Enhanced photocatalytic activity of TiO2 by surface fluorination in degradation of organic cationic compound

Experiments were carried out to investigate the influence of TiO2 surface fluorination on the photodegradation of a representative organic cationic compound, Methylene Blue （MB）. The eleetropositive MB shows poor adsorption on TiO2 surface; its degradation performs a HO. radical-mediated mechanism. In the F-modified system, the kinetic reaction rate enlarged more than 2.5 fold that was attributed mainly to the accumulating adsorption of MB and the increased photogenerated hole available on the F-modified TiO2 surface.     

Dechlorination of carbon tetrachloride by the catalyzed Fe-Cu process

The electrochemical reduction characteristics of carbon tetrachloride (CT) were investigated using cyclic voltammetry in this study. In addition, the difference in reduction mechanisms of CT between Master Builders' iron and the catalyzed Fe-Cu process was discussed. The results showed that CT was reduced directly on the surface of copper rather than by atomic hydrogen produced at the cathode in the catalyzed Fe-Cu process. The reduction was realized largely by atomic hydrogen in Master Builders' iron. The entire CT in 350 ml aqueous solution with 320 mgL was reduced to trichloromethane and dichloromethane in 2.25 h when 100 g of scrap iron with FeCu ratio of 10:1 (ww) were used. Moreover, the reduction rate slowed with time. CT could be reduced at acidic, neutral and alkaline pH from solution by Fe-Cu bimetallic media, but the mechanisms were di?erent. The degradation rate was not significantly in?uenced by pH in the catalyzed Fe-Cu process; in Master Builders' iron it clearly increased with decreasing pH. The kinetics of the reductions followed pseudo-first order in both cases. Furthermore, the reductions under acidic conditions proceeded faster than that under the neutral and alkaline conditions. The catalyzed Fe-Cu process was superior to Master Builders' iron in treating CT-containing water and this advantage was particularly noticeable under alkaline conditions. The reduction was investigated in the cathode (Cu) and anode (Fe) compartments respectively, the results showed that the direct reduction pathway played an important role in the reduction by the catalyzed Fe-Cu process. The catalyzed Fe-Cu process is of practical value.     

Degradation of MTBE and TBA by a new isolate from MTBE-contaminated soil

Methyl ten-butyl ether （MTBE）, a gasoline additive, possesses serious problems to the environmental health. In the present study, a bacterial culture named A-3 which could effectively degrade MTBE was isolated from the MTBE contaminated soil. The isolate was identified as Chryseobacterium sp., a new species capable of degrading MTBE. In order to enhance its degradation ability, selected environment factors were investigated. The results showed that the optimal temperature was in the range of 25-30℃, the pH was 7.0, the inoculum size was 2 × 10^8 CFU/ml and the optimal concentration of MTBE was from 50 to 100 mg/L. The maximum MTBE utilization rate （Vmax） was 102 nmol MTBE/（mg cell protein.h）. Furthermore, it was found that the isolate could also degrade tert-butyl alcohol （TBA）. The degradation rates of TBA were much faster than those of MTBE. The additional TBA would lead to the decrease of the initial MTBE degradation rate and the inhibitory effect of TBA increased with the increase of TBA concentration. Similar protein profiles at least seven peptides were demonstrated after SDS-PAGE analysis of crude extracts obtained from the cells growing in MTBE and TBA culture.     

Effect of copper on the degradation of pesticides cypermethrin and cyhalothrin

The influence of coexisting copper (Cu) ion on the degradation of pesticides pyrethroid cypermethrin and cyhalothrin in soil and photodegradation in water system were studied.Serial concentrations of the pesticides with the addition of copper ion were spiked in the soil and incubated for a regular period of time,the analysis of the extracts from the soil was carried out using gas chromatography (GC).The photodegradation of pyrethroids in water system was conducted under UV irradiation.The effect of Cu~(2 ) on the pesticides degradation was measured with half life (t_(0.5)) of degradation.It was found that a negative correlation between the degradation of the pyrethroid pesticides in soil and Cu addition was observed.But Cu~(2 ) could accelerate photodegradation of the pyrethroids in water.The t_(0.5) for cyhalothrin extended from 6.7 to 6.8 d while for cypermethrin extended from 8.1 to 10.9 d with the presence of copper ion in soil.As for photodegradation,t_(0.5) for cyhalothrin reduced from 173.3 to 115.5 rain and for cypermethrin from 115.5 to 99.0 min.The results suggested that copper influenced the degradation of the pesticides in soil by affecting the activity of microorganisms.However, it had catalyst tendency for photodegradation in water system.The difference for the degradation efficiency of pyrethroid isomers in soil was also observed.Copper could obviously accelerate the degradation of some special isomers.     

我国安全生产基本特征规律研究

从经济社会发展视角,分析安全生产基本特征规律,指出安全生产随产业结构呈现不均衡分布特点,劳动力结构制约安全生产,城市化进程增加安全生产不稳定因素.安全生产与GDP对比分析表明,党和国家采取的一系列重大措施有效抑制了经济快速增长给安全生产带来的负面作用,我国安全生产提前进入事故波动期.通过研究区域经济与安全生产关系,得出我国4大经济区域社会经济发展水平与安全生产之间存在规律性分布特征.该研究的成果为建立安全生产长效机制,实现我国经济社会与生产安全协调发展探讨新的途径.     

水害死了他

大家都知道,水是重要的灭火介质之一。它有4大作用,一是冷却作用;二是对氧的稀释（隔绝）作用;三是对水溶性液体的稀释作用;四是水力冲击作用。一般情况下,灭火主要是利用水的冷却作用,但如果使用不对,这一冷却作用同样可以“杀人”。在一次灭火的时候,水的冷却作用就害死了我的一位朋友。     

湿法烟气脱硫系统优化控制的仿真研究

通过对湿法烟气脱硫系统中的各种运行控制参数进行综合优化,开发了湿法烟气脱硫系统优化控制的仿真软件.该仿真软件对提高湿法烟气脱硫效率和降低运行费用具有一定的指导作用.     

溶菌酶及其在环境工程中的应用研究

文章对溶菌酶的结构特点、作用机制、提取制备、酶活力的测定方法做了简要介绍,并探讨了溶菌酶在环境工程中的应用研究。     

大麦秸秆化感作用方法对农村饮水水源的藻类控制分析

就缺水地区农村饮水水源中藻类控制,介绍了生物化感作用这一处理方法及其原理,提出使用大麦秸秆来进行农村小型池塘的藻类控制方法。实验结果表明,此方法操作简便、效果明显,并具有管理维护简单、运行费用低廉等优势,值得在农村或山区等缺水地区大力推广。     

经济增长方式转变与节约利用土地研究

在当前努力实现经济增长方式转变的过程中,经济方式的转变与节约利用土地资源的关系有待探讨。经济增长方式的本质内容是生产要素的组合和使用方式。转变经济增长方式,即从依靠生产要素的数量扩张而实现的粗放型经济增长,转变为依靠生产要素的效率提高而实现的集约型经济增长[1]。土地作为社会经济发展的重要要素之一,对土地资源的节约利用是实现集约型经济增长的重要内容之一,同时节约利用土地资源对经济增长方式的转变起着重要的促进作用。