全文获取类型
收费全文 | 2245篇 |
免费 | 305篇 |
国内免费 | 1275篇 |
专业分类
安全科学 | 142篇 |
废物处理 | 230篇 |
环保管理 | 243篇 |
综合类 | 1975篇 |
基础理论 | 472篇 |
污染及防治 | 629篇 |
评价与监测 | 61篇 |
社会与环境 | 61篇 |
灾害及防治 | 12篇 |
出版年
2024年 | 4篇 |
2023年 | 46篇 |
2022年 | 81篇 |
2021年 | 93篇 |
2020年 | 101篇 |
2019年 | 106篇 |
2018年 | 108篇 |
2017年 | 109篇 |
2016年 | 138篇 |
2015年 | 156篇 |
2014年 | 167篇 |
2013年 | 315篇 |
2012年 | 252篇 |
2011年 | 206篇 |
2010年 | 170篇 |
2009年 | 167篇 |
2008年 | 138篇 |
2007年 | 221篇 |
2006年 | 212篇 |
2005年 | 173篇 |
2004年 | 154篇 |
2003年 | 133篇 |
2002年 | 103篇 |
2001年 | 58篇 |
2000年 | 77篇 |
1999年 | 77篇 |
1998年 | 58篇 |
1997年 | 48篇 |
1996年 | 34篇 |
1995年 | 26篇 |
1994年 | 22篇 |
1993年 | 27篇 |
1992年 | 7篇 |
1991年 | 9篇 |
1990年 | 9篇 |
1989年 | 3篇 |
1988年 | 3篇 |
1987年 | 3篇 |
1986年 | 8篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有3825条查询结果,搜索用时 93 毫秒
731.
732.
733.
Understanding the degradation behavior of azo dyes in photocatalytic wastewater treatment is of fundamental and practical importance for their application in textile-processing and other coloration industries. In this study, quantum chemistry, as density functional theory, was used to elucidate different degradation pathways of azo pyridone dyes in a hydroxyl radical (HO?)-initiated photocatalytic system. A series of substituted azo pyridone dyes were synthesized by changing the substituent group in the para position of the benzene moiety, ranging from strong electron-donating to strong electron-withdrawing groups. The effect of dye molecular structure on the photocatalytic degradation reaction mechanism was analyzed and quantification of substituent effects on the thermodynamic and kinetics parameters was performed. Potential energy surface analysis revealed the most susceptible reaction site for the HO? attack. The calculated reaction barriers are found to be strongly affected by the nature of substituent group with a good correlation using Hammett σp constants and experimentally determined reaction rates. The stability of pre-reaction complexes and transition state complexes were analyzed applying the distortion-interaction model. The increased stability of the transition state complexes with the distancing from the substituent group has been established. 相似文献
734.
通过零价铁(ZVI)预厌氧与微生物燃料电池(MFC)的协同作用,研究其对单一基质碳源吲哚的降解特性、MFC产电性能及群落分析.结果表明:ZVI(4 g·L-1)的预厌氧可明显促进吲哚(250 mg·L-1)在MFC体系中的降解;其中吲哚与TOC在96 h内的降解率分别为97.17%和89.50%,且吲哚的降解符合一级反应动力学模型;体系中MFC最大输出电压和功率密度可达600 mV和439.55 mW·m-2;通过LC-MS分析,吲哚在协同体系中的主要中间代谢产物为靛红和水杨酸.高通量测序结果表明,ZVI预厌氧体系的引入有利于MFC体系中梭菌(Clostridium sensu stricto)、链霉菌(Streptomyces sp.)、热单胞菌(Thermomonas)的富集与吲哚的厌氧降解;同时促进假单胞菌(Pseudomonas)和梭菌等在代谢过程中的电子转移,提高了MFC的产电性能. 相似文献
735.
太阳光Fenton氧化对含酚废水生物降解影响研究 总被引:5,自引:2,他引:3
研究了太阳光Fenton氧化预处理对含酚废水生物降解性的影响及太阳光Fenton氧化-生化法联合工艺对煤气含酚废水的处理效果。结果表明,煤气含酚废水和模拟含酚废水的生物降解性均较差,太阳光Fenton氧化预处理可明显提高含酚废水的生物降解性,随着H2O2投加量的增加,废水的BOD5/COD比值逐渐增大,生物降解性明显增强。煤气含酚废水直接进行生化处理的COD和挥发酚去除率均较低。当太阳光Fenton氧化过程H2O2用量为22.5%理论投加量时,采用太阳光Fenton氧化-生化法联合工艺可使煤气含酚废水的COD由1357mg/L降低至104mg/L,挥发酚由198.2mg/L降低至0.47mg/L,COD和挥发酚均达到国家二级排放标准。 相似文献
736.
737.
通过向底泥中投加不同量的蔗糖使其发生厌氧反应以模拟不同程度的底泥厌氧环境,研究这种环境和光照强度对菹草石芽萌发和幼苗生理作用的影响。实验结果表明,底泥厌氧环境能显著降低菹草石芽的最终萌发率,且低光照会加剧这种趋势;尽管低光照不一定会提高最终的萌发率,但对提早石芽的萌发是有利的。在01%蔗糖投加处理中,幼苗的叶绿素和可溶性蛋白含量最高(平均为250和1928 mg/g FW),其后随投加量的升高而降低,而游离氨基酸的含量却一直呈上升趋势,最高时达到024 mg/g FW ,但低光照却使它下降;可溶性糖含量基本不受底泥厌氧水平的影响,但随着光照减少而降低。随着厌氧水平的增加(从对照到05%蔗糖投加量),菹草的超氧物歧化酶(SOD)活性呈现上升趋势,但在10%蔗糖投加处理中活性降至最低;而过氧化物酶(POD)活性一直处于下降趋势。研究结论是:底泥厌氧对菹草石芽萌发影响显著,这种影响可能比低光照的限制作用还要重要。轻度的厌氧环境反而能促进菹草幼苗的生理代谢,但随厌氧水平的升高对碳氮平衡和其它生理活动产生不利影响。此外,底泥厌氧环境对菹草幼苗的抗氧化系统也有明显刺激作用。 相似文献
738.
川江流域的土壤退化与防治 总被引:6,自引:0,他引:6
川江流域地区土壤退化按肥力因素分类,并以专家系统确定的指标分类统计表明:土壤物理性退化中以水分不调、过砂和板结化较严重;土壤结构性退化中,以土层浅薄化较显著;土壤营养性退化中,以缺硼、钼、磷较突出,成因主要是生态脆弱、土壤侵蚀作用和过渡开发利用,据此提出了防治退化的基本措施。并从持续发展角度提出了适应该区土壤退化特点的持续农业系统。 相似文献
739.
A. Parviz Koohafkan 《Natural resources forum》2000,24(2):69-81
Land degradation continues to be a major threat to local and national food security. With limited potential to develop new land, any increase in agricultural production must be sought largely through the better use of land already under cultivation. Concerns for the global environment associated with agriculture worldwide have also increased in recent years and require more coordinated efforts at global and national levels with decentralisation of activities at the local level.
This article presents an overview of land resources potential for food production, the processes and extent of land degradation and its economic and environmental costs and impacts, and highlights some macro-economic policies and institutional measures for the prevention of land degradation and rehabilitation of degraded lands. A people-centred programme is presented as a basis for decentralising activities for sustainable land use and land management. Finally, the need for better coordinated efforts of concerned UN, multinational agencies and NGOs for the implementation of Agenda 21 and related conventions is stressed. 相似文献
This article presents an overview of land resources potential for food production, the processes and extent of land degradation and its economic and environmental costs and impacts, and highlights some macro-economic policies and institutional measures for the prevention of land degradation and rehabilitation of degraded lands. A people-centred programme is presented as a basis for decentralising activities for sustainable land use and land management. Finally, the need for better coordinated efforts of concerned UN, multinational agencies and NGOs for the implementation of Agenda 21 and related conventions is stressed. 相似文献
740.
Carlos M. Duarte Daniel E. Canfield 《Journal of the American Water Resources Association》1990,26(6):927-934
ABSTRACT: A survey of 31 Florida spring-runs was conducted to estimate their submerged macrophyte standing crop and primary productivity. The standing crops of submerged vegetation were not significantly (p > 0.05) correlated to either total nitrogen (r = 0) or total phosphorus (r =?0.20) concentrations, but standing crops were significantly (p < 0.01) correlated to the percentage of the spring-run's water surface shaded by marginal vegetation (r =?0.76). Maximum daily rates of primary productivity were positively correlated with average submerged macrophyte standing crops (r = 0.81; p < 0.001) and inversely correlated with the degree of shading by marginal vegetation (r =? 0.43; p < 0.05). 相似文献