白腐真菌反应器处理废水的研究进展

介绍了白腐真菌的生物学特性及其降解污染物的优势,综述了生物转盘反应器、搅拌釜生物反应器、气升式生物反应器、流化床生物反应器、填充床生物反应器、转管生物反应器、空心纤维反应器等白腐真菌反应器的结构特点和在废水处理方面的研究进展,指出了目前白腐真菌反应器应用中存在的问题。     

不同共代谢基质对白腐菌降解吲哚的作用研究

选用氨氮、苯酚和喹啉作为吲哚的共代谢基质,通过白腐菌BP对共基质体系的降解研究了白腐菌在秸秆滤出液培养基中对不同共基质体系的代谢过程,并进行了动力学分析,考察了不同共代谢基质物质对白腐菌漆酶分泌和吲哚降解的影响.结果显示,不同降解体系中的白腐菌都可去除99%以上的吲哚.充分的氮源可提高白腐菌的活性和漆酶酶活的峰值;共基质苯酚和喹啉可以增加白腐菌漆酶产量,为吲哚的降解提供较多的电子,同时苯酚和喹啉也能得到较高的去除.在秸秆滤出液中,白腐菌在pH为6～8之间对吲哚都具有较强的降解能力.吲哚在白腐菌的代谢过程中,可能首先在吡啶环的2和3位发生一步羰基化.     

Distribution of White Whales (Delphinapterus leucas) in the White Sea and the Southeastern Region of the Barents Sea during the Ice Season

The habitats, relative occurrence, and distribution of the white whale in the White Sea and the southeastern Barents sea in every month of the ice season have been studied using the results of an aerial ice survey along standard routes from 1970–1991. In these seas, white whales have been found in each month of the ice season, with single animals, groups, schools or gams, herds, and large congregations of several hundred animals accounting for 10, 22.8, 47.2, 12.9, and 7% of all aggregations of white whales observed, respectively. The relative occurrence of white whales in the White Sea is higher in March and May (32.5 and 30%, respectively) and lower in February, January, and November (15, 10, and 7.5%, respectively); in December and April, the whales are observed very seldom (2.5% in both months). In the southeastern Barents Sea, the relative occurrence of white whales is highest in May (53.3%) and considerably lower in December and February (16.7 and 10%); only a few animals are found during the remaining ice season. Regarding different habitats, the relative occurrences of white whales in open water, in water openings in the ice, near the edge of pack ice, and in ice packs with different degrees of closeness are 21.5, 11.4, 45.7, and 21.4%, respectively.     

白腐真菌对染料脱色及降解过程机理和影响因素

许多白腐真菌对染料具有广谱的脱色和降解能力 ,其脱色及降解作用可能主要是由于其在次生代谢阶段产生的木质素过氧化酶LiPs和锰过氧化酶MnPs所致。培养条件对白腐真菌脱色及降解活性有较大的影响 ,在培养基中加入藜芦醇和二价锰等能够显著提高木质素过氧化酶的产生 ;富氮培养基会抑制LiPs的生成 ;硫脲、叠氮化物、氰化物等均能明显地抑制白腐真菌的脱色及降解活性 ;缓冲液的选择对维持稳定的 pH值和菌丝的形态有一定作用 ,从而影响其脱色效果 ;富氧环境是一切白腐真菌对染料进行脱色和降解的必要条件 ;适度的搅拌混合有利于反应时的物质之间传递 ;一般地 ,在培养时间达到 3天以后白腐真菌才能达到较高的脱色与降解活性。染料分子大小和结构及其基团的位置对脱色及降解效果有明显影响。使用特殊填料极大地提高处理系统中的生物量以克服真菌生长速度相对较慢、提高处理能力是该技术今后的研究重点。     

市场机制在白色污染物回收处置中的应用探讨——以上海一次性塑料餐具废弃物为例

近10年来上海城市生活垃圾组分中,以塑料为代表的包装废物的组分份额上升趋势尤为显著;上海GDP持续高速增长,但单位GDP城市废弃物清运量的下降率却显著低于GDP的年均增长率,一定程度上说明环卫行业的投资渠道较为单一,缺乏竞争和优化配置的市场机制;上海各类废弃塑料主要流向江浙一带,进行小规模低技术层次的加工处理,容易形成隐蔽的废品交易暗流;造成“白色污染”屡禁不止的重要原因是忽视了基于生产者责任的市场调控机制,社会化的回收体系薄弱;上海从2000年10月起,对一次性塑料餐具的回收处置建立了基于生产者责任的市场机制,由于一次性塑料饭盒的区域回收网络建设滞后,实施的效果有效但仍有限.     

Biologically active secondary metabolites in white clover (Trifolium repens L.) – a review focusing on contents in the plant, plant–pest interactions and transformation

Summary.  To exploit biologically active compounds from white clover (Trifolium repens L.) for suppressing weeds and soil-borne diseases, either as isolated products (biopesticides) or through cultivars with enhanced production of these compounds, the biologically active compounds must be identified, plant content measured, and their fate in soil known. The present review summarizes the published knowledge needed for such exploitation; providing essential information on structure and concentration of flavonols, flavones, condensed tannins, isoflavones, isoflavanones, pterocarpans, coumestans, cyanogenic glucosides, and saponins in healthy and stressed white clover plants. Various stresses and particular cultivars affect the concentrations of several of the compounds. Information on biological effects and the degradation/transformation of these compounds in plants or by microorganisms is available. There is no information on the degradation pathway in soil, the mechanisms of exudation and leaching of compounds from plants, and soil sorption properties of the compounds. The clover soil fatigue problem is increasing in grasslands and causes problems especially in organic farming. Research efforts focused on biological elements of clover soil fatigue have not explained it, and the influence of secondary metabolites has not been investigated. There are few investigations into the interaction between beneficial fungi/fungal-diseases and the occurrence of biologically active secondary metabolites in white clover plants. Such studies are critical to better understand beneficial fungi and pathogens.     

非灭菌环境投加染料时间对白腐真菌降解活性染料的影响

应用氮限制液体培养基(C/N=56／8．7)研究了非灭菌环境投加染料时间对白腐真菌Phanerochaete chrysosporium降解活性艳红K-2BP染料的影响．试验结果表明,纯培养2d和3d后,在非灭菌环境投加活性艳红K-2BP染料的体系脱色率与在灭菌环境投加该染料的体系基本相当,其5d脱色率在90％以上;而纯培养ld时在非灭菌环境投加染料体系的脱色率却只有8l％．引起纯培养ld体系脱色率降低的主要原因是活性艳红K-2BP对白腐真菌Phanerochaete chrysosporium的生长有抑制作用和反应体系感染了酵母菌．但是,如果纯培养延长至2d以后,由于白腐真菌菌丝体已在体系内占优势,尽管在非灭菌环境下还有酵母菌侵入,但它不会占优势,从而也就不会影响白腐真菌对染料的降解作用．因此,在氮限制液体培养基中,只要白腐真菌Phanerochaete chrysosporium在反应体系占优势,就可以适当缩短纯培养时间,提前在非灭菌环境投加染料,使白腐真菌Phanerochaete chrysosporium的培养和对活性染料的脱色同步进行．     

Laser tempering based turning process for efficient machining of hardened AISI 52100 steel

Cost-effective machining of hardened steel components such as a large wind turbine bearing has traditionally posed a significant challenge. This paper presents an approach to machine hardened steel parts efficiently at higher material removal rates and lower tooling cost. The approach involves a two-step process consisting of laser tempering of the hardened workpiece surface followed by conventional machining at higher material removal rates with lower cost ceramic tools to efficiently remove the tempered material. The laser scanning parameters that yield the highest depth of tempered layer are obtained from a kinetic phase change model. Machining experiments are performed to demonstrate the possibility of higher material removal rates and improved tool wear behavior compared to the conventional hard turning process. Tool wear performance, cutting forces, and surface finish of Cubic Boron Nitride (CBN) tools as well as low cost ceramic tools are compared in machining of hardened AISI 52100 steel (~63 HRC). In addition, cutting forces and surface finish are compared for the laser tempering based turning and conventional hard turning processes. Experimental results show the potential benefits of the laser tempering based turning process over the conventional hard turning process.     

施加Fe3O4/桑树杆生物炭对土壤砷形态和水稻砷含量的影响

以桑树杆为生物炭原料,制备Fe₃ O₄/桑树杆生物炭(Fe-MBC).通过土壤培养试验,研究不同炭化温度下制备的Fe-MBC对土壤有效态As含量的钝化效果,筛选出钝化效果好的Fe-MBC-800(800℃下炭化制备)并对其进行表征.通过盆栽试验,研究Fe-MBC-800添加比例为1%~7%(质量分数)时,其对种植水稻后土壤pH值、土壤电导率(EC)、土壤As形态、水稻生物量和水稻总As含量的影响.结果表明:①Fe-MBC-800成功负载了Fe₃ O₄,其主要官能团有C=O双键、O-H键、C-O键和Fe-O键; Fe-MBC-800、MBC-800和Fe₃ O₄的比表面积分别为209.659、517.714和68.025 m² ·g^-1.②添加Fe-MBC-800可提高土壤pH值,降低土壤EC值,提高土壤残渣态As含量,降低土壤水溶态As含量和土壤有效态As含量; 土壤中添加7%的Fe-MBC-800后,水溶态As含量和土壤有效态As含量分别降低了81.6%和56.33%.③土壤中Fe-MBC-800的添加比例为5%~7%时,能促进水稻植株的生长,提高水稻生物量,使水稻植株As的累积降低了62.5%~68.75%.     

丢糟和副产硫酸生产白炭黑的工艺研究

利用酒糟锅炉燃烧后的丢糟灰为原料,以氯碱企业中氯气干燥后产生的副产硫酸为酸化剂,采用沉淀法对白炭黑制备的工艺进行了试验研究.结果表明,采用沉淀法制备白炭黑工艺条件为:丢糟灰碱液比为1∶1.4,碱化处理时间4h,加酸速度为0.06 mL/g·min,搅拌速度40 r/min,产物比表面积为189.0m2/g,制备的白炭黑经质量检测符合国家产品标准.