Persistent organic pollutants in soils and sediments from James Ross Island, Antarctica

Soil and sediment samples from James Ross Island were analyzed for their PCB, OCP and PAH contents. Soil concentrations ranged between 0.51 and 1.82 ng g(-1) for seven indicator PCB congeners, between 0.49 and 1.34 ng g(-1) for HCH congeners, between 0.51 and 3.68 ng g(-1) for the sum of p,p'-DDT, DDE, and DDD, and between 34.9 and 171 ng g(-1) for the sum of 16 EPA PAHs. Sediment levels from 0.32 to 0.83 ng g(-1) were found for PCBs, from 0.14 to 0.76 ng g(-1) for HCHs, from 0.19 to 1.15 ng g(-1) for DDTs, and from 1.4 to 205 ng g(-1) for PAHs. A prevalence of low-mass PAHs, less chlorinated PCBs, and more volatile chemicals indicates that the long-range atmospheric transport from populated areas of Africa, South America, and Australia is the most probable contamination source for the solid matrices in James Ross Island.     

Historical record of polycyclic aromatic hydrocarbons (PAHs) and spheroidal carbonaceous particles (SCPs) in marine sediment cores from Admiralty Bay, King George Island, Antarctica

This paper describes the first results of polycyclic aromatic hydrocarbons (PAHs) and spheroidal carbonaceous particles (SCPs) in sediment cores of Admiralty Bay, Antarctica. These markers were used to assess the local input of anthropogenic materials (particulate and organic compounds) as a result of the influence of human occupation in a sub-Antarctic region and a possible long-range atmospheric transport of combustion products from sources in South America. The highest SCPs and PAHs concentrations were observed during the last 30 years, when three research stations were built in the area and industrial activities in South America increased. The concentrations of SCPs and PAHs were much lower than those of other regions in the northern hemisphere and other reported data for the southern hemisphere. The PAH isomer ratios showed that the major sources of PAHs are fossil fuels/petroleum, biomass combustion and sewage contribution generally close to the Brazilian scientific station.     

中国南极长城站室内空气微生物状况

空气微生物是空气洁净程度的重要指标、环境污染状况的真实反映[1] .十年来 ,位于南极半岛的中国长城站常年有考察队员居住和工作 ,尤其在南极之夏 ,不时有各国考察、旅游、观光者出入 .这些都给长城站空气微生物的变化带入了外来因素[2 ] .我们于 1994年 2月 ,随机对站上 19个室内测点作空气微生物考察 ,以监测和比较室内空气微生物含量状况 ,为进一步了解空气微生物的卫生学意义 ,并服务于提高南极考察队员的身体素质 ,加深对南极生态系统的理解而提供一些资料 .1　材料与方法1 .1　测点1994年 2月份分 6天对 19个室内空间作了 2 0次测定 …     

Perfluorinated compounds in the Antarctic region: Ocean circulation provides prolonged protection from distant sources

In order to investigate the extent to which Perfluorinated Contaminants (PFCs) have permeated the Southern Ocean food web to date, a range of Antarctic, sub-Antarctic and Antarctic-migratory biota were analysed for key ionic PFCs.Based upon the geographical distribution pattern and ecology of biota with detectable vs. non-detectable PFC burdens, an evaluation of the potential contributory roles of alternative system input pathways is made. Our analytical findings, together with previous reports, reveal only the occasional occurrence of PFCs in migratory biota and vertebrate predators with foraging ranges extending into or north of the Antarctic Circumpolar Current (ACC).Geographical contamination patterns observed correspond most strongly with those expected from delivery via hydrospheric transport as governed by the unique oceanographic features of the Southern Ocean. We suggest that hydrospheric transport will form a slow, but primary, input pathway of PFCs to the Antarctic region.     

Anthropogenic contaminants in freshwater from the northern Antarctic Peninsula region

This study aimed to evaluate the presence of ultraviolet filters (UV-Fs), benzotriazoles, pyrethroids and per- and polyfluoroalkyl substances (PFASs) in freshwater and wastewater from the northern Antarctic Peninsula region. All water samples analyzed contained UV-Fs residues and high concentrations were detected in anthropogenic impacted sites (< LOD up to 1300 ng/L). Likewise, benzotriazoles were detected in all water samples (< LOQ–920 ng/L). Regarding suspended particulate matter, almost all UV-Fs and all benzotriazoles were measured at concentrations ranging from < LOQ to 33 µg/g dry weight. Pyrethroids were also detected (< LOQ–250 ng/L) and their presence implies the existence of a gateway to the Antarctica Peninsula from other regions. The data confirmed the presence of PFASs (< LOD–7500 ng/L) in this area, in agreement with previous studies. In light of these results, extended monitoring in Antarctica should be carried out to perform a reliable environmental risk assessment leading to propose recommendations to minimize the anthropic impact.Electronic supplementary materialThe online version of this article (10.1007/s13280-020-01404-x) contains supplementary material, which is available to authorized users.     

Spatial and temporal variability of marine-origin matter along a transect from Zhongshan Station to Dome A, Eastern Antarctica

The spatiotemporal distribution pattern of marine-origin matter on the Antarctica ice sheet was used to study variations in the source regions, transport mechanisms and postdepositional influences. We present data on sea salt ions, sulfur components and stable isotopes from surface and snow pit samples collected along the transect route from Zhongshan Station to Dome A during the austral summer in 2012–2013. A general decreasing trend in the accumulation, sea salt ions and sulfur components occurred with increasing distance from the coast and increasing elevation. However, different sources of the marine components, transport pathways and post-depositional influences were responsible for their different spatial distribution patterns. The marine ions in the coastal snow pit varied seasonally, with higher sea salt ion concentrations in the winter and lower concentrations in the summer; the opposite pattern was found for the sulfur compounds. The sea ice area surrounding Antarctica was the main source region for the deposited sea salt and the open sea water for the sulfur compounds. No significant trends in the marine-origin components were detected during the past 3 decades. Several periods of elevated deposition of sea salt ions were associated with lower temperatures(based on δD and δ18O) or intensified wind fields. In comparison to the sea salt ions, the sulfur concentrations exhibited the opposite distribution patterns and were associated with changes in the surrounding sea ice extent.     

Antartic minerals: A common heritage approach

The potential value of Antarctic mineral resources, including petroleum, has already spurred efforts by the Antarctic Treaty powers to establish a legal and technical regime for minerals. Management and control of Antarctic minerals need not, however, be left to the countries that have staked territorial claims or otherwise been active in Antarctica. Possible mineral regimes include open access (or first-come, first-served) and a variety of multilateral and international approaches. This article suggests that a common heritage approach would be most suitable for Antarctica and, despite opposition to such an approach among the Antarctic Treaty powers, would be a practical solution to the mineral development issue. The time for international organizations to act to establish such a common heritage regime is, however, growing short.     

Mapping sediment contamination and toxicity in Winter Quarters Bay,McMurdo Station,Antarctica

Winter Quarters Bay (WQB) is a small embayment located adjacent to McMurdo Station, the largest researchbase in Antarctica. The bay is approximately 250 m wide andlong, with a maximum depth of 33 m. Historically, trashfrom the McMurdo Station was piled on the steep shoreline ofWQB, doused with fuel and ignited. That practice hasceased, and the adjacent land area has been regraded tocover the residual waste. The bottom of WQB remainslittered with drums, equipment, tanks, tires, cables, andother objects, especially the southeastern side of the baywhere dumping took place. Sediments are contaminated withPCBs, metals, and hydrocarbon fuels. The objectives of this study were to map the distributionof organic contaminants in WQB, assess the toxicity of WQB sediments using a simple microbial test, anddetermine correlations between toxicity and contaminantlevels. The study suggests that adverse ecological effectshave occurred from one or more of the contaminants found inWQB but the source of the toxic impacts to bay sedimentsremains unknown. Whole sediment toxicity was onlycorrelated with oil-equivalent while solvent extracts ofsediments were correlated with PAHs and oil-equivalent. Theauthors recommend that an integrated research plan bedeveloped that focuses on determining what additionalinformation is needed to make informed decisions on possibleremediation of WQB.     

Distribution of Heavy Metals in Surface Sediments from an Antarctic Marine Ecosystem

The concentrations of lead, cadmium, copper,chromium, iron, manganese and zinc in surfacesediments collected from Potter Cove, in the 25de Mayo Island (King George Island), Antarctica, andits drainage basin, were measured by atomic absorptionspectroscopy. The obtained results were use todetermine the areal and vertical distribution of themetals of in the Cove and potential sources of thesemetals to this environment. The geochemical datasuggest that most of the metals found in Potter Coveconstitute a redistribution of autochthonous materialswithin the ecosystem. Therefore, the metalconcentrations can be considered to be present atnatural background levels in surface sediments.     

The Fate in the Marine Environment of a Minor Diesel Fuel Spill from an Antarctic Research Station

Monitoring was undertaken of the fate in the marine environment of an accidental spill of diesel fuel (1000 litres) from Faraday Research Station, Galindez Island, Antarctica in March 1992. On the day after the incident concentrations in seawater reached a maximum of 540 µg 1-1 for n-alkanes and 222 µg 1-1 for polycyclic aromatic hydrocarbons (PAH). However, concentrations returned to local background levels within one week. The fuel had an immediate toxic effect on intertidal limpets in the local station area, and 100 animals were found dead the day after the spill. Surviving animals had elevated concentrations of both n-alkanes and PAH for over a month after the spill, reaching a maximum of 9960 µg kg-1 for n-alkanes and 90 µg kg-1 for PAH 30 days after the spill occurred. This was the result of accumulation from a residue of the diesel being flushed by rainwater into the littoral zone. Seven months after the spill concentrations of both n-alkanes and PAH in limpets living close to the station were still an order of magnitude greater than those found in animals at an uncontaminated control site. This is because limpets living in the littoral zone were continually exposed to chronic but low-level hydrocarbon contamination from station activities. The diesel spill itself had a very minor, localised and short-term impact on the Antarctic marine environment.