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261.
Cu~(2+)、Zn~(2+)对生物脱氮系统的影响 总被引:1,自引:1,他引:0
Cu2+和Zn2+是污水处理工艺中经常遇到的金属离子.在驯化好的活性污泥系统中,研究了金属离子Cu2+和Zn2+在0~100 mg/L浓度下对活性污泥牛物脱氮系统的影响.试验发现Cu2+>5 mg/L、Zn2+>30 ms/L时,对硝化过程具有明显的抑制作用,在同样浓度的试验条件下Cu2+对硝化过程的抑制作用比Zn2+大.Cu2+≤0.5 mg/L时对反硝化过程具有一定的促进作用,有助于提高TN的去除效果;Cu2+>0.5 mg/L时,对反硝化产牛抑制作用,随着浓度的增加,TN去除率逐渐下降.Zn2+不影响反硝化过程,仅在大于30 mg/L时,对硝化过程产生抑制作用.重金属Cu2+对生物脱氮系统的影响明显强于Zn2+. 相似文献
262.
辽河油田稠油泥砂综合处理工艺的研究* 总被引:5,自引:3,他引:2
稠油污泥作为含油污泥的典型代表,其成分极为复杂、处理难度极大,由于目前国内外尚无成熟工艺可完全实现其"减量化、资源化、无害化处理",给油田生产和环境保护带来了严重影响。文章分析了稠油污泥的组成及性质,根据稠油污泥来源不同实施分类预处理,利用热风干化技术将其减量,经热解气化焚烧和热能利用,为实现含油污泥无害化处理进行了有益探索。 相似文献
263.
264.
地下饮用水中痕量NO2-的催化动力学法测定 总被引:3,自引:0,他引:3
报道了一种新的测定NO2-的高选择性和高灵敏度的催化光度分析法.基于H3PO4介质中,碘绿与溴酸钾的氧化还原反应受亚硝酸盐的催化使碘绿褪色.据此建立了测定NO2-的新方法.本方法检出限为0.29μg/L,该方法用于地下饮用水、环境标样的测定,相对标准偏差为1.05%~4.80%,加标回收率为95%~117%. 相似文献
265.
Ali-Khodja H Belaala A Demmane-Debbih W Habbas B Boumagoura N 《Environmental monitoring and assessment》2008,138(1-3):219-231
Total suspended particulate matter and deposition fluxes of particles were investigated in the town of Didouche Mourad which
is located 13 km north of Constantine. Samples of air particulate matter were collected at one site located in the heart of
the town and situated 3 km north of a cement plant. Samples were collected from 2 November 2002 to 28 April 2003 every 3 days
using a high volume air sampler. Sampling intervals were 24 h in all cases. During the same period, samples of dust fallout
were collected at the same site. Samples were collected at 30-day intervals. Lead, chromium, manganese, nickel, copper, cobalt
and cadmium deposition fluxes were measured and both the soluble and insoluble fractions were determined. Furthermore, the
information gathered by this study was correlated with the corresponding hourly weather data provided by a weather station
installed at the study station. The possible sources for dust and trace metals were analyzed by comparing average contributions
of wind aspects to the concentrations and depositions of mass and chemical species with the average frequencies of wind direction.
The mean concentration was 300 μg/m3. The average dust deposition rate through the period of study was 221 mg/(m2.day). Results indicate that anthropogenic sources contribute greatly to trace elements. An exposure assessment to the heavy
metals taking into account the inhalation route and soil dust ingestion was carried out and allowed direct comparison of trace
metal intakes via these routes. 相似文献
266.
Heavy metal contamination from mining sites in South Morocco: Monitoring metal content and toxicity of soil runoff and groundwater 总被引:5,自引:0,他引:5
El Khalil H El Hamiani O Bitton G Ouazzani N Boularbah A 《Environmental monitoring and assessment》2008,136(1-3):147-160
The aim of the present work is the assessment of metal toxicity in runoff, in their contaminated soils and in the groundwater
sampled from two mining areas in the region of Marrakech using a microbial bioassay MetPLATE™. This bioassay is based on the
specific inhibition of the β-galactosidase enzyme of a mutant strain of Escherichia coli, by the metallic pollutants. The stream waters from all sampling stations in the two mines were all very toxic and displayed
percent enzyme inhibition exceeding 87% except SWA4 and SWB1 stations in mine C. Their high concentrations of copper (Cu) and zinc (Zn) confirm the acute toxicity shown by MetPLATE.
The pH of stream waters from mine B and C varied between 2.1 and 6.2 and was probably responsible for metal mobilization,
suggesting a problem of acid mine drainage in these mining areas. The bioassay MetPLATE™ was also applied to mine tailings
and to soils contaminated by the acidic waters. The results show that the high toxicity of these soils and tailings was mainly
due to the relatively concentration of soluble Zn and Cu. The use of MetPLATE™ in groundwater toxicity testing shows that,
most of the samples exhibited low metal toxicity (2.7–45.5% inhibition) except GW3 of the mine B (95.3% inhibition during
the wet season and 82.9% inhibition during the dry season). This high toxicity is attributed to the higher than usual concentrations
of Cu (189 μg Cu l−1) and Zn (1505 μg Zn l−1). These results show the potential risk of the contamination of different ecosystems situated to the vicinity of these two
metalliferous sites. The general trend observed was an increase in metal toxicity measured by the MetPLATE with increasing
total and mobile metal concentrations in the studied matrices. Therefore, the MetPLATE bioassay is a reliable and fast bioassay
to estimate the metals toxicity in the aquatic and solids samples. 相似文献
267.
Fernandes C Fontaínhas-Fernandes A Cabral D Salgado MA 《Environmental monitoring and assessment》2008,136(1-3):267-275
Esmoriz–Paramos lagoon is an ecosystem of great ecological importance that is located on the northwest coast of Portugal and
has been degraded as a result of industrial and anthropogenic activities. Concentrations of heavy metals (Cr, Cu, Pb and Zn)
were measured in water, sediment and in tissues (liver and muscle) of Liza saliens, which is the dominant fish from the lagoon. Comparisons between metal concentrations in water and sediments were made with
those in tissues of fish caught at the lagoon. Metals in water were quantified predominantly bound to particulate and equalled
or exceeded the limit of chronic reference values. Metal concentrations in sediments varied among sampled sites. The relative
order of concentrations was “Zn > Cu ∼ Pb > Cr” the same pattern observed for metals in water. Metals in fish tissues showed
higher concentrations in liver (262 mg Cu·Kg−1 and 89 mg Zn·Kg−1) than in muscle (<3 mg Cu·Kg−1 and 26 mg Zn·Kg−1), while Pb and Cr were not detected. These results suggest that Cu and Zn are the metals of major concern in the lagoon.
Mullet detritivorous feeding habits, bioaccumulation pattern and the high sediment metals concentrations relative to the water
suggest that sediments can be the most important source of contamination in this ecosystem. The positive relationship found
between Cu in liver and fish length demonstrates that time of exposure is a crucial factor in bioaccumulation. Condition indices
(K and HSI) in mullets from the lagoon were higher compared to mullets from sea, suggesting abnormal condition in the lagoon
population. We conclude that metals chronic exposure in the lagoon can impose considerable fish stress. The results also show
that the lagoon is an area of environmental concern. 相似文献
268.
Govil PK Sorlie JE Murthy NN Sujatha D Reddy GL Rudolph-Lund K Krishna AK Rama Mohan K 《Environmental monitoring and assessment》2008,140(1-3):313-323
Studies on quantitative soil contamination due to heavy metals were carried out in Katedan Industrial Development Area (KIDA),
south of Hyderabad, Andhra Pradesh, India under the Indo-Norwegian Institutional Cooperation Programme. The study area falls
under a semi-arid type of climate and consists of granites and pegmatite of igneous origin belonging to the Archaean age.
There are about 300 industries dealing with dyeing, edible oil production, battery manufacturing, metal plating, chemicals,
etc. Most of the industries discharge their untreated effluents either on open land or into ditches. Solid waste from industries
is randomly dumped along roads and open grounds. Soil samples were collected throughout the industrial area and from downstream
residential areas and were analysed by X-ray Fluorescence Spectrometer for fourteen trace metals and ten major oxides. The
analytical data shows very high concentrations of lead, chromium, nickel, zinc, arsenic and cadmium through out the industrial
area. The random dumping of hazardous waste in the industrial area could be the main cause of the soil contamination spreading
by rainwater and wind. In the residential areas the local dumping is expected to be the main source as it is difficult to
foresee that rain and wind can transport the contaminants from the industrial area. If emission to air by the smokestacks
is significant, this may contribute to considerable spreading of contaminants like As, Cd and Pb throughout the area. A comparison
of the results with the Canadian Soil Quality Guidelines (SQGL) show that most of the industrial area is heavily contaminated
by As, Pb and Zn and local areas by Cr, Cu and Ni. The residential area is also contaminated by As and some small areas by
Cr, Cu, Pb and Zn. The Cd contamination is detected over large area but it is not exceeding the SQGL value. Natural background
values of As and Cr exceed the SQGL values and contribute significantly to the contamination in the residential area. However,
the availability is considerably less than anthropogenic contaminants and must therefore be assessed differently. The pre-
and post-monsoon sampling over two hydrological cycles in 2002 and 2003 indicate that the As, Cd and Pb contaminants are more
mobile and may expect to reach the groundwater. The other contaminants seem to be much more stable. The contamination is especially
serious in the industrial area as it is housing a large permanent residing population. The study not only aims at determining
the natural background levels of trace elements as a guide for future pollution monitoring but also focuses on the pollution
vulnerability of the watershed. A plan of action for remediation is recommended. 相似文献
269.
The Singrauli region in the southeastern part of Uttar Pradesh, India is one of the most polluted industrial sites of Asia.
It encompasses 11 open cast coalmines and six thermal power stations that generate about 7,500 MW (about 10% of India’s installed
generation capacity) electricity. Thermal power plants represent the main source of pollution in this region, emitting six
million tonnes of fly-ash per annum. Fly-ash is deposited on soils over a large area surrounding thermal power plants. Fly-ashes
have high surface concentrations of several toxic elements (heavy metals) and high atmospheric mobility. Fly ash is produced
through high-temperature combustion of fossil fuel rich in ferromagnetic minerals. These contaminants can be identified using
rock-magnetic methods. Magnetic susceptibility is directly linked to the concentration of ferromagnetic minerals, primarily
high values of magnetite. In this study, magnetic susceptibility of top soil samples collected from surrounding areas of a
bituminous-coal-fired power plant were measured to identify areas of high emission levels and to chart the spatial distribution
of airborne solid particles. Sites close to the power plant have shown higher values of susceptibility that decreases with
increasing distance from the source. A significant correlation between magnetic susceptibility and heavy metal content in
soils is found. A comparison of the spatial distribution of magnetic susceptibility with heavy-metal concentrations in soil
samples suggests that magnetic measurements can be used as a rapid and inexpensive method for proxy mapping of air borne pollution
due to industrial activity. 相似文献
270.
Accumulation of Heavy Metals in Epiphytic Lichens Near a Municipal Solid Waste Incinerator (Central Italy) 总被引:1,自引:0,他引:1
S. Loppi E. Putortì S. A. Pirintsos V. De Dominicis 《Environmental monitoring and assessment》2000,61(3):361-371
The epiphytic lichen Parmelia caperata was usedas biomonitor in the area of a municipal solid wasteincinerator (Poggibonsi, central Italy) to investigatethe levels and the spatial distribution of the heavymetals Al, Cd, Cr, Cu, Fe, Hg, Pb and Zn. Levels ofAl, Cu and Hg were similar to those in unpollutedareas, whereas high values were found for Cr, Zn andespecially Cd. The distribution pattern of the lastthree metals and the exponential relationship of theirconcentrations with distance from the incinerator,showed that the disposal plant is a local source ofatmospheric pollution due to Cd, Cr and Zn. For thesemetals, long-term hazard should be seriously taken into account. 相似文献