重金属污染的稻田土中总有机碳和颗粒态碳的变化

从广东大宝山矿区横石河下游受重金属污染的水稻田采集6个土壤剖面样品,研究了土壤中总有机碳(TOC)、颗粒态有机碳(POC)和POC/TOC比率的垂直分布特征,并探讨不同污染程度对土壤有机碳含量及稳定性的影响.结果表明,与轻度污染和中度污染采样点相比,在重度污染的各土层中,TOC含量显著下降,其垂直分布有显著改变.POC含量在不同土层间的变化与TOC表现出相似的规律,但差异更显著.重金属污染会影响土壤有机碳不同组分在土壤剖面上的垂直分布特征及分配比例,从而影响土壤有机碳的稳定性和可利用性.中度重金属污染使POC含量显著增高,土壤有机碳变得易于分解和损失;重度污染使TOC含量显著降低,不利于土壤有机碳的固定和积累.不同重金属对土壤有机碳稳定性的影响不同,Pb表现出与Cu、Cd的拮抗作用,Pb使有机碳稳定性增加;而Cu和Cd则相反.但多种重金属联合效应使土壤有机碳稳定性呈降低趋势.     

污泥龄对高浓度含氮废水亚硝化稳定性的影响研究

为考察污泥龄与高浓度含氮废水亚硝化稳定性之间的关系,采用连续进水、间歇排水SBR工艺,当水力停留时间为0.75 d,污泥停留时间为3 d时,系统亚硝化率约为75%和氨氮降解率约为60%。试验结果证明SRT控制在一定范围内能实现对硝酸菌的"洗出",使亚硝酸菌占据系统中的优势地位,从而保证了系统较高的亚硝化率。     

掺Fe^3＋A-TiO2粉末的水热法制备及其光催化降解甲基橙

以硫酸钛为原料用水热法制备了掺Fe^3＋TiO2粉末,用SEM和XRD测定了样品的形貌和晶型,研究了以自制的掺Fe^3＋A-TiO2对甲基橙溶液的光催化降解作用。结果表明：所制备的TiO2为锐钛矿型TiO2即A-TiO2。365nm紫外光照射下,用自制的掺Fe^3＋A-TiO2降解甲基橙溶液的最佳条件是：10mg·L^-1的甲基橙溶液中加入0.050g掺5%Fe^3＋（物质的量比）A-TiO2粉末,用HNO3调节溶液成酸性后,18℃恒温反应4h,降解率达到57.8%。     

沈阳地区霾的环境特征研究

利用沈阳市1961—2009年的气象资料,分析了霾天气出现的年季特征及其天气形势特征。利用边界层气象资料与污染物质量浓度资料对特定的霾过程从边界层到污染物质量浓度条件进行了分析。结果表明：沈阳地区霾的出现呈现逐年上升的趋势,近5 a平均每年为120 d左右,目前霾天数已经占到了全年的30%~40%。冬秋季节出现霾天气较多,秋冬两季霾日数占全年霾日总数的75%。凌晨到上午是霾出现的高发期,02—08时霾出现频率占总霾数的44.5%。霾的出现主要发生在冬秋季节冷空气势力不强,大气扩散能力较弱,边界层出现逆温时刻。接地逆温层厚度常常稳定在200~300 m高度左右,PM10质量浓度与能见度（霾）呈负相关,相关系数-0.402 7。风速与能见度（霾）呈正相关,相关系数为0.886 4。     

Influence of haze pollution on water-soluble chemical species in PM2.5 and size-resolved particles at an urban site during fall

To investigate the influence of haze on the chemical composition and formation processes of ambient aerosol particles,PM_(2.5) and size-segregated aerosol particles were collected daily during fall at an urban site of Gwangju,Korea.During the study period,the total concentration of secondary ionic species(SIS) contributed an average of 43.9% to the PM_(2.5) ,whereas the contribution of SIS to the PM_(2.5) during the haze period was 62.3%.The NO_3 and SO~(2-)_4 concentrations in PM_(2.5) during the haze period were highly elevated,being 13.4 and 5.0 times higher than those during non-haze period,respectively.The PM,NO~-_3,SO~(2-)_4,oxalate,water-soluble organic carbon(WSOC),and humic-like substances(HULIS) had tri-modal size distributions peaks at 0.32,1.0,and 5.2 μm during the non-haze and haze periods.However,during the non-haze period they exhibited dominant size distributions at the condensation mode peaking at 0.32 μm,while on October 21 when the heaviest haze event occurred,they had predominant droplet mode size distributions peaking at 1.00 μm.Moreover,strong correlations of WSOC and HULIS with SO~(2-)_4,oxalate,and K+at particle sizes of 1.8 μm indicate that secondary processes and emissions from biomass burning could be responsible for WSOC and HULIS formations.It was found that the factors affecting haze formation could be the local stable synoptic conditions,including the weak surface winds and high surface pressures,the long-range transportation of haze from eastern China and upwind regions of the Korean peninsula,as well as the locally emitted and produced aerosol particles.     

基于剪切梁理论的爆破扰动对巷道顶板稳定性影响研究

厚煤层沿底布置巷道顶板维护难度较大,从爆破扰动影响顶板稳定性的角度对此进行了研究.在分析爆破应力波远区破坏效应的基础上,建立了沿底布置巷道顶板的剪切梁模型,依此研究了顶板煤、岩体的水平位移及应力分布规律,最后以某矿地质条件为原型利用Flac3D数值软件进行了模拟研究.研究发现:基于爆破应力波的远区破坏效应,沿底布置巷道的顶板煤层与上覆岩层的相对错动可以用剪切梁理论加以分析.基于此得到了厚煤层巷道顶板中煤层与岩层单调加载过程及循环加载条件下的位移及应力分布,单次爆破对顶板的影响有限,多次扰动的累积效应会对其产生一定程度的损伤.模拟中,随着装药量的增加,沿底布置巷道顶板煤、岩体的水平位移随之增加,且煤体的位移量大于岩体;持续扰动条件下,煤、岩体的水平位移均出现了累加效应,且随着动力扰动作用次数的增加,煤、岩体的相对错动逐渐增大,容易产生顶板离层垮落等动力灾害.研究成果对加强扰动作用下顶板的支护管理具有一定的理论与指导意义.     

复合法在露天矿边坡稳定性分析中的应用

边坡的稳定性问题关系到人们的生命安全,对其进行研究是非常有必要的。以白云鄂博铁矿的D区边坡稳定性分析为例,采用复合法进行研究,首先通过对其边坡进行现场节理的详细线测量绘制赤平投影图,来判断出可能发生破坏的位置;其次通过Sarma法进行平衡理论计算,稳定性系数结果为0．75;最后通过FLAC3D进行数值模拟计算,得出应力、应变云图,另对分析出可能破坏的两个位置进行剖面计算,计算后的稳定性系数结果分别为0．5、0．6。总之,边坡稳定性系数均小于1,可能发生失稳,需对其进行加固,保证矿山安全开采。     

Uneven distribution of urban green spaces in a coastal city in northwest Mexico

ABSTRACT

Extent and distribution of urban green spaces (UGS) in Mazatlan (Mexico) are analysed using remote sensing and GIS techniques. Vegetated areas (2,270?ha), a third of the urban area in 2015, were reclassified into green spaces (GS), urban tree (UT) and open spaces (OS), based in the normalised difference vegetation index, relating them with demographic and socioeconomic data. UGS allocation per capita amount 55?m², mainly represented by the UT class, with the largest patches associated with low developed and very high marginalised areas, and also with very low marginalised sectors, while the lowest allocation correspond to medium and low marginalisation, highly populated sector, without significant correlations. Despite the USG allocation, it is required a better urban planning to maintain public UGS and to protect the local flora, threatened by the introduction of exotic, ornamental species (64% of UT), to guarantee the provision of ecosystem services to the population.     

改性硅藻土陶瓷生物膜载体的制备及性能研究

主要对硅藻土的烧结改性进行了进一步的研究,并对改性硅藻土用于污水处理系统生物膜的载体制作进行参数研究。通过设置适宜的污水水力学特性、良好的载体挂膜性能表征、实验运行稳定性等多方面进行对比实验,得出最佳生物膜挂膜性能的改性硅藻土陶瓷生物膜载体。     

基于CDEM露天煤矿顺倾软岩边坡三维稳定性分析

为解决露天煤矿顺倾层状软岩边坡稳定性这一技术难题,基于连续介质离散元数值模拟方法,从理论上探讨了降深与清帮至不同位置对顺倾软岩边坡稳定性的影响。结合白音华一号矿南帮工程实例,针对各煤层降深及清帮方案,基于CDEM数值算法对边坡稳定性进行计算,对比分析了坡体位移、应力分布及演化特征,进而阐明多个弱层对复合边坡产生的叠加效应,以及清帮减载对边坡稳定性的影响。结果表明,白音华一号矿首采区南帮边坡变形不会对南排土场稳定性造成影响,揭露多个弱层对边坡变形与稳定性下降有一定的叠加效应,清帮不能显著提高边坡稳定性,但可减小作用在弱层上的法向应力和剪切应力,进而减缓滑坡发生的过程,提高边坡动态发展过程中的安全性。