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161.
Biosorption of silver ions onto Bacillus cereus biomass was investigated. Overall kinetic experiments were performed for the
determination of the necessary contact time for the attainment of equilibrium. It was found that the overall biosorption process was
best described by pseudo second-order kinetic model. The crystals detected by scanning electron microscope and X-ray photoelectron
spectroscopy suggested the precipitation was a possible mechanism of biosorption. The molecular genetics of silver resistance of B.
cereus biomass was also detected and illustrated by a whole cell sensor tool. 相似文献
162.
Tao Zhang Qiucheng Li Lili Ding Hongqiang Ren Ke Xu Yonggang Wu Dong Sheng 《环境科学学报(英文版)》2011,23(6):881-890
Chemical precipitation to form magnesium ammonium phosphate (MAP) is an effective technology for recovering ammonium
nitrogen (NH4
+-N). In the present research, we investigated the thermodynamic modeling of the PHREEQC program for NH4
+-N
recovery to evaluate the effect of reaction factors on MAP precipitation. The case study of NH4
+-N recovery from coking wastewater
was conducted to provide a comparison. Response surface methodology (RSM) was applied to assist in understanding the relative
significance of reaction factors and the interactive effects of solution conditions. Thermodynamic modeling indicated that the saturation
index (SI) of MAP followed a polynomial function of pH. The SI of MAP increased logarithmically with the Mg2+/NH4
+ molar ratio
(Mg/N) and the initial NH4
+-N concentration (CN), respectively, while it decreased with an increase in Ca2+/NH4
+ and CO3
2??/NH4
+
molar ratios (Ca/N and CO3
2??/N), respectively. The trends for NH4
+-N removal at different pH and Mg/N levels were similar to the
thermodynamic modeling predictions. The RSM analysis indicated that the factors including pH, Mg/N, CN, Ca/N, (Mg/N) (CO3
2??/N),
(pH)2, (Mg/N)2, and (CN)2 were significant. Response surface plots were useful for understanding the interaction effects on NH4
+-N
recovery. 相似文献
163.
在突发环境污染事件和区域生态风险筛查中迫切需要环境样品中重金属离子的快速检测技术手段。环境样品中重金属离子的快速检测技术有电化学方法和生物学方法。电化学检测方法主要是阳极溶出伏安法(AnodicStripping Voltammetry,ASV),可以同时检测多种重金属离子,有标准化认证的产品,但是检测成本相对较高。随着纳米粒子技术(Nanoparticles,NPs)和石英微天平分析技术(Quartz Crystal Microbalance,QCM)的引入,ASV法的检测成本将不断降低;生物检测方法包括免疫检测(Immunoassay,IA)和功能DNA(Functional DNA)检测技术。重金属离子的免疫检测技术样品通量大,检测成本低,已经广泛用于食品行业,其中汞离子的免疫检测方法已经成为环境样品标准检测方法之一。免疫检测传感器技术将拓展重金属离子的快速检测的应用空间。功能DNA传感器检测的研究为重金属离子的快速检测提供了新的技术手段,但是这些仅限于实验室研究,还没有达到实际应用的水平。 相似文献
164.
165.
166.
167.
168.
The brominated products, formed in chlorination treatment of benzophenone-4 in the presence of bromide ions, were identified, and the formation pathways were proposed.Under disinfection conditions, benzophenone-4 would undertake electrophilic substitution generating mono- or di-halogenated products, which would be oxidized to esters and further hydrolyzed to phenol derivatives. The generated catechol intermediate would be transformed into furan-like heterocyclic product. The product species were p H-dependent,while benzophenone-4 elimination was chlorine dose-dependent. When the chlorination treatment was performed on ambient water spiked with benzophenone-4 and bromide ions, most of brominated byproducts could be detected, and the acute toxicity significantly increased as well. 相似文献
169.
Mengnjo J. Wirmvem Takeshi Oh Wilson Y. Fantong Samuel N. Ayonghe Jonathan N. Hogarh Justice Y. Suil Asobo Nkengmatia E. Asaah Seigo Ooki Gregory Tanyileke Joseph V. Hell 《环境科学学报(英文版)》2014,26(4):801-809
Rainwater characteristics can reveal emissions from various anthropogenic and natural sources into the atmosphere. The physico-chemical characteristics of 44 monthly rainfall events (collected between January and December 2012) from 4 weather stations (Bamenda, Ndop plain, Ndawara and Kumbo) in the Bamenda Highlands (BH) were investigated. The purpose was to determine the sources of chemical species, their seasonal inputs and suitability of the rainwater for drinking. The mean pH of 5 indicated the slightly acidic nature of the rainwater. Average total dissolved solids (TDS) were low (6.7 mg/L), characteristic of unpolluted atmospheric moisture/air. Major ion concentrations (mg/L) were low and in the order K+ 〉 Ca2+ 〉 Mg2~ 〉 Na+ for cations and NO3 〉〉 HCO3 〉 SO] 〉 CI- 〉 PO3- 〉 F- for anions. The average rainwater in the area was mixed Ca-Mg-SO4-CI water type. The CI-/Na+ ratio (1.04) was comparable to that of seawater (1.16), an indication that N a+ and CI originated mainly from marine (Atlantic Ocean) aerosols. High enrichments of Ca2+, Mg2+ and SO2- to Na+ ratios relative to seawater ratios (constituting 44% of the total ions) demonstrated their terrigenous origin, mainly from Saharan and Sahelian arid dusts. The K+/Na+ ratio (2.24), which was similar to tropical vegetation ash (2.38), and NO3 was essentially from biomass burning. Light (〈 100 mm) pre-monsoon and post-monsoon convective rains were enriched in major ions than the heavy (〉 100 mm) monsoon rains, indicating a high contribution of major ions during the low convective showers. Despite the acidic nature, the TDS and major ion concentrations classified the rainwater as potable based on the WHO guidelines. 相似文献
170.
采用CWAO(催化湿式空气氧化)法处理甲基橙模拟印染废水,以过量浸渍法制备催化剂,以水样COD Cr去除率和脱色率表征催化剂的活性,以催化剂使用后处理出水中溶出的金属离子质量浓度表征催化剂的稳定性.结果表明,多组分催化剂的金属组分构成为Cu、Fe、La,m(Cu)∶m(Fe)∶m(La)为1∶1∶2,35℃下动态共浸渍8 h,450℃下焙烧3 h,由此制备得到Cu-Fe-La/FSC催化剂.应用该催化剂,以CWAO法处理模拟印染废水,废水COD Cr去除率和脱色率可分别达到79.1%和98.9%,催化剂的活性较高;使用该催化剂处理后的废水中Cu、Fe、La、Al的溶出量(以ρ计)分别为6.1、2.4、2.2、3.2 mg/L,说明金属元素的溶出量较低,催化剂的稳定性较高. 相似文献