Organochlorine pesticide in water and bottom sediment from Aiba Reservoir (Southwestern Nigeria)

Levels of organochlorine pesticides (OCPs) in water and sediment from Aiba reservoir (Southwestern Nigeria) have been assessed. The aim of the study was to investigate the pollution status of the reservoir water and the bottom sediment. Analytical measurements were carried out for 20 OCPs using standard literature methods. The results showed higher levels of OCPs in the bottom sediment than the water. Significant positive correlations at p<0.05 level were observed for OCPs compounds in water except γ-BHC and endosulfan III, whereas in sediments α-chlordane, dieldrin, endosulfan II, pp-DDT, endrin ketone and methoxychlor did not show any correlation, and aldrin was negatively correlated with pp-DDD. The mean levels of OCPs in both water and sediments were higher, in most cases, than recommended levels for drinking water. Owing to possible toxicity and bioaccumulation tendency of OCPs by the aquatic habitats, the levels of OCPs detected in water and sediment samples could be a source of future health problems. Environmental monitoring of the reservoir is highly recommended.     

Modeling and optimization of Nile blue sulfate mineralization by heterogeneous fenton oxidation

Artificial neural network and response surface methodology have been used to develop a model for simulation and optimization of the removal of Nile blue sulfate by heterogeneous Fenton oxidation. Experimental data were used to train an artificial neural network model with linear transfer function at the output layer and a tangent sigmoid transfer function at the hidden layer. A Box–Behnken design was employed to assess the effects of input process parameters on the total organic carbon removal. First order kinetics and lumped kinetics models were used to describe the reaction; a high regression coefficient indicated that the latter fitted best. The formation of non-oxidizable compounds was shown by liquid chromatography–mass spectrometry.     

热带海洋环境下舰艇携行弹药的环境效应分析

分析了我国东海、南海和印度洋亚丁湾海域的气候环境特征,在此基础上,结合弹药在舰艇上的存放/使用位置分析,得出了环境因素对不同位置舰艇携行弹药的影响程度。鉴于环境因素对弹药的环境影响效应是综合性的,以弹药防护包装、弹体、装药、引信等分系统为对象,分别开展了环境效应分析,综述了其在热带海洋环境下的环境效应。建议加强舰艇携行弹药局部环境监测、损伤效应与机理研究,并建立数据库,为我军舰艇携行弹药环境适应性设计与验证、环境控制措施和维护保养措施制定提供数据基础,支撑我国海军不断走向深蓝。     

Paraquat Adsorption,Degradation, and Remobilization in Tropical Soils of Thailand

Paraquat adsorption, degradation, and remobilization were investigated in representative tropical soils of Yom River Basin, Thailand. Adsorption of paraquat in eight soil samples using batch equilibration techniques indicated that adsorption depended on soil characteristics, including exchangeable basic cations and iron content. Multiple regression analysis indicated significant contribution of exchangeable calcium percentage (ECP), total iron content (TFe) and exchangeable sodium percentage (ESP) to paraquat sorption (Q). ESP and TFe were significant at all adsorption stages, whereas ESP was significant only at the initial stage of paraquat adsorption. Adsorption studies using two soils representing clay and sandy loam textures showed that paraquat adsorption followed the Freundlich model, exhibiting a nonlinear sorption curve. Paraquat adsorption was higher in the clay soil compared to the sandy loam soil with K _f values of 787 and 18, respectively. Desorption was low with 0.04 to 0.17% and 0.80 to 5.83% desorbed in clay and sandy loam soil, respectively, indicating some hysteresis effect. Time-dependent paraquat adsorption fitted to the Elovich kinetic model indicated that diffusion was a rate-limiting process. Paraquat mobility and degradation studies conducted using both field and laboratory soil column experiments with clay soil showed low mobility of paraquat with accumulation only in the surface 0–5 cm layer under field conditions and in the 0–1 cm layer in a laboratory soil column experiment. Degradation of paraquat in soil was faster under field conditions than at ambient laboratory conditions. The degradation rate followed a first-order kinetic model with the DT₅₀ at 36–46 days and DT₉₀ around 119–152 days.     

The Value of Rehabilitating Logged Rainforest for Birds

Abstract: The recent advent of carbon crediting has led to a rapid rise in biosequestration projects that seek to remove carbon from the atmosphere through afforestation and forest rehabilitation. Such projects also present an important potential opportunity to reverse biodiversity losses resulting from deforestation and forest degradation, but the biodiversity benefits of different forms of biosequestration have not been considered adequately. We captured birds in mist nets to examine the effects of rehabilitation of logged forest on birds in Sabah, Borneo, and to test the hypothesis that rehabilitation restores avian assemblages within regenerating forest to a condition closer to that seen in unlogged forest. Species richness and diversity were similar in unlogged and rehabilitated forest, but significantly lower in naturally regenerating forest. Rehabilitation resulted in a relatively rapid recovery of populations of insectivores within logged forest, especially those species that forage by sallying, but had a marked adverse effect on frugivores and possibly reduced the overall abundance of birds within regenerating forest. In view of these results, we advocate increased management for heterogeneity within rehabilitated forests, but we strongly urge an increased role for forest rehabilitation in the design and implementation of a biodiversity‐friendly carbon‐offsetting market.     

Prenatal ultrasound diagnosis of cloacal exstrophy associated with myelocystocele complex by the ‘elephant trunk–like’ image and review of the literature

A case of cloacal exstrophy (CE) was detected by ultrasound as early as 22 weeks of gestation in association with myelocystocele complex, an unusual form of occult spinal dysraphism often associated with such a disease. The ultrasonographic diagnosis was made through the detection of a wavy cord-like segment of soft tissue protruding from the anterior abdominal wall, just below the umbilical cord insertion, strongly resembling the trunk of an elephant. Our article enforces the suggestion that the ultrasound elephant trunk–like image should be added to the existing major criteria for making prenatal diagnosis of CE. Copyright © 2005 John Wiley & Sons, Ltd.     

(Relative) autonomism,policy currents and the politics of mobilisation for food sovereignty in the United States: the case of Occupy the Farm*

Food sovereignty movements (FSMs) globally have sought to rearrange relations between land, power, state actions and societal forces outside the state, towards a new ideal of democratised, egalitarian and ecological food systems. The question of how best to reach this ideal has vexed movements and scholars alike, with many anti-capitalist theorists proposing that because of the historical dedication of states to maintaining unequal and unsustainable capitalist relations, change must be pursued outside and against the state rather than through it (i.e. through “autonomism”). Yet, analysis of FSMs globally shows that autonomism is relative, partial and best seen as an aspirational ideal rather than a fixed dogma. This paper deepens this insight by analysing a case within the United States where a local direct action group promoted food sovereignty by illegally occupying public land. The case shows how even apparently autonomist movements can through influence on state and societal actors contribute to state-based “policy currents” that flow in the direction of food sovereignty. This mutual codetermination by actors in and out of state institutions of the possibility and shape of “policy currents” renders state–society relations as important, even to those interested in (relative) autonomism. This paper thus leaves behind dichotomous interpretations of (and recommendations for) FSMs vis-à-vis autonomism, in order to unpack the influence (in thought) and impact (in action) of autonomist tendencies in food sovereignty construction.