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151.
基于PMF模型的九龙江流域农田土壤重金属来源解析 总被引:18,自引:11,他引:7
选取九龙江流域农田土壤为研究对象,运用电感耦合等离子体质谱(ICP-MS)和原子荧光光谱(AFS)测定了土壤中重金属含量,通过正定矩阵因子分析模型(PMF)解析农田土壤中重金属的主要来源.结果表明,研究区域农田土壤中大部分金属相对福建省土壤环境背景值已存在一定程度的富集,部分土壤中Cd、Zn、Pb和Cu含量超过农用地土壤污染风险筛选值(GB15618-2018),且各金属在研究区不同区域(北溪流域、西溪流域和河口区)分布存在中等变异.Cr、Ni、Cu、Zn和Cd的含量在北溪流域的龙岩区域较高,Pb的含量在西溪流域较高,而Co、Hg和As的含量在河口区域较高.正定矩阵因子分析模型(PMF)得出的源成分谱和源贡献率具有非负性质,土壤中重金属实测值与模型预测值拟合曲线呈现较好相关性,结果相对合理,能满足研究需要.正定矩阵因子分析模型(PMF)解析得出:研究区农田土壤中重金属主要来源有自然源、农业活动、燃煤释放和工业活动,其对农田土壤中重金属的综合贡献率分别为37. 0%、26. 7%、17. 6%和18. 7%. 相似文献
152.
A. M. Rusanov 《Russian Journal of Ecology》2007,38(1):11-15
The influence of the Buzuluk Pine Forest on biodiversity of plants and soil properties in adjacent territories has been studied. The results show that in the immediate vicinity of the pine forest, under the influence of the relatively mild and humid mesoclimate, natural phytocenoses are dominated by mesophytic species. Biodiversity reaches a peak at a distance of 17–18 km from the forest, which is explained by the presence of both mesophytes and xerophytes in the same phytocenosis. The same zone is also characterized by the maximum diversity of soil properties and structural complexity of the soil cover. Grass communities on ordinary chernozems with a homogeneous soil cover, typical of the steppe zone, are formed at greater distances from the forest. 相似文献
153.
154.
I. V. Shtangeeva 《Chemistry and Ecology》1995,11(2):85-95
Neutron activation analysis was used for the determination of the elemental composition of different plants and soils. Variations in concentrations of elements during the day were found. Mean concentrations, standard deviations and relationships between elements in soils and different parts of plants were studied. It was shown that the behaviour of chemical elements in samples from urban and unpolluted areas have significant differences. 相似文献
155.
The organic fraction of a municipal solid waste was added in different doses to an eroded soil formed of loam and with no
vegetal cover. After three years, the changes in macronutrient content and the chemical-structural composition of its organic
matter were studied. The addition of the organic fraction from a municipal solid waste had a positive effect on soil regeneration,
the treated soils being covered with spontaneous vegetation from 1 yr onwards. An increase in electrical conductivity and
a fall in pH were noted in the treated soils as were increases in macronutrients, particularly N and available P and the different
carbon fractions. Optical density measurements of the organic matter extracted with sodium pyrophosphate showed that the treated
soils contained an organic matter with less condensed compounds and with a greater tendency to evolve than the control. A
pyrolysis-gas chromatography study of the organic matter extracted with pyrophosphate showed large quantities of benzene both
in the treated soils and control; pyrrole was also relatively abundant, although this fragment decreased as the dose rose.
Xylenes and pyridine were present in greater quantities in the control and furfural in the treated soils. Three years after
addition to the soil, the organic matter had a higher proportion of fragments derived from aromatic compounds and a smaller
proportion derived from hydrocarbons. Similarity indices showed that, although the added and newly formed organic matter 3
yr after addition continued to differ from that of the original soil and to be more mineralizable, the transformations it
has undergone made it more similar to the original organic matter of the soil than it was at the moment of being added. 相似文献
156.
Suvi Monni Paula Perälä Kristiina Regina 《Mitigation and Adaptation Strategies for Global Change》2007,12(4):545-571
According to the United Nations Framework Convention on Climate Change (UNFCCC) and Kyoto Protocol under it, industrial countries
have to estimate their greenhouse gas emissions annually, and assess the uncertainties in these estimates. In Finland, agricultural
methane (CH4) and nitrous oxide (N2O) emissions represent 7% of anthropogenic greenhouse gas emissions, and globally the share is much higher. Agriculture is
one of the most uncertain emission categories (representing over 20% of greenhouse gas inventory uncertainty in Finland),
due to both high natural variability of the emission sources and poor knowledge of the emission-generating processes. In this
paper, we present an uncertainty estimate of agricultural CH4 and N2O emissions from Finland in 2002. Uncertainties were estimated based on measurement data, literature and expert judgement,
and total uncertainty in agriculture was calculated using Monte Carlo simulation. According to the calculations, agricultural
CH4 and N2O emissions from Finland were 3.7 to 7.8 Tg carbon dioxide (CO2) equivalents, 5.4 Tg being the mean value.Estimates of CH4 emissions are more reliable than those of N2O. N2O from agricultural soils was the most uncertain emission category, and the uncertainty was not reduced by using available
national measurement data of N2O fluxes. Sensitivity study revealed that the uncertainty in total agricultural inventory could be 7% points lower, if more
accurate emission estimation methods were used, including 1) improved data collection in area estimates of organic soils,
2) climate-specific methods for N2O from agricultural soils as already presented in literature, and 3) more detailed CH4 estimation methods for enteric fermentation which can be achieved by investigating national circumstances and digestible
systems of animals in more detail. 相似文献
157.
Assessment of labile phosphorus fractions and adsorption characteristics in relation to soil properties of West African savanna soils 总被引:2,自引:0,他引:2
O. C. Nwoke B. Vanlauwe J. Diels N. Sanginga O. Osonubi R. Merckx 《Agriculture, ecosystems & environment》2003,100(2-3):285
A large proportion of total P in the soils of the area is unavailable to plants and consequently P is the second most limiting nutrient. The labile and moderately labile phosphorus fractions and adsorption characteristics of surface and subsurface horizons of eleven soil profiles in the derived savanna (DS) and the northern Guinea savanna (NGS) of West Africa were assessed. The labile P fractions are the resin and HCO3-extractable inorganic (Pi) and organic (Po) P. The moderately labile fractions are the NaOH-extractable portion of soil P in the Hedley sequential procedure. In the DS soils, the resin P, considered the most readily available fraction, varied from 1 to 14 mg kg−1, HCO3-Pi ranged from 3.3 to 11, and HCO3-PO was between 4 and 12 mg kg−1 in the surface horizon. In the NGS, the topsoil contained 1.5–3 mg kg−1 of resin P, 5–8 mg kg−1 of HCO3-Pi, and 7.5–9.7 mg kg−1 of HCO3-Po. Sodium hydroxide-Po was the largest of the fractions in all the soils studied. It ranged from 23 to 55 mg kg−1 in the topsoil. In general, the labile P levels were higher in soils of the DS than of the NGS and were related to the oxalate-extractable Fe (Feox), and Al (Alox) as well as to soil texture. The subsoil of Kasuwan Magani (profile KS 9–21 cm) required 153 mg P kg−1 to maintain 0.2 mg P l−1 in solution (standard P requirement), and Danayamaka (profile DD 7–32 cm) required 145 mg P kg−1. These could translate to 214 and 200 kg P ha−1 if a plow layer of 10 cm is assumed. Because these are within the plow layer, more P fertilizer would be needed for crop production than in the other soils. The standard P requirement and the adsorption maxima were related to Feox and Alox, dithionite-Fe (Fed), and texture. The increase in labile P content with decreasing Feox and Alox could imply that management practices capable of reducing the activities of Fe and Al in solution might improve P availability. 相似文献
158.
159.
水稻土施用城市污泥盆栽通菜土壤中邻苯二甲酸酯(PAEs)的残留 总被引:13,自引:0,他引:13
应用GC/MS联机检测技术对水稻土施用城市污泥盆栽通菜(Ipomoea aquatic)后土壤中6种邻苯二甲酸酯化合物(PAEs)进行分析.结果表明,盆载通菜土壤中6种PAEs的总含量(∑PAEs)在7.667-40.025 mg/kg之间,平均为26.137 mg/kg,其高低次序为佛山污泥>广州污泥>佛山污泥加化肥>广州污泥+化肥>空白>化肥.与空白对照相比,施用污泥和污泥+化肥处理的土壤中∑PAEs含量显著提高,但单施化肥的土壤中∑PAEs含量降低.不同处理土壤中的PAEs化合物是以一种或两种化合物为主,主要是DnBP和/或DEHP,显示了不同的PAEs分布特征. 相似文献
160.