全文获取类型
收费全文 | 1975篇 |
免费 | 226篇 |
国内免费 | 817篇 |
专业分类
安全科学 | 142篇 |
废物处理 | 323篇 |
环保管理 | 187篇 |
综合类 | 1493篇 |
基础理论 | 176篇 |
污染及防治 | 640篇 |
评价与监测 | 52篇 |
灾害及防治 | 5篇 |
出版年
2024年 | 16篇 |
2023年 | 74篇 |
2022年 | 111篇 |
2021年 | 113篇 |
2020年 | 113篇 |
2019年 | 105篇 |
2018年 | 96篇 |
2017年 | 87篇 |
2016年 | 94篇 |
2015年 | 116篇 |
2014年 | 176篇 |
2013年 | 128篇 |
2012年 | 135篇 |
2011年 | 116篇 |
2010年 | 118篇 |
2009年 | 112篇 |
2008年 | 128篇 |
2007年 | 128篇 |
2006年 | 113篇 |
2005年 | 125篇 |
2004年 | 120篇 |
2003年 | 104篇 |
2002年 | 97篇 |
2001年 | 71篇 |
2000年 | 69篇 |
1999年 | 58篇 |
1998年 | 38篇 |
1997年 | 50篇 |
1996年 | 39篇 |
1995年 | 34篇 |
1994年 | 25篇 |
1993年 | 20篇 |
1992年 | 18篇 |
1991年 | 24篇 |
1990年 | 27篇 |
1989年 | 19篇 |
1988年 | 1篇 |
排序方式: 共有3018条查询结果,搜索用时 46 毫秒
101.
102.
103.
104.
针对不锈钢产品酸洗处理过程中产生的氮氧化物浓度高、对大气污染的影响大、且难于净化治理等特性,在上海某不锈钢项目中设计了一套酸雾净化系统。该设计解决了酸洗中产生的氮氧化物难以净化的问题,提升了氮氧化物处理技术,它将成为不锈钢酸洗行业中氮氧化物净化处理技术的发展方向。 相似文献
105.
Catalytic bubble-free hydrogenation reduction of azo dye by porous membranes loaded with palladium (Pd) nanoparticles was studied for the first time. The effects of Pd loading, dye concentration and reuse repetitions of membranes were investigated. In reduction, the dye concentration decreased whereas the pH rose gradually. An optimal Pd loading was found. The catalytic membranes were able to be reused more than 3 times. 相似文献
106.
Photocatalytic ozonation of phenol and oxalic acid (OA) was conducted with a Ag^+/TiO2 catalyst and different pathways were found for the degradation of different compounds. Ag^+ greatly promoted the photocatalytic degradation of contaminants due to its role as an electron scavenger. It also accelerated the removal rate of OA in ozonation and the simultaneous process for its complex reaction with oxalate. Phenol could be degraded both in direct ozonation and photolysis, but the TOC removal rates were much higher in the simultaneous processes due to the oxidation of hydroxyl radicals resulting from synergetic effects. The sequence of photo-illumination and ozone exposure in the combined process showed quite different effects in phenol degradation and TOC removal. The synergetic effects in different combined processes were found to be highly related to the properties of the target pollutants. The color change of the solution and TEM result confirmed that Ag+ was easily reduced and deposited on the surface of Tit2 under photo-illumination, and dissolved again into solution in the presence of ozone. This simple cycle of enrichment and distribution of Ag^+ can greatly benefit the design of advanced oxidation processes, in which the sequences of ozone and photo-illumination can be varied according to the needs for catalyst recycling and the different properties of pollutants. 相似文献
107.
Catalytic oxidation is widely used in pollution control technology to remove volatile organic compounds. In this study, Pd/ZSM-5 catalysts with different Pd contents and acidic sites were prepared via the impregnation method. All the catalysts were characterized by means of N2 adsorption- desorption, X-ray fluorescence (XRF), HE temperature programmed reduction (H2-TPR), and NH3 temperature programmed desorption (NH3-TPD). Their catalytic performance was investigated in the oxidation of butyl acetate experiments. The by-products of the reaction were collected in thermal desorption tubes and identified by gas chromatography/mass spectrometry. It was found that the increase of Pd content slightly changed the catalytic activity of butyl acetate oxidation according to the yield of CO2 achieved at 90%, but decreased the cracking by-products, whereas the enhancement of strong acidity over Pd-based catalysts enriched the by-product species. The butyl acetate oxidation process involves a series of reaction steps including protolysis, dehydrogenation, dehydration, cracking, and isomerization. Generally, butyl acetate was cracked to acetic acid and 2- methylpropene and the latter was an intermediate of the other by-products, and the oxidation routes of typical by-products were proposed. Trace amounts of 3-methylpentane, hexane, 2-methylpentane, pentane, and 2-methylbutane originated from iso4merization and protolysis reactions. 相似文献
108.
Mo-modified Pd/Al2O3catalysts were prepared by an impregnation method and tested for the catalytic combustion of benzene. The catalysts were characterized by N2 isothermal adsorption, X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS), temperatureprogrammed desorption of NH3(NH3-TPD), H2temperature-programmed reduction(H2-TPR), and high-angle annular dark-field scanning transmission electron microscopy(HAADF-STEM). The results showed that the addition of Mo effectively improved the activity and stability of the Pd/Al2O3catalyst by increasing the dispersion of Pd active components, changing the partial oxidation state of palladium and increasing the oxygen species concentration on the surface of catalyst. In the case of the Pd-Mo/Al2O3catalyst,benzene conversion of 90% was obtained at temperatures as low as 190°C, which was 45°C lower than that for similar performance with the Pd/Al2O3catalyst. Moreover, the 1.0% Pd-5% Mo/Al2O3catalyst was more active than the 2.0% Pd/Al2O3catalyst. It was concluded that Pd and Mo have a synergistic effect in benzene catalytic combustion. 相似文献
109.
目前针对加装FBC-DPF(燃油添加剂-柴油机颗粒捕集器)后的柴油机放特性研究较少,并且缺乏FBC-DPF对颗粒物中PAHs排放量的影响效果研究.为全面评估加装FBC-DPF后柴油机颗粒物排放特性和FBC-DPF对柴油机尾气中的颗粒物排放污染控制效果,在发动机台架上对装有FBC-DPF的重型柴油机进行了颗粒物排放特性试验.利用电子低压撞击仪(ELPI)测量加装FBC-DPF前、后柴油机颗粒物的数浓度与粒径分布,用玻璃纤维滤膜采集加装FBC-DPF前、后尾气中的固相PAHs,利用色谱质谱联用仪对加装FBC-DPF前、后尾气中的固相PAHs进行定量分析.结果表明:①加装FBC-DPF后柴油机排放的颗粒物数浓度大幅降低,FBC-DPF对尾气中颗粒物的捕集效率平均值在95%左右;②加装FBC-DPF后柴油机固相PAHs总比排放量有所降低,在大负荷区域降幅在25.0%~88.0%之间;③加装FBC-DPF前的颗粒物中位直径为30~89 nm,而加装FBC-DPF后的颗粒物中位直径为41~98 nm,平均增幅为38.2%.对于国Ⅳ及未来国Ⅴ柴油机排放法规,FBC-DPF是解决柴油机颗粒物排放的有效手段;此外,FBC-DPF可以大幅降低柴油机尾气中的有毒成分,并且能够适应高含硫量的燃油环境. 相似文献
110.
室外空气不好,也影响车内空气质量,不少车主安装车载空气净化器来抵抗雾霾侵袭,希望以此降低车内PM2.5污染。
市场上销售的大部分车载空气净化器都声称具有除甲醛、去异味、除PM2.5等功能。专家指出,大部分车载空气净化器由于受功率等因素制约,去除PM2.5的功能有限,效果不如车载空调的内循环系统。 相似文献