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121.
Ordered mesoporous carbon supported iron catalysts(Fe/OMC) were prepared by the incipient wetness impregnation method and investigated in Fenton-like degradation of 4-chlorophenol(4CP) in this work. XRD and TEM characterization showed that the iron oxides were well dispersed on the OMC support and grew bigger with the increasing calcination temperature. The catalyst prepared with a lower calcination temperature showed higher decomposition efficiency towards 4CP and H2O2, but more metals were leached. The effect of different operational parameters such as initial pH, H2O2 dosage, and reaction temperature on the catalytic activity was evaluated. The results showed that 96.1% of 4CP and 47.4% of TOC was removed after 270 min at 30°C, initial pH of 3 and 6.6 mmol/L H2O2. 88% of 4CP removal efficiency was retained after three successive runs, indicating Fe/OMC a stable catalyst for Fenton reaction. 4CP was degraded predominately by the attack of hydroxyl radical formed on the catalyst surface and in the bulk solution due to iron leaching. Based on the degradation intermediates detected by high performance liquid chromatography, possible oxidation pathways were proposed during the 4CP degradation. 相似文献
122.
A novel coupled system using Co–Ti O2 was successfully designed which combined two different heterogeneous advanced oxidation processes, sulfate radical based Fenton-like reaction(SR-Fenton) and visible light photocatalysis(Vis-Photo), for degradation of organic contaminants. The synergistic effect of SR-Fenton and Vis-Photo was observed through comparative tests of 50 mg/L Rhodamine B(Rh B) degradation and TOC removal. The Rhodamine B degradation rate and TOC removal were 100% and 68.1% using the SR-Fenton/Vis-Photo combined process under ambient conditions, respectively. Moreover, based on XRD, XPS and UV-DRS characterization, it can be deduced that tricobalt tetroxide located on the surface of the catalyst is the SR-Fenton active site, and cobalt ion implanted in the Ti O2 lattice is the reason for the visible light photocatalytic activity of Co–Ti O2. Finally, the effects of the calcination temperature and cobalt concentration on the synergistic performance were also investigated and a possible mechanism for the synergistic system was proposed. This coupled system exhibited excellent catalytic stability and reusability,and almost no dissolution of Co2+was found. 相似文献
123.
Jin Y. Fan Jin J. Geng Hong Q. Ren Xiao R. Wang Chao Han 《Journal of environmental science and health. Part. B》2013,48(10):844-850
Roundup® is a glyphosate-based herbicide containing a mixture of surfactants. This paper evaluates the toxic effects of Roundup® and its main constituents on the goldfish, Carassius auratus, after 7 days exposure. Fish were exposed to 0.16, 0.032 and 0.0064 mg/L of Roundup® [containing 41% isopropylamine salt of glyphosate (G.I.S) and 18% polyoxyethylene amine (POEA)], G.I.S, and POEA. Their livers were taken for determining reactive oxygen species (ROS), superoxide dismutase (SOD) activity, malondialdehye (MDA) content and acetylcholinesterase (AChE) activity. Hydroxyl radical (·OH) could be induced by exposing Roundup® at a rate of 43%–111%, G.I.S at 90%–124% and POEA at142%–157%. A decreased SOD activity was observed in fish exposed to G.I.S and POEA. The contents of MDA significantly increased when exposed to Roundup® at all concentrations, 0.16 mg/L G.I.S and 0.032 mg/L POEA. The exposure led to an inhibition of AChE in livers overall during the experimental periods. POEA was more toxic than Roundup® or G.I.S during this experiment. AChE and ·OH are supposed to be sensitive biomarkers of the exposure of Roundup® and its main constituents to C. auratus. 相似文献
124.
William Back Bruce B. Hanshaw 《Journal of the American Water Resources Association》1971,7(5):1008-1016
ABSTRACT. Interest in the geochemistry of groundwater is increasing owing to the great number of current projects involving underground liquid waste storage, artificial recharge of potable water, accidental contamination of groundwater bodies, sanitary landfills, and pollution monitoring. Geochemical techniques used to facilitate the understanding of a groundwater system range from extremely simple to those requiring sophisticated theories, equipment, and procedures. An interpretation of the simple trilinear diagram for samples collected from the Yucatan Peninsula of Mexico provided evidence that the fresh-water body was only a few tens of meters thick and was underlain everywhere by an extensive body of salt water. A geochemical technique that has been used effectively to identify the source of salt water in coastal aquifers is measurement of the carbon-14 concentrations. Carbon-14 has been used in a regional carbonate aquifer to determine the velocity of groundwater movement, rates of chemical reactions, and distribution of hydraulic conductivity. The application of principles of irreversible thermodynamics to groundwater systems provides a basis for constructing models which permit prediction, over both time and space, of changes in head distribution and chemical character of the water resulting from imposed stresses on the system. In essence, proper application of irreversible thermodynamics combines the potential theory of Hubbert with principles of reversible chemical thermodynamics, such as solution of carbonate minerals, to describe and explain controlling chemical reactions and processes of groundwater systems. 相似文献
125.
Aniline degradation by electrocatalytic oxidation 总被引:4,自引:0,他引:4
The degradation of aniline solution in alkaline medium of pH 11.0 by electrocatalytic oxidation has been studied using an electrochemical reactor containing a SnO2–Sb2O3–PtO anode and a Ti cathode, both of 54 cm2 area. Hydroxyl radicals (HO√) are produced at the anode, being tested with the trace catcher salicylic acid and phenol by spectrophotometery and high performance liquid chromatography. Intermediates dianiline, 4-anilino phenol and azobenzol were detected by gas chromatography–mass spectrometry. The existence of HO√ produced in the aniline degradation was assayed with scavenger tertiary butanol. The results showed that electrocatalytic oxidation is an effective process for the degradation of aniline. A general reaction pathway that accounts for aniline degradation to CO2 involving those intermediates is proposed. 相似文献
126.
J.C. Doornkamp 《Journal of environmental management》1998,52(4):327-333
A review of the difficulties associated with the definition of coastal flood frequencies and magnitudes leads to a recognition that there is considerable doubt in many parts of the world as to the precise nature of this particular hazard. Similarly, a review of the sea-level measurements that have been used to indicate a response to global warming shows that there is uncertainty about the amount of other controlling influences. What is clear, however, are that past management decisions about human endeavours in the coastal zone (including flood defences, occupance of flood-prone lands, extraction of ground water and natural gas) have had an impact on relative land and sea levels and have done more to increase the risk of coastal flooding than can be assigned so far to global warming. In addition, these changes induced by human activity may render inappropriate calculations of coastal-flood frequencies based on historical records since the latter relate to a period of time when the controls on flooding may have been very different. 相似文献
127.
128.
Jasbir Singh 《Journal of Loss Prevention in the Process Industries》1994,7(6):481-491
Exothermic runaway reactions that generate non-condensible gas as the temperature increases, as is typical of decompositions for example, can reach extremely high rates of pressure rise necessitating emergency relief of the process vessel containing the reactant. Sizing of a relief device using presently recommended methods (e.g. DIERS) frequently leads to extremely large and expensive vents. This paper presents a methodology that leads to a simple but much improved method for vent sizing, fully allowing for two-phase release of the gas—liquid mixture. A number of examples are presented which lead to interesting conclusions about the influence of plant variables. 相似文献
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130.