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Carlos A. Grande Alírio E. Rodrigues 《International Journal of Greenhouse Gas Control》2008,2(2):194-202
One of the most important sources of CO2 emissions are the fossil-fuel fired plants for production of electricity. Removal of CO2 from flue gas streams for further sequestration has been proposed by the International Panel on Climate Change experts as one of the most reliable solutions to mitigate anthropogenic greenhouse emissions. When natural gas is employed as fuel, the molar fraction of CO2 in the flue gas is lower than 5% causing serious problems for capture. The purpose of this work is to present experimental validation of an Electric Swing Adsorption (ESA) technology that may be employed for carbon capture for low molar fractions of CO2 in the flue gas streams. To improve energy utilization, an activated carbon honeycomb monolith with low electrical resistivity was employed as selective adsorbent. A mathematical model for this honeycomb is proposed as well as different ESA cycles for CO2 capture. 相似文献
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Seyyed Salar Meshkat Ebrahim Ghasemy Alimorad Rashidi Omid Tavakoli Mehdi Esrafili 《Frontiers of Environmental Science & Engineering》2021,15(5):109
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The feasibility of using a chemical reaction-based approach for evaluating and modelling the role of adsorption reactions in determining the geochernical confinement capacity of natural geological barriers is being studied as part of an on-going R & D programme. The confined superficial aquifer underlying the Centre de Stockage de l'Aube facility, a geological barrier for this site, has been used as a case study with the following aims. First, development of a site characterisation protocol and demonstration of its use to determine the principal geochemical characteristics of aquifer materials using batch experiments and to represent the information obtained in terms of a chemical model. The experimental results obtained for Ni2+ partitioning as a function of total Ni, pH, total Ca and total solid can be satisfactorily represented in terms of reactions with an ion exchange site and a single amphoteric surface hydroxyl site with ferrihydrite reaction constants. A second objective is the incorporation of the reactions in a coupled geochemistry/transport code, and to verify the applicability of the coupled code predictions for Ni2+ mass transfer by comparison with the results obtained during column tracer experiments. The breakthrough curve and equilibrium solid phase Ni loading, predicted by a one-dimensional coupled model for a column tracer experiment, agree closely with observed data.Additional studies are underway to reduce model conditionality, to extend the adsorption model to other analogue cations and anions, to incorporate the effect of natural organic matter and to take into consideration precipitation/dissolution of amorphous Fe surface phases. 相似文献
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以Hg(NO3)2、Cu(NO3)2水溶液为模拟工业废水,以侧链具N、S配位基的网状聚合物冠醚为吸附剂,研究了聚合物冠醚对HP(2+)、Cu(2+)的吸附性能。讨论了溶液温度、pH值、金属离子浓度及时间对吸附性能的影响,该聚合物冠醚对Hg(2+)具有较高的吸附容量和较快的吸附速度。 相似文献
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以国产硅胶担体为固体吸附剂,采集空气中联苯-联苯醚。经热解吸、制冷、闪蒸后,用气相色谱法测定。实验结果,在常温下,国产硅胶对联苯-联苯醚的吸附率达100%;解吸回收率为97.5%:变异系数<5%;方法的检测限为0.4μg。 相似文献
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膨润土粘土矿吸附焦化废水中氨氮的研究 总被引:13,自引:0,他引:13
研究了膨润土粘土矿对碳酸铵溶液中NH4^+离子和焦化废水中氨氮的吸附。结果表明:在低液固比时,颗粒膨润土对碳酸铵溶液中NH4^+离子的吸附效果优于粉状膨润土;在高液固化时,粉状膨润土的吸附效果优于颗粒膨润土。颗粒膨润土对焦化废水中氨氮的吸附效果优于粉状膨润土和活化膨润土。 相似文献
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催化裂化废催化剂对废水中镉的吸附研究 总被引:1,自引:0,他引:1
本文以石油催化裂化废催化剂作为废水中镉的吸附剂,探讨了吸附时间、温度、pH值、吸附剂用量对吸附效果的影响。吸附平衡试验结果表明,废催化剂对镉的吸附属单分子层吸附,吸附较易进行,吸附过程可用Langmuir模式和Freundich模式较好地描述。 相似文献