全文获取类型
收费全文 | 313篇 |
免费 | 45篇 |
国内免费 | 294篇 |
专业分类
安全科学 | 11篇 |
废物处理 | 18篇 |
环保管理 | 36篇 |
综合类 | 374篇 |
基础理论 | 92篇 |
污染及防治 | 100篇 |
评价与监测 | 9篇 |
社会与环境 | 12篇 |
出版年
2024年 | 5篇 |
2023年 | 19篇 |
2022年 | 35篇 |
2021年 | 20篇 |
2020年 | 14篇 |
2019年 | 20篇 |
2018年 | 27篇 |
2017年 | 51篇 |
2016年 | 30篇 |
2015年 | 37篇 |
2014年 | 46篇 |
2013年 | 58篇 |
2012年 | 43篇 |
2011年 | 36篇 |
2010年 | 36篇 |
2009年 | 36篇 |
2008年 | 10篇 |
2007年 | 25篇 |
2006年 | 22篇 |
2005年 | 10篇 |
2004年 | 10篇 |
2003年 | 10篇 |
2002年 | 8篇 |
2001年 | 9篇 |
2000年 | 6篇 |
1999年 | 7篇 |
1998年 | 3篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1987年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有652条查询结果,搜索用时 140 毫秒
211.
几种污水处理材料对COD和Cr(Ⅵ)的去除比较研究 总被引:2,自引:0,他引:2
研究了活性炭、硅藻土、高岭土和改性玉米秸秆几种常见污水处理材料对污水中有机物(COD)和Cr(Ⅵ)的吸附效果,发现活性炭吸附污水中有机物的效果最好,经活性炭吸附的污水的COD去除率达88.8%。同时,活性炭对Cr(Ⅵ)也有很强的吸附能力。硅藻土和高岭土对有机物的吸附效果较差,对Cr(Ⅵ)具有较好的吸附效果。改性玉米秸秆对Cr(Ⅵ)表现出很强的吸附能力,在低浓度Cr(Ⅵ)的吸附实验中,可以达到比活性炭更高的吸附量,开发应用潜力巨大。 相似文献
212.
Johannes A. Hagström Mario R. Sengco Tracy A. Villareal 《Journal of the American Water Resources Association》2010,46(1):187-198
Hagström, Johannes A., Mario R. Sengco, and Tracy A. Villareal, 2010. Potential Methods for Managing Prymnesium parvum Blooms and Toxicity, With Emphasis on Clay and Barley Straw: A Review. Journal of the American Water Resources Association (JAWRA) 46(1):187-198. DOI: 10.1111/j.1752-1688.2009.00402.x Abstract: Harmful algal bloom (HAB) control and mitigation is a complex problem in ecosystem management. Phytoplankton play an important role in aquatic ecosystems as primary producers and food sources for many commercially important shellfish and there are limited options for targeting just a single species within the community. Chemical treatments (e.g., algaecides), rotting barley straw, nitrogen and phosphorus manipulation, and clay and/or flocculants are but a few techniques tested or used to reduce fish kills or shellfish contamination during a HAB event. Prymnesium parvum control has focused on the use of chemicals, nutrient manipulation, and clay flocculation. However, many HAB control methods have been rejected due to their effects on ecosystems, high costs, or limited effects on target organisms. For example, rotting barley straw (Hordeum vulgare) is considered to be an environmentally friendly alternative, but has been found to have very different results on the phytoplankton community depending on the dominating taxa and is ineffective against P. parvum and dinoflagellate blooms. Clay flocculation is a useful control/mitigation technique during fish kills in marine aquaculture sites in South Korea and can be effective in freshwater if the correct combination of clay and flocculent is used. Toxins produced by P. parvum and Karenia brevis also bind to phosphatic clay, thereby removing and/or neutralizing the toxins, but there is concern that the clay will have a negative effect on sessile organisms. Some shellfish suffer high mortalities and significant impacts on somatic and reproductive tissue growth at high clay loads; however, benthic communities appear to be unchanged after five years of clay treatment in South Korea. There are likely site-specific and ecosystem-specific characteristics that make generalizations about control options difficult and require careful assessment of options at each location. 相似文献
213.
安徽省油菜秸秆资源综合利用方案研究 总被引:2,自引:0,他引:2
估算了安徽省油菜秸秆的资源量及分布,分析了其综合利用现状及其存在的问题,预测了未来4—5年安徽省的油菜秸秆资源量。评价油菜秸秆用途的适宜性,提出其综合利用方案与措施建议。 相似文献
214.
215.
216.
应用膨化技术对玉米秸秆进行预处理.在单因素实验基础上,以还原糖转化率为影响值设计正交实验,研究温度、pH、液固比、酶浓度及酶解时间五因素对纤维素酶解过程的影响.得出玉米秸秆糖化酶解最佳工艺条件为:温度48℃,pH 4.5,液固比8:1,酶浓度36.0 U/g,酶解时间25 h;在此工艺条件下还原糖转化率达到28.98%.扫描电镜表征对比观察可看出,膨化后玉米秸秆纤维素酶解充分;结合红外光谱对各组分特征基团分析表明,膨化后的玉米秸秆酶解的纤维素基团特征峰变化更为明显. 相似文献
217.
MD. Munir H. Khan S. Ali A. Fakhru'l-Razi MD. Z. Alam 《Journal of environmental science and health. Part. B》2013,48(4):381-386
Cellulase production was carried out by solid state bioconversion (SSB) method using rice straw, a lignocellulosic material and agricultural waste, as the substrate of three Trichoderma spp. and Phanerochaete chrysosporium in lab-scale experiments. The results were compared to select the best fungi among them for the production of cellulase. Phanerochaete chrysosporium was found to be the best among these species of fungi, which produced the highest cellulase enzyme of 1.43 IU/mL of filter paper activity (FPase) and 2.40 IU/mL of carboxymethylcellulose activity (CMCase). The “glucosamine” and “reducing sugar” parameters were observed to evaluate the growth and substrate utilization in the experiments. In the case of Phanerochaete Chrysosporium, the highest glucosamine concentration was 1.60 g/L and a high concentration of the release of reducing sugar was measured as 2.58 g/L obtained on the 4th day of fermentation. The pH values were also recorded. The range of the pH was about 5.15 to 5.56 in the case of Phanerochaete Chrysosporium. 相似文献
218.
改性玉米秸秆吸附Cu^2+的动力学和热力学 总被引:2,自引:0,他引:2
本研究用ZnCl2作为活化剂,使用功率640W的微波照射4min的方法制备改性玉米秸秆。考察投加量、pH、吸附时间对吸附性能的影响,并对等温吸附特征、吸附动力学和热力学进行了系统研究。结果表明:投加量为0.2g,pH为6,改性玉米秸秆对Cu^2+具有很好的吸附效果,吸附在8h后达到平衡。该吸附过程符合Langmuir及Freundlich等温吸附模型和准二级动力学方程,其反应的吉布斯自由能△G〈0,为自发反应过程。 相似文献
219.
为研究混合水解对麦秸水解产酸的影响,以猪粪、厨余和蔬菜废物为原料,研究其分别与麦秸混合水解产酸的特性,分析了水解过程中pH值、COD、SCOD和VFAs的变化。结果表明,除麦秸+蔬菜废物最佳出料时间为3~9d外,麦秸、麦秸+厨余垃圾、麦秸+猪粪水解液最佳出料时间均为3~7d,7d后水解液COD浓度下降;将蔬菜废物与麦秸混合水解,水解液pH值降低幅度最大,水解液中总有机酸浓度最高,pH值最低为5.31,有机酸浓度最高达6.46g/L,且水解液中SCOD浓度、SCOD/COD比值最大;添加猪粪明显促进了麦秸有机物的水解溶出,麦秸单位干物质水解率和产酸率较对照分别提高了43%~134%和50.53%,但对提高水解液SCOD浓度、SCOD/COD比、TVFA浓度、降低水解液pH值的效果不如蔬菜废物;添加厨余垃圾的效果介于猪粪和蔬菜废物之间。从促进麦秸水解产酸的角度,以添加猪粪的效果最好。 相似文献
220.
Suman Manna 《Journal of environmental science and health. Part. B》2013,48(7):463-472
The objective of this research was to investigate the effect of wheat and rice biochars on pyrazosulfuron-ethyl sorption in a sandy loam soil. Pyrazosulfuron-ethyl was poorly sorbed in the soil (3.5–8.6%) but biochar amendment increased the herbicide adsorption, and the effect varied with the nature of the feedstock and pyrolysis temperature. Biochars prepared at 600°C were more effective in adsorbing pyrazosulfuron-ethyl than biochars prepared at 400°C. Rice biochars were better than wheat biochars, and higher herbicide adsorption was attributed to the biochar surface area/porosity. The Freundlich constant 1/n suggested nonlinear isotherms, and nonlinearlity increased with increase in the level of biochar amendment. Desorption results suggested sorption of pyrazosulfuron-ethyl was partially irreversible, and the irreversibility increased with increase in the level of biochar. Both sorption and desorption of pyrazosulfuron-ethyl correlated well with the content of biochars. The free energy change (ΔG) indicated that the pyrazosulfuron-ethyl sorption process was exothermic, spontaneous and physical in nature. Persistence studies indicated that biochar (0.5%) amendment did not have significant effect on herbicide degradation, and its half-life values in the control, 0.5% WBC600- and RBC600-amended rice planted soils were 7, 8.6, and 10.4 days, respectively. 相似文献