Chemical oxidation of sulfadiazine by the Fenton process: Kinetics,pathways, toxicity evaluation

This paper investigated sulfadiazine oxidation by the Fenton process under various reaction conditions. The reaction conditions tested in the experiments included the initial pH value of reaction solutions, and the dosages of ferrous ions and hydrogen peroxide. Under the reaction conditions with pH 3, 0.25 mM of ferrous ion and 2 mM of hydrogen peroxide, a removal efficiency of nearly 100% was achieved for sulfadiazine. A series of intermediate products including 4-OH-sulfadiazine/or 5-OH-sulfadiazine, 2-aminopyrimidine, sulfanilamide, formic acid, and oxalic acid were identified. Based on these products, the possible oxidation pathway of sulfadiazine by Fenton's reagent was proposed. The toxicity evaluation of reaction solutions showed increased antimicrobial effects following the Fenton oxidation process. The results from this study suggest that the Fenton oxidation process could remove sulfadiazine, but also increase solution toxicity due to the presence of more toxic products.     

Appendix

Abstract

An atrazine‐degrading bacterial isolate (M91–3) was able to utilize simazine and cyanazine as N sources for glucose‐dependent growth. The degradation of these three 5‐triazine herbicides was also investigated in binary and ternary mixtures. The organism used atrazine and simazine indiscriminately, whereas cyanazine degradation was slow and delayed until the depletion of the two other herbicides. There was no apparent effect of other commonly used herbicides on the rate of atrazine degradation by M91–3.     

Sorption Kinetics of Atrazine and Diuron in Soils from Southern Brazil

Abstract

Sorption kinetics of atrazine and diuron was evaluated in soil samples from a typical landscape in Paraná. Samples were collected (0–20 cm) in a no-tillage area from Mamborê, PR, which has been cultivated under a crop rotation for the last six years. Six sampling points of the slope were selected to represent a wide range of soil chemical and physical properties found in this area. Radiolabeled tracers (¹⁴C-atrazine and ¹⁴C-diuron) were used and the radioactivity was detected by liquid scintillation counting (LSC). Sorption was accomplished for increasing equilibration periods (0.5, 1.5, 3, 6, 12, 24, and 48 h). Kinetics data fitted adequately well to Elovich equation, providing evidences that soil reaction occurs in two distinct stages: a fast, initial one followed by a slower one. During the fast phase, 34–42 and 71–79% of total atrazine and diuron applied were sorbed to soil samples. No important differences were found among combinations of soil and herbicide sorption during the slow phase. The unrealistic conditions under batch experiments should be overestimating sorption in the fast phase and underestimating diffusion in the slow phase. Sorption of both herbicides was positively correlated to organic carbon and clay contents of soils, but atrazine was much less sorbed than diuron, showing its higher potential to contaminate groundwater, specially in sandy, low organic carbon soils.     

Green manure plants for remediation of soils polluted by metals and metalloids: Ecotoxicity and human bioavailability assessment

Borage, white mustard and phacelia, green manure plants currently used in agriculture to improve soil properties were cultivated for 10 wk on various polluted soils with metal(loid) concentrations representative of urban brownfields or polluted kitchen gardens. Metal(loid) bioavailability and ecotoxicity were measured in relation to soil characteristics before and after treatment. All the plants efficiently grow on the various polluted soils. But borage and mustard only are able to modify the soil characteristics and metal(loid) impact: soil respiration increased while ecotoxicity, bioaccessible lead and total metal(loid) quantities in soils can be decreased respectively by phytostabilization and phytoextraction mechanisms. These two plants could therefore be used for urban polluted soil refunctionalization. However, plant efficiency to improve soil quality strongly depends on soil characteristics.     

环境空气中VOC s 的监测技术新进展

大气中的挥发性有机物(VOCs)严重威胁着人类的健康,目前对它的监测技术的研究越来越多.文章综述了近年来国内外在VOCs的采样及测试技术上的进展,重点介绍了固相微萃取、罐取样、吸附法等采样技术以及以气相色谱法为主的分析方法,并对一些非色谱法的分析技术进行了简单介绍.     

INFLUENCE OF SMALL MAMMALS ON STORMFLOW RESPONSES OF PINE-COVERED CATCHMENTS1

ABSTRACT: The relative abundance of small mammals in five forest land cover types on the upper Coastal Plain of north Mississippi was determined. Burrowing mammals accounted for one-half of the total captures; one shrew species that accounted for over one-fourth of the total captures had a strong affinity for well-stocked pine plantations. The opportunity for detention and retention of rainfall was enhanced by burrowing activity. Reductions of stormflow volumes 12 to 15 years after replacing poor quality, upland hardwoods with loblolly pine were only partially explained by increased interception of rainfall; much of the residual reductions are postulated to be due to small mammal burrows. Small mammal activity deserves further study as an important aspect of forest land hydrology.     

A TAU-LIKE TEST FOR TREND IN THE PRESENCE OF MULTIPLE CENSORING POINTS1

ABSTRACT: A common problem arises in testing for trends in water quality when observations are reported as “less than detection limit.” If a single detection limit is used for the entire study, existing non-parametric statistical methods, modified for ties, are applicable. If, however, the detection limit varies during the course of the study, resulting in multiple detection limits, then the commonly used trend detection methods are not appropriate. A statistic similar to Kendall's tau, but based on expected ranks, is proposed. Monte Carlo simulations show that the normal approximation to the distribution of this statistic is quite good, even for small samples and a large proportion of censored observations. The statistic is also shown to have greater power than the ad-hoc method of treating all observations less than the target censored observation as tied.     

AN APPLICATION OF INVESTMENT TIMING ANALYSIS: DUAL WATER SYSTEMS1

ABSTRACT: A general methodology to study the economics of dual water systems (defined here as a separate distribution system for untreated low quality local surface Water for outdoor municipal water supply) is summarized and the application of the method to a rapidly growing city is presented. In the first step, a cost-benefit criterion for evaluating dual systems is developed. The criterion is then extended to a dynamic case where the population to be served increases with time and where the dual system is allowed to expand. The optimal investment time to introduce the dual water supply project is obtained by maximizing social welfare. The model is applied to the city of West Jordan, Utah, where a dual system is currently being proposed. Model results indicate that for the city as a whole dual supply is not economically feasible. However, when the model is applied to a part of the city, it is found feasible and the optimal time to initiate the project would be in the year 1989.     

CHANGES IN WATER POLICY IN THE PEOPLE'S REPUBLIC OF CHINA1

ABSTRACT: Ideology has predisposed the People's Republic of China against the use of prices to allocate water. Prolonged drought in north China has made the Chinese more aware of their unfavorable water resource inventory and the expense of expanding supply. Therefore, as part of the economic liberalization commenced since the death of Mao Zedong, China has started to make more active use of pricing to regulate demand and reduce the need for supply expansion.     

碳中和愿景下电力部门低碳转型路径研究

碳中和愿景一方面加速了全社会电气化发展,致使电力需求持续增加,另一方面对尽早实现零碳电力提出要求,电力部门低碳转型进程更加紧迫而复杂。本文首先定性分析碳中和背景下电力部门的总体转型思路和技术不确定性影响,其次采用电力部门与终端部门耦合的C~3IAM/NET模型对电力需求进行预测,同时根据关键低碳技术发展的保守预期和积极预期设计多种情景,以开展电力低碳转型路径优化和成本效益研究。结果显示,发电碳排放量峰值可能出现在40亿～42亿吨,在2049—2060年有望实现零碳电力,电力部门低碳转型速度和效果因技术不确定性而存在明显差异。2021—2060年电力低碳转型累计投入为171万亿～180万亿元,CCS技术累计减排贡献超过250亿吨,可再生能源电力占比需达到68%以上,风电和光电将成为主要电力。