巴东组紫红色泥岩干湿循环强度弱化特性的试验研究

三峡库区发育有大量三叠系巴东组第四段紫红色泥岩(T_2b~4,简称为巴东组紫红色泥岩),受库水位升降的影响其强度易弱化而影响库岸边坡的稳定性,开展三峡库区巴东组紫红色泥岩强度弱化特性的研究可为相关工程地质条件的评价提供参考。首先,依次开展了干湿循环试验和三轴压缩试验,分析巴东组紫红色泥岩的强度弱化特性,并通过CT扫描试验观察试样表面与内部的细观损伤特性;其次,基于CT扫描重构模型,开展了考虑试样内部初始损伤的三轴压缩条件下数值模拟试验;最后,基于岩石的变形特征,提出考虑岩石变开过程压密阶段的能量消耗的一种新的能量耗散模型。试验结果表明:0～10 kPa预应力下的干湿循环试验只对试样表面粗糙度有轻微的影响;干湿循环条件下,试样的峰值强度和残余强度与干湿循环次数呈负线性相关;基于CT扫描重构模型的试样三轴压缩数值模拟试验结果与室内三轴压缩试验结果具有较好的一致性,能体现试样内部的初始损伤特性,更符合实际;改进后的能量耗散模型适合于分析考虑岩石压密阶段的变形过程。     

Synthesis and enhanced visible-light responsive of C,N,S-tridoped TiO2 hollow spheres

C,N,S-tridoped TiO2 hollow spheres （labeled as C,N,S-THs） were synthesized using carbon spheres as template and C,N,S-tridoped TiO2 nanoparticles as building blocks. The structure and physicochemical properties of the catalysts were characterized by X- ray diffraction （XRD）, scanning electron microscopy （SEM）, UV-Vis diffuse reflectance spectrum （DRS）, N2 adsorption-desorption isotherms, X-ray photoelectron spectroscopy （XPS） and Photoluminescence emission spectroscopy （PL）. The results showed that the hollow spheres had average diameter of about 200 nm and the shell thickness was about 20 nm. The tridoped TiO2 hollow spheres exhibited strong absorption in the visible-light region. C,N,S-tridoped could narrow the band gap of the THs by mixing the orbit O 2p with C 2p, N 2p and S 3p orbits and shift its optical response from ultraviolet （UV） to the visible-light region. PL analysis indicated that the electron-hole recombination rate of TiO2 hollow spheres had been effectively inhibited when doped with C, N and S elements. The photocatalytic activities of the samples were evaluated for the degradation of X-3B （Reactive Brilliant Red dye, C.I. Reactive Red 2） aqueous solution under visible-light （λ 〉 420 nm） irradiation. It was found that the C,N,S-tridoped TiO2 hollow spheres indicated higher photocatalytic activity than commercial P25 and the undoped counterpart photocatalyst.     

化学沉淀法去除稀土湿法冶炼废水中钙与高浓度氨氮研究

离子型稀土湿法冶炼过程中会产生大量氨氮废水,由于废水中含有大量Ca2+,而Ca2+是影响磷酸铵镁沉淀法脱氮效率的重要因素.向废水中投入Na2CO3固体生成CaCO3沉淀物,去除废水中的Ca2+,再利用磷酸铵镁(MAP)沉淀法去除废水中的氨氮.实验采用响应面实验设计方法中的中心复合设计法,利用响应面分析法对磷酸铵镁沉淀法反应参数进行优化,得到最优反应条件及最优反应条件下沉淀产物.利用扫描电子显微镜(SEM)及X射线衍射(XRD)对最优反应条件下两种沉淀物进行分析.结果表明,当n(Ca2+)∶n(CO23-)=1∶1.05,搅拌速率为1 500 r.min-1,反应时间为30 min时,Ca2+去除率接近100%;对除钙后废水进行磷酸铵镁法脱氮处理的最优反应条件为:pH=9.03,n(Mg)∶n(N)=1.20,n(P)∶n(N)=1.1,反应时间为30 min,搅拌速率为1 000 r.min-1,氨氮去除率达到95.40%,剩余总磷浓度为5.65 mg.L-1;沉淀物分别为纯净的CaCO3及MgNH4PO4.6H2O.     

安讯士推出高感光度监控摄像机

全球网络视频领先厂商─安讯士网络通讯公司(Axis Communications),日前对外正式推出一款集成安讯士最新"觅光者"技术、且性能杰出的固定型网络摄像--AXIS Q1602系列网络摄像机。AXIS Q1602/-E无论在室内还是室外,     

中国应该尽早出台自己的RFID标准

顾客推着满车物品走近付账台,先进的RFID(射频识别)系统能远距离一举扫描所有物品标签,让超市从此告别排队.目前,已有中国企业掌握该技术,但因制定统一标准滞后,它们很可能在5年错失28亿美元市场.     

Functionalized CMK-3 mesoporous carbon with 2-amino-5-mercapto-1,3,4-thiadiazole for Hg(II) removal from aqueous media

Ordered mesoporous carbon（CMK-3） was synthesized and functionalized with 2-amino-5-mercapto-1,3,4-thiadiazole groups（AMT-OCMK-3） for Hg（Ⅱ） removal from aqueous solution. The modified CMK-3 was characterized by X-ray diffraction, N2adsorption-desorption isotherm, scanning electron microscopy and Fourier transform infrared spectroscopy. The effects of solution pH, contact time, initial Hg（Ⅱ） concentration and matrix effect were studied. The adsorption data were successfully fitted with the Langmuir model, exhibiting high adsorption capacity of 450.45 mg/g of AMT-OCMK-3. In the solid-phase extraction system a series of experimental parameters such as sample flow rate, sample volume,eluent volume and concentration of the eluent solution have been investigated and established for preconcentration of Hg（Ⅱ） in aqueous solution. The results showed that the enrichment factor for Hg（Ⅱ） was 250, the precision（relative standard deviation（RSD）, %） for six replicate measurements was 2.05% and the limit of detection for Hg（Ⅱ） was achieved at0.17 μg/L.     

Removal of cobalt(Ⅱ) ion from aqueous solution by chitosan-montmorillonite

Montmorillonite （MMT） modified with chitosan （CTS, molecular weight = S x 104） was applied to remove heavy metal cations by using Co2＋ as a model ion. An increase in MMT interlayer distance observed from X-ray diffraction indicates the intercalation of CTS into MMT. Together with the results of scanning electron microscopy and Fourier transform infrared spectroscopy, it was concluded that the composite material of CTS and MMT （CTS-- MMT） was prepared successfully. The mass ratio of CTS to MMT had a strong influence on the adsorption performance of CTS-MMT. The highest adsorption value of 150 mg/g was obtained over the composite material with CTS to MMT mass ratio of 0.25, which is much higher than those reported in other studies. The adsorption isotherms and kinetic results indicated that Co2＋ was adsorbed over CTS-MMT in a multilayer model, and the chemical sorption of Co2＋ was determined to be the rate-limiting step.     

臭氧氧化四种偶氮染料废水的效果研究

以酸性大红、中性枣红、阳离子红、活性黑5四种模拟印染废水开展O3氧化偶氮染料的效果研究.实验中发现O3对染料具有非常好的脱色效果,30 min后除中性枣红外其他三种染料脱色率接近100％,但是单独O3的TOC去除率不高.光谱扫描表明,处理后染料的特征吸收峰很快消失,而紫外光区的吸收峰变化很小,推测O3氧化以直接氧化为主,打开了染料分子的发色基团,但并未将染料分子彻底氧化.还应加强O3氧化能力、彻底矿化去除污染物的研究.     

环球扫描

<正>白蚁蚁穴可以预测气候变化美国卡内基研究所全球生态系的科学家通过对南非克鲁格国家公园192平方英里(约497平方公里)内的4万多座蚁穴定位研究发现,根据白蚁筑巢的形状大小就可以预测非洲草原地区的气候变化。考虑到非洲草原丛林茂密,难以绘制地图,科学家们使用Carnegie Airborne Observatory(CAO)系统绘制了一个非洲草原的3D植被地形图。CAO是一种空中绘图系统,可以穿透树丛对地面进行扫描,     

3D打印——哆啦A梦的口袋

在人们对3D打印技术还不太熟悉的时候,设计师们通过它已经可以打印出会飞的飞机、能吃的蛋糕、可以穿的衣服和鞋子,甚至可以"克隆"出另一个自己……3D打印,大家也许略有耳闻,然而相信大部分从却未见其真面目。前段时间在全国热映的大片《十二生肖》中,成龙戴一副白手套,摸了摸国宝十二生肖的头像,就把头像的数据扫描进了电脑。与此同时,他的伙伴在一台神奇的机器里,瞬间就把一个一模一样的兽首制造出来。你可能认为这种神奇的技