典型地区农用地污染调查及风险管控标准探讨

针对《土壤污染风险管控标准——农用地土壤污染风险管控标准》(GB 15618—2018),提出以土壤中全量浓度筛选值和管控值作为衡量农用地土壤污染风险管控的标准,对湖南省部分稻田农用地土壤及点对点稻米样品中镉、铅、砷、汞的总量和有效态浓度及稻米中含量进行监测,根据重金属总量浓度分为低风险、中风险、高风险3组。结果显示:(1)土壤及稻米中镉含量基本为随着风险级别的升高而增加,铅、砷在土壤和稻米中含量无规律性结果,汞监测结果均为未检出。(2)低风险组稻米镉超标率为12. 0%,高风险组稻米镉达标率为33. 3%,表明利用总量浓度对农用地土壤潜在风险进行分组存在一定的局限性。(3)依据4种重金属在土壤中总量及稻米(早稻)中含量情况,对风险级别进行调整并综合判断:有58个样品为低风险组,占样品总数的68. 2%,超标率为零;有15个样品为中风险组,占样品总数的17. 7%,超标率为80. 0%;有12个样品为高风险组,占样品总数的14. 1%,超标率为100. 0%。调整后评价结果与上述标准的划分目标更接近,能够提高上述标准的准确性和实用性。     

秸秆发酵产氢的影响因素研究

以加热预处理的厌氧活性污泥为接种物,以秸秆（稻草、麦杆）为发酵底物进行微生物产氢实验,研究了不同秸秆粒径、纤维素酶用量、预处理方法、发酵液pH值对秸秆发酵产氢速率以及产氢气量的影响.其中颗粒粒径为170 μm的稻草经过NaOH预处理,按照底物与纤维素酶用量1∶1的比例酶解,进而发酵产氢的单位总产氢量为90.5 mL/g,最大单位产氢速率为0.58 mL/(h·g).     

米糠生物质解毒含铬(Ⅵ)水溶液的研究

农林生物质是一种成本低、环境友好的重金属废水处理材料,也是受重金属污染环境的修复材料之一.实验讨论了初始pH值、米糠用量、吸附时间对含铬(Ⅵ)水溶液解毒的影响.结果表明,米糠对Cr(Ⅵ)存在吸附作用,同时也有解毒还原能力.100 mL浓度为100 mg/L的含铬溶液,在初始pH为2、米糠用量为3 g、吸附-反应平衡时间7 h的条件下,生物质吸附去除溶液中的铬为14.4%,而原溶液中Cr(Ⅵ)解毒了57.2%,米糠生物质吸附总铬的能力为0.48 mg Cr/g(生物质).米糠生物质有潜在的吸附铬和修复受铬污染环境的利用价值.     

Optimizing mixture properties of biodiesel production using genetic algorithm-based evolutionary support vector machine

Nowadays, biodiesel is used as one of the alternative renewable energy due to the increasing energy demand. However, optimum production of biodiesel still requires a huge number of expensive and time-consuming laboratory tests. To address the problem, this research develops a novel Genetic Algorithm-based Evolutionary Support Vector Machine (GA-ESIM). The GA-ESIM is an Artificial Intelligence (AI)-based tool that combines K-means Chaotic Genetic Algorithm (KCGA) and Evolutionary Support Vector Machine Inference Model (ESIM). The ESIM is utilized as a supervised learning technique to establish a highly accurate prediction model between the input--output of biodiesel mixture properties; and the KCGA is used to perform the simulation to obtain the optimum mixture properties based on the prediction model. A real biodiesel experimental data is provided to validate the GA-ESIM performance. Our simulation results demonstrate that the GA-ESIM establishes a prediction model with better accuracy than other AI-based tool and thus obtains the mixture properties with the biodiesel yield of 99.9%, higher than the best experimental data record, 97.4%.     

未来30a凉山州水稻盛夏低温危害风险分析

根据(BCC)气候系统模式第五阶段试验计划(CMIP5-RCP6.0)预测的2006~2050年各格点逐日平均温度,通过订正反演出2021~2050年凉山州各站点逐日平均温度,结合凉山州不同区域水稻抽穗杨花期低温指标,统计了各站水稻盛夏低温频次、水稻安全播种期、安全齐穗期以及安全生长季差,构建了水稻盛夏低温危害风险指数I=exp(Id+ip-2),并以此进行低温危害风险的区域划分,结果表明:(1)凉山州水稻盛夏低温频次为0.1~3.0次/a,在区域和年际之间差异很大;(2)与近30a比较,凉山州水稻安全播种期普遍提前10 d左右,提前最多的达20 d以上。安全齐穗期只有少数站点推迟,大多数站点都有提前的趋势;(3)海拔1 500 m以下为无风险区,1 500~2 000 m的区域为低风险区,2 000~2 500 m为中风险区,2 500~2 600 m为高风险区,分区结果与实际情况相符,为凉山州未来水稻生产布局、应对气候变化的影响提供科学依据。     

铬渣的热解无害化处理

采用热解工艺无害化处理铬渣,探讨了稻秆在铬渣无害化处理中的作用.研究了热解温度、稻秆与铬渣质量比、铬渣粒径及保温时间对铬渣热解无害化处理的影响,并分析了热解前后热解产物中铬元素形态的变化.结果表明,热解工艺能有效地将铬渣中Cr(Ⅵ)还原,稻秆热解过程中产生的气相挥发分对Cr(Ⅵ)的还原起核心作用.较为适宜的热解条件:热解温度为400 ℃,稻秆与铬渣质量比为0.10,铬渣粒径<2 000 μm,保温时间为10 min.在该热解条件处理下,热解产物中的Cr(Ⅵ)质量浓度为121 mg/kg,低于热解前铬渣中的Cr(Ⅵ)(3 400 mg/kg).热解后,可交换态及碳酸盐结合态铬含量降低,大部分铬转化成了稳定的有机结合态和残渣态,极大地降低了铬渣的危害.第一作者:张大磊,男,1982生,博士研究生,研究方向为固体废弃物热处理.     

抽穗期低温对杂交晚粳宁67A／K1722结实率的影响

利用人工气候箱研究了抽穗期低温对杂交晚粳新组合宁67A/K1722开花量、包颈率及结实率的影响。结果表明：低温使抽穗速度明显变慢,开花量减少,包颈率呈现上升趋势,不同温度处理对结实率的影响不同,17℃与21℃处理间差异极显著,而19℃与21℃间差异不显著,不同时期处理及不同处理天数（3d,5d,7d和12d）间结实率差异不显著,表明该组合对抽穗期低温的耐受力较强,对抽穗期耐低温的鉴定指标问题进行了讨论。     

延边地区水稻稳产高产施肥体系的探讨

采用二次饱和D-最优设计,建立了有机肥、氮肥、磷肥和钾肥配合施用对水稻产量影响的数学模型.研究表明有机肥施用量的过多或过少均使水稻产量下降,化肥的施用也有相似的影响;有机肥与氮肥、磷肥、钾肥只有施用量在适宜的范围内,交互作用较大,产量最高.提出了延边地区水稻获得稳产、高产的施肥体系.     

秸秆腐解剂在秸秆还田中的效果研究初报

在大田、微区和盆栽条件下,研究了秸秆腐解剂对小麦、水稻生长及产量的影响,同时研究了秸秆腐解剂对小麦、水稻秸秆腐解速率及对土壤肥力的影响。结果表明,稻、麦秸秆还田时施用秸秆腐解剂对提高稻、麦产量具有明显的增产效果,增产的原因是穗数和粒数增加;稻、麦秸秆还田量不同时,还田量大且配施秸秆腐解剂的效果较还田量小好;麦秸秆还田方式不同时,麦秸以栽稻前耕翻还田且配施秸秆腐解剂的效果较好,上水沤制的效果较差;秸秆腐解剂能促进稻、麦秸秆较快腐解,减轻和防止多量秸秆还田给作物生长带来不利影响,并可稳定和提高土壤养分含量。     

Diversity of antibiotic resistance genes and encoding ribosomal protection proteins gene in livestock waste polluted environment

The rapid development and increase of antibiotic resistance are global phenomena resulting from the extensive use of antibiotics in human clinics and animal feeding operations. Antibiotics can promote the occurrence of antibiotic resistance genes (ARGs), which can be transferred horizontally to humans and animals through water and the food chain. In this study, the presence and abundance of ARGs in livestock waste was monitored by quantitative PCR. A diverse set of bacteria and tetracycline resistance genes encoding ribosomal protection proteins (RPPs) from three livestock farms and a river were analyzed through denaturing gradient gel electrophoresis (DGGE). The abundance of sul(I) was 10³ to 10⁵ orders of magnitude higher than that of sul(II). Among 11 tet-ARGs, the most abundant was tet(O). The results regarding bacterial diversity indicated that the presence of antibiotics might have an evident impact on bacterial diversity at every site, particularly at the investigated swine producer. The effect of livestock waste on the bacterial diversity of soil was stronger than that of water. Furthermore, a sequencing analysis showed that tet(M) exhibited two genotypes, while the other RPPs-encoding genes exhibited at least three genotypes. This study showed that various ARGs and RPPs-encoding genes are particularly widespread among livestock.