管式反应器石灰雾液脱硫的数学模拟

建立的一维管式反应器雾液脱硫模型是对蒸发和吸收过程的耦合，以膜理论为基础的吸收机理同时考虑了含硫组分的离解、扩散、反应和固体颗粒的溶解。参数敏感性分析表明，对系统脱硫率影响最显的是出口干湿球温差，石灰颗粒粒度和入口ＳＯ２浓度、传质过程的分析表明，反应开始阶段液膜扩散和固体溶解阻力均存在，而气膜扩散在整个反应过程中都起着重要作用。     

喀喇昆仑-昆仑山昆虫区系

喀喇昆仑-昆仑山昆虫区系属于典型的古北区性质,古北种占53.93％,中亚成分占16.85％,北坡受中亚成分影响大,南坡占有多数的高山成分。这一地域昆虫区系的形成和演替与其地质历史密切相关。由于印度板块不断向北挤压,喀喇昆仑-昆仑山强烈抬升,随着塔里木盆地的形成,地域性的昆虫区系便产生了,并有其特有成分的分化:亚种级的分化,种级的分化甚至属级的分化     

基于3S的玉溪市土壤侵蚀敏感性评价研究

以玉溪市为研究区域，运用GIS软件对影响土壤侵蚀的因子进行叠加分析，获取玉溪市土壤侵蚀敏感性等级分布图，并与土壤侵蚀现状图加以对比，结果显示：发生土壤侵蚀的地区一定是土壤侵蚀的敏感地区，但土壤侵蚀的敏感地区不一定发生土壤侵蚀：森林覆盖量、质量和人为活动是影响土壤侵蚀的主要原因。     

活性氧的化学发光测定法

以作者近年来的研究结果为中心 ,综合地介绍过氧化氢 (H2 O2 )、单线态氧 ( 1O2 )、超氧阴离子自由基 ( .O-2 )以及羟自由基 ( .OH)等活性氧化学发光研究的最新动态 .侧重介绍活性氧的鲁米诺、光泽精、甲壳动物荧光素化学发光测定体系 ,比较了这几种方法的各自特点和应用情况     

Insights into reactive oxygen species formation induced by water-soluble organic compounds and transition metals using spectroscopic method

Ambient particulate matter (PM) can cause adverse health effects via their ability to produce Reactive Oxygen Species (ROS). Water-Soluble Organic Compounds (WSOCs), a complex mixture of organic compounds which usually coexist with Transition Metals (TMs) in PM, have been found to contribute to ROS formation. However, the interaction between WSOCs and TMs and its effect on ROS generation are still unknown. In this study, we examined the ROS concentrations of V, Zn, Suwannee River Fulvic Acid (SRFA), Suwannee River Humic Acid (SRHA) and the mixtures of V/Zn and SRFA/SRHA by using a cell-free 2′,7′-Dichlorodihydrofluorescein (DCFH) assay. The results showed that V or Zn synergistically promoted ROS generated by SRFA, but had an antagonistic effect on ROS generated by SRHA. Fluorescence quenching experiments indicated that V and Zn were more prone to form stable complexes with aromatic humic acid-like component (C1) and fulvic acid-like component (C3) in SRFA and SRHA. Results suggested that the underlying mechanism involving the fulvic acid-like component in SRFA more tending to complex with TMs to facilitate ROS generation through π electron transfer. Our work showed that the complexing ability and complexing stability of atmospheric PM organics with metals could significantly affect ROS generation. It is recommended that the research deploying multiple analytical methods to quantify the impact of PM components on public health and environment is needed in the future.     

上海白龙港排污口附近潮滩沉积物中重金属总量及其化学形态分析

利用Tessier分级提取法依次提取了上海白龙港排污口附近潮滩沉积物中几种重金属元素的化学形态 ,结果表明 :Cu、Pb、Fe、Zn、Cr在沉积物中均以残渣态为主 ,Mn以碳酸盐结合态为主 ,占到总量的 5 0 %左右 ;秋季碳酸盐结合态重金属向铁锰氧化物结合态发生形态迁移与转化 ,在低潮滩沉积物中 ,碳酸盐结合态重金属发生分解以后 ,一部分向上覆水发生了迁移和扩散 ;Cu、Pb、Fe、Mn重金属元素之间具有良好的相关性 ,Zn、Cr在沉积物中也表现出相似的化学行为。     

Degradation of Populus euphratica community in the lower reaches of the Tarim River, Xinjiang, China

IntroductionRiparian systems are aquatic-terrestrial ecotones withunique biotic , biophysical and landscape characteristics(Gregory, 1991 ; Naiman, 1997 ; Wiens , 2002) and areshaped by fluvial geomorphic processes . Riparian plantcommunities perform an i…     

Human appropriation of net primary production as determinant of avifauna diversity in Austria

The relationship between land-use induced changes in production ecology and avifauna diversity was analysed using a GIS land cover dataset on a 0.25 km × 0.25 km grid covering Austria's national territory. Considering only aboveground processes, the “human appropriation of net primary production” (HANPP = potential NPP − NPP_t), actual NPP (NPP_act), harvest (NPP_h) and NPP_t (= NPP_act − harvest) were recalculated based on existing datasets. Elevation as well as indicators of land cover heterogeneity and landscape heterogeneity were also considered. Correlation analyses were performed between these potential determinants of avifauna diversity and breeding bird species richness data as well as the percentage of endangered breeding birds included in the Austrian red list. Four spatial scales—0.25 km × 0.25 km, 1 km × 1 km, 4 km × 4 km and 16 × 16 km, were analysed. It was shown that breeding bird species richness was more strongly correlated with production ecological indicators and elevation than with heterogeneity indicators. A residual analysis in which the effect of elevation (a proxy for climate) on species richness and its potential determinants was removed confirmed the importance of the availability of trophic energy (NPP) for bird diversity patterns. The results support the species-energy hypothesis, thus confirming the notion that HANPP could be a useful pressure indicator for biodiversity loss.     

Adsorption performance of CMK-3 and C-FDU-15 in NO removal at low temperature

CMK-3 and C-FDU-15 samples were synthesized using hard-templating and evaporationinduced self-assembly(EISA) methods,respectively.The pore structures of CMK-3 and CFDU-15 as well as commercial activated carbon were characterized by means of X-ray diffraction,field emission scanning electron microscopy,transmission electron microscopy,and N_2 adsorption–desorption.Adsorption of NO was investigated by means of thermogravimetric analysis,temperature-programmed desorption of NO + O_2,and in situ diffuse reflectance Fourier transform infrared spectroscopy.The results show that the CMK-3 and C-FDU-15 materials possessed ordered and uniform structures.The coadsorption capacity of NO and O_2 decreased in the sequence CMK-3(88.6 mg/g) C-FDU-15(71.7 mg/g) AC(25.3 mg/g).There were two main adsorption species on CMK-3 and CFDU-15:nitrite and nitrate.Nitrite is converted to nitrate easily.However,the adsorption species were more complex on AC,with nitrite being the main species.Moreover,CMK-3 and C-FDU-15 exhibit excellent regeneration efficiency compared with AC.The excellent NO adsorption performance of CMK-3 and C-FDU-15 was associated with their ordered mesoporous structures and high surface areas.The research provides more options for NO adsorption in the future.