淡水环境中短链氯化石蜡的预测无效应浓度及生态风险评估

短链氯化石蜡(short-chain chlorinated paraffins, SCCPs)是《斯德哥尔摩公约》增列的一类持久性有机污染物。搜集筛选出SCCPs对8种淡水生物的慢性毒性数据,构建了物种敏感度分布曲线(SSD),推导出SCCPs的淡水预测无效应浓度(PNECwater)为0.425μg·L~(-1),淡水沉积物预测无效应浓度(PNECsed)为992.5μg·kg-1。搜集了国内外部分淡水河流水体及沉积物中SCCPs环境暴露数据,运用商值法,评估SCCPs的生态风险。结果表明,长江中游和白洋淀水体风险商范围为2.6～154.4和3.7～132.5,处于高风险;国外河流SCCPs污染水平较低,北美地区与日本淡水河流SCCPs风险商小于1,处于低风险。长江中游沉积物的SCCPs的风险商高达400.6,呈现显著风险,欧洲工业区域淡水沉积物中SCCPs存在潜在风险。本研究为SCCPs水质标准制定与环境风险管理提供参考依据。     

Persistent free radicals in humin under redox conditions and their impact in transforming polycyclic aromatic hydrocarbons

• Regulation of redox conditions promotes the generation of free radicals on HM. • HM-PFRs can be fractionated into active and inactive types depending on stability. • The newly produced PFRs readily release electrons to oxygen and generate ROS. • PFR-induced ROS mediate the transformation of organic contaminants adsorbed on HM. The role of humic substance-associated persistent free radicals (PFRs) in the fate of organic contaminants under various redox conditions remains unknown. This study examined the characterization of original metal-free peat humin (HM), and HM treated with varying concentrations of H₂O₂ and L-ascorbic acid (VC) (assigned as H₂O₂-HM and VC-HM). The concentration of PFRs in HM increased with the addition of VC/H₂O₂ at concentrations less than 0.08 M. The evolution of PFRs in HM under different environmental conditions (e.g., oxic/anoxic and humidity) was investigated. Two types of PFRs were detected in HM: a relatively stable radical existed in the original sample, and the other type, which was generated by redox treatments, was relatively unstable. The spin densities of VC/H₂O₂-HM readily returned to the original value under relatively high humidity and oxic conditions. During this process, the HM-associated “unstable” free radicals released an electron to O₂, inducing the formation of reactive oxygen species (ROS, i.e., ^•OH and ^•O₂⁻). The generated ROS promoted the degradation of polycyclic aromatic hydrocarbons based on the radical quenching measurements. The transformation rates followed the order naphthalene>phenanthrene>anthracene>benzo[a]pyrene. Our results provide valuable insight into the HM-induced transformation of organic contaminants under natural conditions.     

紫金山登山道主要树种抗火性研究

比较分析了紫金山登山道两侧主要树种的抗火能力,对紫金山不同立地、区位的森林生物防火林带建设和树种选择进行探讨和分析。利用层次分析法,从树种燃烧特性、生物学和生态抗火特性三个方面对紫金山登山道路两侧32种主要树种的抗火性进行综合评价分析,并利用聚类分析对32种树种的抗火性进行分类。结果表明:石楠、油茶、冬青、栓皮栎、青冈、枸骨、麻栎等12种树种综合抗火性较强;朴树、枫香、黄檀、黄连木等7种树种综合抗火性一般;糙叶树、短叶中华石楠、苦树、山胡椒、紫薇、狭叶山胡椒等12种树种综合抗火性较弱;马尾松综合抗火性最弱。树种抗火性评价的11项评价指标中树叶特性、含水率、树皮特征、热值、树冠结构5项指标对树种抗火性影响较大,综合生物学特征对树种抗火性影响最大。冬青、青冈、女贞等常绿大乔木,石楠、油茶、枸骨、茶树等常绿灌木抗火性较强,可以作为防火树种。糙叶树、短叶中华石楠、苦树、山胡椒、紫薇、狭叶山胡椒、瓜木、构树、鸡爪槭、白檀、青桐、卫矛、马尾松等抗火性差,在森林防火中需要重点防护。     

独塔自锚式悬索桥吊索力影响参数敏感性分析*

为了解成桥吊索力对构件刚度、索鞍位置、温度、吊索张拉力等参数的敏感性,保证自锚式悬索桥体系转换能够安全顺利地完成,以天水市罗家沟大桥为工程背景,采用解析法修正空缆线形、有限元法模拟施工过程,分析张拉前参数和张拉过程参数变化对成桥吊索力的影响。结果表明:刚性吊索索力对吊索抗拉刚度变化敏感,在实际施工前可根据实测数据对吊索张拉力进行适当调整;中、长吊索索力对张拉时环境温度比较敏感,中、长吊索临近的吊索索力对第1轮吊索的张拉力偏差比较敏感,在实际施工时应采取相应的措施对张拉力予以精确控制;吊索力对散索鞍沿滑动面滑动的边界处理较敏感,应在有限元建模和施工时予以重视。     

基于LMDI的我国能源消费因素分解研究

经济飞速发展使我国能源消费急剧增长,能源消费与能源供给、环境污染矛盾日益突出。在分析我国能源消费和能源消费强度变化趋势的基础上,运用LMDI法将我国1996--2010年能源消费变化分解为产出效应、结构效应和强度效应,探讨产出提高、结构调整、效率提高对我国能源消费和能源强度的影响。结果显示,生产规模扩大对能源消费起到正向的拉动作用,结构调整对缓解能源消费增长还有较大的上升空间,能源强度对能源消费的抑制效应自“十一五”期间起作用逐步显现。     

麻栎混交林空间结构与物种多样性研究

林分空间结构是指林木在林地上的分布格局,以及林木之间树种、大小、分布等空间关系。林分空间结构决定了树木之间的竞争势及其空间生态位,在很大程度上决定了林分的稳定性、发展的可能性和经营空间的大小。研究目的在于揭示麻栎混交林林分空间结构与物种多样性特征,为林分空间结构调整和物种多样性保护提供理论依据。利用混交度、大小比数和角尺度3种空间结构参数,以及丰富度指数、Shannon-Wiener指数、Pielou指数等物种多样性数量指标,分析了青阳县麻栎混交林林分空间结构以及群落物种多样性特征。结果表明:乔木层优势树种麻栎多为中度以下混交,小叶栎和枫香多为强度和极强度混交;麻栎在空间大小和重要值对比上占有优势地位,小叶栎处于次要地位,枫香处于劣势地位为受压树种;从林分平面布局上看,该林分空间分布多为随机分布。分层物种丰富度和Shannon-Wiener指数依次是乔木层<草(含藤)本层<灌木层;而均匀度Pielou指数则是乔木层<灌木层<草(含藤)本层;生态优势度Simpson指数为乔木层>草本层>灌木层;灌木层有17科18属21种植物,淡竹占优势地位,野茉莉、山胡椒等占亚优势地位;草本层有10科12属13种植物,禾叶土麦...     

燃煤电厂的可吸入颗粒物排放

简要分析了燃煤过程中可吸入颗粒物的形成机理,指出燃煤电厂对可吸入颗粒物的贡献及目前控制可吸入颗粒物排放措施的局限性,提出电厂在脱硫的同时应控制可吸入颗粒物等污染物的排放。     

饮食业油烟道火灾事故概率的模糊事故树分析

根据常规事故树定量计算中基本事件概率的不确定性问题,通过引入模糊集的概念,将常规事故树中基本事件的发生概率模糊化,用三角形模糊数代替确定性发生概率,应用模糊数截集方法,推导了模糊事故树的相关算法.采用模糊事故树方法得到饮食业油烟道火灾事故发生概率,并进行了敏感性分析,找出对顶事件发生概率影响较大的基本事件,确认减小油烟道火灾事故发生的相关措施.研究表明,饮食业油烟道火灾事故概率的模糊事故树分析是切实可行的,有助于对饮食业油烟道火灾的认识、预防和扑救工作.     

四种砷化合物对藻类生长及光合作用的影响——以三角褐指藻为例

为了给砷对生态系统的影响研究提供参考,利用调制叶绿素荧光技术探讨了自然环境中常见的4种形态的砷对三角褐指藻生长和光合作用的影响.结果表明,在36 h内,亚砷酸盐对藻类生物量的增长和光合活性都有明显的抑制作用;砷酸盐在抑制藻类生长的同时却因为干扰代谢而使藻类表现出光合活性的增强;一甲基砷酸盐和二甲基砷酸盐对藻类在这些方面的影响相对较弱.但对藻类光能利用效率、非光化学淬灭系数等还是产生了较明显的影响.因此,除亚砷酸盐毒性较强之外,其余几种砷化合物在宏观层次上都观测不到明显的生长抑制效应,但是在微观层次上已表现出对光合效应的不同影响.     

Beneath the Straw: In Defense of Participatory Adaptive Management

Our recent paper advocating adaptive management of invasive nonnative species (INS) in Kings Bay, Florida received detailed responses from both Daniel Simberloff, a prominent invasion biologist, and Mark Sagoff, a prominent critic of invasion biology. Simberloff offers several significant lines of criticism that compel detailed rebuttals, and, as such, most of this reply is dedicated to this purpose. Ultimately, we find it quite significant that Simberloff, despite his other stated objections to our paper, apparently agrees with our argument that proposals for alternative management of established INS (i.e., alternatives to minimization/eradication) should not be rejected on an a␣priori basis. We argue that more specific development and application of adaptive approaches toward INS management, whether in Kings Bay or other appropriate case studies, would be facilitated if ecosystem managers and invasion biologists follow Simberloff’s lead on this key point. While Sagoff largely shares (and, indeed, served as a primary source for developing) our general arguments that challenge common moral and scientific assumptions associated with invasion biology, he does question our suggestion that participatory adaptive management provides an appropriate framework for approaching environmental problems in which science and politics are inherently entangled. We attempt to answer this criticism through a brief sketch of what participatory adaptive management might look like for Kings Bay and how such an approach would differ from past management approaches.