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71.
阐述了氨法烟气脱硫技术的原理和工艺特点.介绍了Walther氨法、AMASOX氨法、GE氨法、NADS氨-肥法、电子束氨法和流光放电氨法烟气脱硫工艺,重点介绍了新型流光放电氨法烟气脱硫技术的特点及其工程应用情况.展望了氨法烟气脱硫技术的应用前景. 相似文献
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Within the European monitoring network (EMEP, ) several different sampling procedures for measuring the main air components have been applied. This has contributed to systematic
concentration differences and a comparability problem. Since 1997 co-located experiments in 15 countries have been carried
out to quantify these differences. In addition, three major measurement campaigns were organized by EMEP between 1985 and
1991. Differences among results depend on the concentration level and methods used. The decrease in SO2 concentrations over the last twenty years has placed greater demands on the methodology. Absorbing solutions methods for
SO2, (H2O2 and tetrachloromercurate (TCM)) typically have higher detection limits than the reference method, which uses KOH impregnated
filters. The TCM method also has problems with negative interference, especially in summertime. UV fluorescence monitors have
in a few cases proven to give good results, but interferences, detection limit and poor maintenance can be problems. For NO2, many countries are using the TGS absorption solution method, which has a higher detection limit than the reference method
using NaI impregnated glass sinters. The Salzmann method gives unreliable results at concentrations below 1 μgN/m3, and even at higher concentrations the uncertainty is rather unsatisfactory. The chemiluminescence monitor with molybdenum
converters tends to systematically overestimate NO2 concentrations, possibly because zero-drift problems and the non-specific response to NO2. Particulate sulphate measurements in general have lower bias and uncertainties than gas and other aerosol measurements. 相似文献
74.
Zn(Ⅱ)对生物质碳源处理酸性矿山排水中厌氧微生物活性影响 总被引:1,自引:1,他引:0
通过厌氧批实验的方法,探讨了在硫酸盐还原菌(SRB)法处理模拟酸性矿山排水(AMD)的过程中,以油菜秸秆为碳源时,Zn2+浓度对SRB活性的影响.结果表明,在60 d实验中,以油菜秸秆为碳源时,当Zn2+初始浓度在73.7~196.8 mg.L-1范围时,SRB具有良好活性,实验结束时,pH从初始的5.0上升至中性范围,硫酸根还原率达到96%以上,同时Zn2+浓度降至0.05 mg.L-1以下.Tessier固体形态分类、场发射扫描电镜(FE-SEM)和X射线衍射仪(XRD)分析发现,Zn以有机物及硫化物的形态被固定,其中硫化物主要为闪锌矿(ZnS).当Zn2+初始浓度为262.97 mg.L-1时,SRB的活性受到强烈的抑制,实验结束时,pH从初始的5.0降至4.0左右,硫酸根还原率只有27%,Zn2+维持在较高浓度范围(25 mg.L-1).油菜秸秆可以作为SRB法长期处理AMD的缓释碳源,能为微生物生长繁殖提供物质和能量;秸秆的吸附性可降低Zn2+的生物毒性,使得SRB可以适应高浓度的Zn2+;SRB可以通过形成硫化物矿物的形式固定元素Zn. 相似文献
75.
Bayesian estimation of European sulphur emissions using monitoring data and an acid deposition model
A statistical method for estimating national emissions of acidifying air pollutants in Europe is presented. The method uses an acid deposition model to match official emissions data from European countries and measured depositions from a monitoring network. An application to 1990 sulphate data demonstrates the method and suggests some tendencies in the reported emissions. The proposed framework may prove useful for verifying national compliance with emissions standards, and the method should be applicable also to other substances than sulphur dioxide. The problem of designing an optimal monitoring network may also be assessed within the proposed statistical framework. 相似文献
76.
对苯二酚生产中含硫酸锰废水的综合利用 总被引:1,自引:0,他引:1
根据硫酸锰废水的特性,采用中和除铁和硫化除钴、镍等方法先使废水净化,得到合格电解液.其后对该电解液通电并加入硒电解24小时,再经钝化等处理制得金属锰.利用电解硫酸锰后的阳极废水制取碳酸锰,并从碳酸锰废水中回收硫酸铵.本工艺简单可行,产品金属锰纯度达99.8%以上,经济和环境效益显著. 相似文献
77.
铁盐和铝盐混凝剂对消毒副产物的控制作用及机制研究 总被引:4,自引:0,他引:4
以三氯化铁和硫酸铝为研究对象,探讨了两种混凝剂对三氯甲烷生成量的控制作用及控制机制.结果表明,与硫酸铝相比,三氯化铁可以更好地控制三氯甲烷的生成量,对有机物的去除方面,也具有良好的效果.E4/E6变化表明,三氯化铁和硫酸铝对水中有机物的去除机制不同,硫酸铝主要去除水中大分子的有机物,三氯化铁更倾向于去除水中小分子有机物,而这些小分子有机物通常是消毒副产物的前体物,从而使三氯化铁对消毒副产物的控制作用较硫酸铝明显. 相似文献
78.
79.
During the last two decades, the importance of sulphur dioxide as a pollutant has moved away from its association with suspended particulate matter, to it being a precursor of SO
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aerosol (acidic e.g. sulphuric acid, or neutralised e.g. ammonium sulphate). Co-located concentration data of sulphur dioxide and SO
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, at nine monitoring sites situated in predominantly rural areas in the United Kingdom, collected over the time period 1979–1995, have been analysed. The time series for both species are discussed for the sites. Further analysis has shown that there is a degree of correlation between sulphur dioxide and SO
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for most of the sites considered. This correlation is of approximately the same level for most of the sites taken independently and together, and in most cases the slopes and intercepts associated with the simple empirical model equations arising from the correlation analysis, are of the same order of magnitude. The implementation of these site-dependent model equations within dispersion models for the prediction of the concentration of airborne sulphate aerosol from knowledge of sulphur dioxide concentration is discussed. Furthermore, the correlation analysis revealed the influence of transported sulphate aerosol on the local concentration, especially during high concentration episodes. 相似文献
80.
Shalini Singh Prem Dureja Sushil Kumar 《Journal of environmental science and health. Part. B》2013,48(3):337-346
Abstract The degradation of α and β isomers of endosulphan and endosulphan sulphate in four sterilized and non sterilized Indian soils under laboratory conditions was studied. Degradation was found to be more in non‐sterilized as compared to the sterilized soil. The half life of α‐endosulphan, β‐endosulphan and endosulphan sulphate was found to be 136.8, 273 and 301 days in sterilized Alfisol and 55, 256 and 277 days in non‐sterilized Alfisol, respectively. α‐Endosulphan degraded more readily than β‐endosulphan and endosulphan sulphate under both sterilized and non‐sterilized soil conditions. 相似文献