四川酸雨的综合防治对策研究

本文在四川酸雨来源、成因、危害的基础上，结合国内外酸雨防治的经验，确定了四川酸雨的主要控制因子、控制目标和致酸污染物的削减率。针对四川的特点，提出了控制四川酸雨的战略和工程措施，为四川的经济发展、城市建设与环境保护等的规划、决策提供了科学依据。     

Compromise solutions to the acid deposition control problem: a theoretical model and some simulation results

Acid deposition is a muitifaceted environmental phenomenon whose control represents one of the most controversial environmental policy areas. Because of the longrange transport of air pollutants contributing to acid deposition, its control is the responsibility of more than one region. Given the interdependence between the economic and environmental impacts of acid deposition as well as the interregional conflicts over its control, the present article proposes an interregional integrated economic-environmental model for the study of the impacts of acid deposition control policies. This model is solved with the use of a compromise programming procedure which facilitates the explicit treatment of conflicting regional goals. After the theoretical and operational forms and the solution procedure of the proposed model are described, the use of the model is illustrated with a simulation example using the 1963 MRIO accounts and hypothetical environmental data. The compromise programming procedure can form the basis for interactive decision processes when policy makers are exposed to the solutions yielded by the model. The model's usefulness and future research directions are discussed.     

Acid deposition in aquatic ecosystems: Setting limits empirically

The problem of acid deposition and its harmful effects on aquatic ecosystems has created a new branch of science that is called upon to provide the knowledge on which legislative controls can be based. However, because of the nature of existing legislation, which requires evidence of cause and effect between industrial emissions and pollution, and because of science's inability to provide this information over the short term, considerable controversy has arisen about whether sufficient information exists to warrant control measures at this time. Among those who advocate controls, there is genuine divergence of opinion about how stringent the controls must be to achieve any desired level of protection.The controversy has led to an impasse between the scientific and political participants, which is reflected in the slow pace of progress toward an effective management strategy. Resolution of the impasse, at least in the short term, may demand that science and politics rely on empirical models rather than explanatory ones. The empirical model, which is the major proposal in this article, integrates all of the major variables and many of the minor ones, and constructs a three-dimensionally curved surface capable of representing the status of any waterbody subjected to the effects of acid deposition. When suitably calibrated—a process involving the integration of knowledge and data from aquatic biology, geochemistry, meteorology, and limnology—it can be used to depict limits to the rate of acid deposition required for any level of environmental protection. Because it can generate a pictorial display of the effects of management decisions and legislative controls, the model might serve as a basis for enhancing the quality of communication among all the scientific and political participants and help to resolve many of their controversies.     

EVALUATION OF NEXRAD STAGE III PRECIPITATION DATA OVER A SEMIARID REGION1

This study examines NEXRAD Stage III product (hourly, cell size 4 km by 4 km) for its ability in estimating precipitation in central New Mexico, a semiarid area. A comparison between Stage III and a network of gauge precipitation estimates during 1995 to 2001 indicates that Stage III (1) overestimates the hourly conditional mean (CM) precipitation by 33 percent in the monsoon season and 55 percent in the nonmonsoon season; (2) overestimates the hourly CM precipitation for concurrent radar‐gauge pairs (nonzero value) by 13 percent in the monsoon season and 6 percent in the nonmonsoon season; (3) overestimates the seasonal precipitation accumulation by 11 to 88 percent in monsoon season and underestimates by 18 to 89 percent in the nonmonsoon season; and (4) either overestimates annual precipitation accumulation up to 28.2 percent or underestimates it up to 11.9 percent. A truncation of 57 to 72 percent of the total rainfall hours is observed in the Stage III data in the nonmonsoon season, which may be the main cause for both the underestimation of the radar rainfall accumulation and the lower conditional probability of radar rainfall detection in the nonmonsoon season. The study results indicate that the truncation caused loss of small rainfall amounts (events) is not effectively corrected by the real‐time rain gauge calibration that can adjust the rainfall rates but cannot recover the truncated small rainfall events. However, the truncation error in the monsoon season may be suppressed due to the larger rainfall rate and/or combined effect of overestimates by bright band and hail contaminations, virga, advection, etc. In general, improvement in NEXRAD performance since the monsoon season in 1998 is observed, which is consistent with the systematic improvement in the NEXRAD network.     

贵州地区酸雨作用下典型森林植被冠层淋溶规律研究

选择贵州龙里生态园为研究区域,对当地马尾松林和针阔混交林2种典型植被的冠层穿透水化学特征进行了比较,分析了酸雨作用下植被的冠层淋溶规律.对2007年6月～2008年11月的监测数据的分析结果表明,酸雨经过森林冠层后,pH值明显升高,针阔混交林对酸雨的缓冲性能优于马尾松林.在常年酸沉降作用下,2种冠层对NH4+具有较强的吸收作用,对NO3-也有一定的吸收,对当地土壤酸化起到了一定的缓冲作用.通过雨量加权计算,研究区森林冠层析出量最大是Mg2+、K+、Ca2+等营养元素离子,长期的酸雨影响易造成森林营养亏损.     

酸雨对泰山古碑石刻侵蚀的模拟研究

为研究我国华东典型山地地区的酸沉降对文物古迹的影响,选取与泰山古碑石刻材质相同的花岗石,采用pH分别为3.0、3.8、4.7、5.6的人工模拟酸雨对泰山花岗石进行周期浸泡实验,测定不同pH值下的腐蚀速率;同时利用扫描电子显微镜(SEM)观测试验前后样品表面特征;并对浸泡前后的样品表面粉末进行X射线衍射分析。实验结果表明:影响石材腐蚀的主要因素是酸雨的酸度;花岗石石样受到侵蚀后,质量减少百分数随pH值降低而增大,最大质量损失达到0.073%,而当pH值大于3.8时,石样的最终腐蚀情况基本一致,基本在0.02%左右;并且无论是高酸度酸雨,还是低酸度酸雨,都对材料外观造成了损害;蚀后样品查出了CaSO4和MgSO4相分。     

降水量对降水酸度的影响分析——以重庆为例

利用重庆市主城区5年的酸雨观测资料和降水资料,采用统计和建模的方法分析了各次降水的降水量对酸雨的影响。结果表明,降水量对酸雨的影响非常明显。降水pH值随降水量的变化总体呈双谷W型,第一个最低值位于17mm的降水量附近,pH低至3.8;第二个最低值位于40mm的降水量附近,pH低至4.0。酸雨频率的变化规律与pH值相反,呈双峰M型。pH值随降水量的变化规律各季节基本一致,除冬季因无大的降水而呈V型外,其余三个季节都呈W型。将pH值随降水量的变化分为3个主要变化区域,构造了pH值随降水量变化的经验公式,该经验公式各组成部分及公式中各参数的物理意义都非常明确,经过意义明确的简单法则和计算即可确定公式中的参数。该经验公式的精度较高,对酸雨的深入研究具有一定的参考价值。     

β-环糊精接枝壳聚糖对酸性红R的吸附研究

为改善壳聚糖的吸附性能,用苯甲醛保护壳聚糖氨基,通过与环氧氯丙烷和β-环糊精的反应合成了新的吸附剂β-环糊精接枝壳聚糖,研究了其对偶氮染料酸性红R的吸附行为,考察了酸性红R的初始浓度、pH对吸附效果的影响。结果发现当酸性红R的浓度≤100mg/g时,合成物的吸附量随酸性红R浓度的增大而增加,当浓度进一步增大时,吸附量趋于平衡。合成物对酸性红R的吸附效果在pH为2～4之间最好。相比于Freundlich吸附等温式(R2=0.8476),β-环糊精接枝壳聚糖对酸性红R的吸附规律明显更符合Langmuir吸附等温式(R2=0.9977)。吸附动力学采用了准一级速率方程(R2=0.8609)和准二级速率方程来描述,结果表明吸附动力学符合准二级速率方程(R2=0.9945)。β-环糊精接枝后的壳聚糖对酸性红R的平衡吸附容量可以提高20.2mg/g。     

柠檬酸-Fe（Ⅱ）／K2S2O8降解泥水体系中敌草隆的研究

研究了泥水体系中柠檬酸-Fe（Ⅱ）／K2SO8降解敌草隆时各影响因子的作用机制,通过正交实验确定了反应的最佳操作条件为：K2SO8浓度为2．0mmol／L,Fe（Ⅱ）浓度为1．0mmol／L,柠檬酸浓度为0．5mmol／L,反应时间为120min,pH=7．0。此奈件下,0．1mmol／L敌草隆降解率可达97．6％。采用分子探针竞争实验鉴定了体系中产生的硫酸根自由基。     

湖南省酸性降水变化趋势及防治措施研究

酸性降水污染的研究在世界范围内发展迅速,酸雨已成为举世瞩目的污染问题。湖南省通过降水监测工作,积累了大量宝贵的监测数据。本文在对全省近8年的降水监测数据进行综合分析的基础上,研究了本省酸性降水的污染特征和变化趋势,分析了酸雨的成因,并提出了防治酸雨污染的对策和建议,为全面掌握湖南省酸雨污染现状和发展趋势,更好地制定全省的酸雨污染控制政策提供了依据。