器计时精度和抗干扰性。经对多组火灾损伤后的结构混凝土试件的测试,获取了6组共60个声时数据,用给出的方法进行了计算,得出的裂纹深度值与观察结果能较好地吻合。理论与实测表明,提出的裂纹检测方法和开发出的测试仪器具有实用性。     

Development of statistical models for predicting muscle and mental activities during repetitive precision tasks

This study was conducted to develop muscle and mental activities on repetitive precision tasks. A laboratory experiment was used to address the objectives. Surface electromyography was used to measure muscle activities from eight upper limb muscles, while electroencephalography recorded mental activities from six channels. Fourteen university students participated in the study. The results show that muscle and mental activities increase for all tasks, indicating the occurrence of muscle and mental fatigue. A linear relationship between muscle activity, mental activity and time was found while subjects were performing the task. Thus, models were developed using those variables. The models were found valid after validation using other students’ and workers’ data. Findings from this study can contribute as a reference for future studies investigating muscle and mental activity and can be applied in industry as guidelines to manage muscle and mental fatigue, especially to manage job schedules and rotation.