催化臭氧氧化对生化尾水中典型有机物的去除特性

系统深入地分析了Fe-Ce/AC催化臭氧氧化对化工园区污水厂生化尾水中典型有机物的去除特性。与单独臭氧氧化相比,催化臭氧氧化可将TOC去除率从7.89%大幅提升至17.54%。120 min时UV_(254)和特征紫外吸光度(SUVA)的去除率分别高达66.80%和59.73%,证明了催化臭氧氧化可有效去除含共轭结构或芳环结构的不饱和有机物。催化臭氧氧化对生化尾水中腐殖酸类(HA)、溶解性微生物产物类(SMP)和疏水性腐殖酸类(HOA)3种荧光组分的去除过程均符合一级动力学模型,且由一级动力学速率常数可知,与生化尾水色度直接相关的HA和HOA被优先去除。40 min时HA、SMP和HOA的去除率即高达95.24%、93.21%和92.96%。     

成都市夏季大气挥发性有机物污染及其对二次有机气溶胶生成的贡献

于2014年7月8日至8月13日在成都市城区和工业区选取两个点位开展挥发性有机物(VOCs)样品采集工作,分析结果显示,成都市夏季城区大气中VOCs质量浓度在34.1~458.8μg/m3,平均值为(137.3±91.8)μg/m3;工业区大气中VOCs质量浓度在26.7~474.9μg/m3,平均值为(135.9±103.5)μg/m3。早高峰时段(7:00~10:00)两个点位VOCs的浓度水平均高于其他时段,说明VOCs浓度受机动车排放的影响较为明显。用·OH消耗速率和臭氧生成潜势评估VOCs大气化学反应活性,结果显示,芳香烃和烯烃是影响大气化学反应活性的关键组分。城区和工业区的二次有机气溶胶(SOA)的生成潜势分别为4.859、4.559μg/m3,芳香烃不仅是臭氧生成潜势的关键活性组分,同时也是SOA的重要前体物。     

Diquat associated with copper sources for algae control: Efficacy and ecotoxicology

The aims of this research were to evaluate the efficacy of copper oxychloride (CuCl₂.3Cu(OH)₂), copper hydroxide (Cu(OH)₂) and diquat (1.1′-ethylene-2.2′-bipyridyldiylium dibromide), isolated and in association with 0.1% of both copper sources, in the control of the unicellular algae Ankistrodesmus gracilis and the filamentous algae Pithophora kewesis, and to determine the acute toxicity of the tested chemicals in Hyphressobrycon eques, Pomacea canaliculata, Lemna minor and Azolla caroliniana. The efficacy was estimated by the methods of chlorophyll a and pheophytin a readings, changed into growth inhibition percentage. Both algae were exposed to the following concentrations: 0.2; 0.4; 0.8; 1.2 mg L^?1 of diquat and its association with the copper sources; and 0.1; 0.3; 0.5; 0.7; 1.0 and 1.5 mg L^?1 in the isolated applications of copper hydroxide and copper oxychloride. An untreated control was kept. The acute toxicity was estimatedby 50% lethal concentration (LC50). The copper sources were effective for A. gracilis control, at rates as high as 0.1 mg L^?1 (>95% efficacy). Isolated diquat and its association with copper hydroxide were both effective at rates as high as 0.4 mg L^?1, with 95 and 88% control efficacy, respectively. The copper oxychloride was effective at 0.2 mg L^?1, with 93% efficacy. None of the tested chemicals and associations was effective on P. kewesis control. The most sensitive non target organism to the tested chemicals was L. minor; the less sensitive was H. eques.     

生态文明的内涵及其现实意义

生态文明的定义有狭义与广义之分,不加区分乱用势必会造成逻辑混乱。作为广义意义上的生态文明,作为一种崭新的文明形态,其内涵至少要从自然观、价值观、生产方式、生活方式这四个方面来把握。党的十七大首次明确提出建设生态文明的战略要求,标志着中国共产党对中国特色社会主义建设规律认识的深化,是中国特色社会主义理论体系的又一重大创新成果,它对于我国走出生态困境、构建社会主义和谐社会、落实科学发展观具有现实意义。     

接触氧化法深度去除二级出水中氨氮的研究

采用生物接触氧化法对生活污水处理厂出水进行深度处理,探讨了水力停留时间、温度及pH值等因素对氨氮去除效果的影响。结果表明：水力停留时间1．5h时,污水厂出水经过处理后氨氮的浓度小于5mg／L,去除率达到82％以上,出水符合国家生活杂用水水质标准(CJ25,1-89)。     

老填埋场竖向加高扩容工程的沉降计算与分析

针对老填埋场竖向加高扩容时垃圾堆体沉降机理的特殊性,将老垃圾堆体的沉降分为3部分:主固结沉降、次应力沉降、降解沉降,并研究各部分沉降的计算方法。结合工程实例,对沉降计算公式中有关参数取值进行探讨,并对扩容垃圾荷载作用下原垃圾堆体的沉降发展趋势进行分析,为扩容工程设计采取相应的沉降控制措施提供了依据。     

传染病医院建筑给排水设计初探

本文针对传染病医院建筑给排水的设计进行研究.从实例出发,分析了传染病院的功能特点及不同类型传染病所采取的措施要点,从有利于洁净及防止二次污染、污水处理及消防给水设计等几个方面提出自己的看法及相应的技术措施.     

Characterization of carbonaceous species in PM2.5 in Xi'an during spring

The characterization of carbonaceous species in PM_2.5 during a spring period in a suburb of Xi'an, China was investigated. PM_2.5 samples were collected on quartz filters and analyzed for organic carbon (OC) and elemental carbon (EC). The thermal optical reflectance method was used. The minimum OC/EC ratio method was used to estimate the concentration of secondary organic carbon (SOC). The distribution of eight carbon fractions was investigated as well. The average mass concentrations of OC and EC were 15.90 and 8.38 μg/m³, respectively. The average OC/EC ratio ranged from 1.16 to 3.16 with an average value of 2.25. This implies the existence of SOC in PM_2.5. The mean SOC concentration was 7.20 μg/m³, accounting for 45.28% of total OC. This result suggests that SOC is a significant component of OC in the suburb of Xi'an. Results from the distribution of eight carbon fractions revealed that emissions from motor vehicle, coal combustion, and road dust were the main source of carbonaceous particles in the sampling period.     

杭州市大气VOCs浓度特征及其化学活性研究

2018年4月至2019年3月对杭州市城区大气中117种挥发性有机物（VOCs）开展了为期一年的手工采样观测,分析了VOCs各组分的浓度特征、臭氧生成潜势（OFP）和二次有机气溶胶（SOA）生成潜势。结果显示,观测期杭州市大气VOCs体积分数均值为（56.72±29.56）×10^-9,含氧挥发性有机物（OVOCs）、烷烃和卤代烃是其主要组分,分别占33.86%、30.70%、15.73%。VOCs体积分数前10位的物种为丙烷、甲醛、异丁烷、乙烷、乙酸乙酯、二氯甲烷、正丁烷、丙酮、甲苯和1,2-二氯乙烷。杭州市VOCs的OFP为135.18×10^-9,各VOCs组分的OFP贡献为OVOCs（45%） > 芳香烃（22%） > 烯烃和炔烃（21%） > 烷烃（11%） > 卤代烃（1%）,其中甲醛、乙烯和乙醛是OFP主要贡献者。SOA生成潜势为1.64 μg/m³,芳香烃是最重要的SOA前体物。SOA生成潜势最大的5种VOCs物种为甲苯、对/间二甲苯、乙苯、邻二甲苯和苯,因此控制来自机动车尾气和溶剂使用过程中产生的VOCs可有效降低SOA的生成。通过甲苯与苯体积分数比分析发现,杭州市城区芳香烃除了来自机动车尾气以外,在春、夏季和秋、冬季还分别受到生物质燃烧和涂料溶剂的影响;分析了乙烷与乙炔体积分数比、乙炔与CO体积分数比,发现杭州市气团的老化程度呈现整体较高的特点。     

多米诺效应定量风险分析

根据多米诺效应的特点,提出了针对多米诺场景和效应后果的定量风险分析方法.首先辨识多米诺效应的事故场景,针对场景的复杂性和事故后果的严重性,运用数学模型和概率分析手段对主要事故场景进行分析; 其次根据初始事故的影响,运用设备损坏概率模型计算二次目标设备的损坏概率和场景的后果; 最后,运用人体脆弱性模型对效应后果进行分析,量化多米诺效应的风险,结合风险分析方法和理论得到直观的个人风险和F-N社会风险曲线.多米诺分析流程及计算的结果表明,多米诺效应对个人风险和社会风险都造成了显著的变化,加强多米诺效应分析有利于工厂规划布局和安全管理.