Density functional theory (DFT) studies of vanadium-titanium based selective catalytic reduction (SCR) catalysts

Based on density functional theory (DFT) and basic structure models, the chemical reactions on the surface of vanadium-titanium based selective catalytic reduction (SCR) denitrification catalysts were summarized. Reasonable structural models (non-periodic and periodic structural models) are the basis of density functional calculations. A periodic structure model was more appropriate to represent the catalyst surface, and its theoretical calculation results were more comparable with the experimental results than a non-periodic model. It is generally believed that the SCR mechanism where NH₃ and NO react to produce N₂ and H₂O follows an Eley-Rideal type mechanism. NH₂NO was found to be an important intermediate in the SCR reaction, with multiple production routes. Simultaneously, the effects of H₂O, SO₂ and metal on SCR catalysts were also summarized.     

Cumulative impact assessment in environmental planning: A coastal wetland watershed example

Several theoretical, analytical, and institutional difficulties have impeded the development and application of the assessment of cumulative environmental impacts. Watershed development on coastal wetlands offers an ideal context for evaluating the land disturbance target approach to cumulative impact assessment. A model land use planning system involving a time series approach was developed for Elkhorn Slough in California. The approach included four major components: evaluation of erosion susceptibility, measurement of land disturbance, establishment of a land disturbance target, and a comparison of existing and target land disturbance values. Further research is needed to test the transferability of the approach in a wide range of coastal watersheds and to verify the applicability of the methods to other cumulative impact problems.     

How effective are River Basin Management Plans in reaching the nutrient load reduction targets?

Riverine nutrient loads are among the major causes of eutrophication of the Baltic Sea. This study applied the Soil & Water Assessment Tool (SWAT) in three catchments flowing to the Baltic Sea, namely Vantaanjoki (Finland), Fyrisån (Sweden), and Słupia (Poland), to simulate the effectiveness of nutrient control measures included in the EU’s Water Framework Directive River Basin Management Plans (RBMPs). Moreover, we identified similar, coastal, middle-sized catchments to which conclusions from this study could be applicable. The first modelling scenario based on extrapolation of the existing trends affected the modelled nutrient loads by less than 5%. In the second scenario, measures included in RBMPs showed variable effectiveness, ranging from negligible for Słupia to 28% total P load reduction in Vantaanjoki. Adding spatially targeted measures to RBMPs (third scenario) would considerably improve their effectiveness in all three catchments for both total N and P, suggesting a need to adopt targeting more widely in the Baltic Sea countries.Electronic supplementary materialThe online version of this article (10.1007/s13280-020-01393-x) contains supplementary material, which is available to authorized users.     

Nitrogen fixation estimates for the Baltic Sea indicate high rates for the previously overlooked Bothnian Sea

Dense blooms of diazotrophic filamentous cyanobacteria are formed every summer in the Baltic Sea. We estimated their contribution to nitrogen fixation by combining two decades of cyanobacterial biovolume monitoring data with recently measured genera-specific nitrogen fixation rates. In the Bothnian Sea, estimated nitrogen fixation rates were 80 kt N year⁻¹, which has doubled during recent decades and now exceeds external loading from rivers and atmospheric deposition of 69 kt year⁻¹. The estimated contribution to the Baltic Proper was 399 kt N year⁻¹, which agrees well with previous estimates using other approaches and is greater than the external input of 374 kt N year⁻¹. Our approach can potentially be applied to continuously estimate nitrogen loads via nitrogen fixation. Those estimates are crucial for ecosystem adaptive management since internal nitrogen loading may counteract the positive effects of decreased external nutrient loading.     

Seasonal and spatial variability of Po,U and Pu levels in the river catchment area assessed by application of neural-network based classification

The present study deals with the application of self-organizing maps (SOM) in order to model, classify and interpret seasonal and spatial variability of ²¹⁰Po, ²³⁸U and ^239+240Pu levels in the Vistula river basin. The data set represents concentration values for 3 alpha emitters (²¹⁰Po, ²³⁸U and ^239+240Pu) measured in surface water samples collected at 19 different sampling locations (8 in major Vistula stream while 11 in right or left Vistula tributaries) during four seasons (winter, spring, summer and autumn) in the framework of a one-year quality monitoring study. The advantages of an SOM algorithm, its classification and visualization ability for environmental data sets, are stressed. The neural-network based classification made it possible to reveal specific patterns related to both seasonal and spatial variability. In the middle and upper part of Vistula catchment as well as in the right-shore tributaries, concentrations of ²¹⁰Po and ²³⁸U during summer and winter are the lowest. Concentrations of ²¹⁰Po and ²³⁸U increase significantly during spring and autumn in the Vistula river catchment, especially in the delta of Vistula river. High concentration of anthropogenic originated ^239+240Pu indicates “site-specific” character of pollution in two large left-shore tributaries located in the middle part of the Vistula drainage area. Efficient classification of sampling locations could lead to an optimization of river radiochemical sampling networks and to a better tracing of natural and anthropogenic changes along Vistula river stream.     

Transnational environmental collective action facing implementation constraints – the case of nutrient leakage in the Baltic Sea Action Plan

While scholars have showed a long-standing interest for how to design effective environmental treaties and other international agreements, less interest has been paid to implementation phases of these agreements. This article takes the Eutrophication Segment in the Baltic Sea Action Plan as an example of a regional effort to reduce nutrient leakages, where national reporting of adopted strategies has been a key mechanism to improve implementation effectiveness. It is shown that although transnational collective action theory is a powerful tool to analyse underlying drivers and priorities in state implementation policies, a deeper analysis of domestic and external constraints can shed additional light on observed implementation gaps. Varying views among countries on, for example, the role of stakeholder participation, legitimacy and top-down governing versus multi-stakeholder governance approaches may comprise domestic constraints that make effective and efficient implementation problematic. In terms of external constraints, states’ balancing of action plan objectives versus other international commitments, such as other environmental treaties and EU Directives, is shown to potentially reduce implementation efficiency as well.     

The Effects of Hypoxia on Sediment Nitrogen Cycling in the Baltic Sea

Primary production in the eutrophic Baltic Sea is limited by nitrogen availability; hence denitrification (natural transformation of nitrate to gaseous N₂) in the sediments is crucial in mitigating the effects of eutrophication. This study shows that dissimilatory nitrate reduction to ammonium (DNRA) process, where nitrogen is not removed but instead recycled in the system, dominates nitrate reduction in low oxygen conditions (O₂ <110 μM), which have been persistent in the central Gulf of Finland during the past decade. The nitrogen removal rates measured in this study show that nitrogen removal has decreased in the Gulf of Finland compared to rates measured in mid-1990s and the decrease is most likely caused by the increased bottom water hypoxia.     

Impact of Climate Change on Fish Population Dynamics in the Baltic Sea: A Dynamical Downscaling Investigation

Understanding how climate change, exploitation and eutrophication will affect populations and ecosystems of the Baltic Sea can be facilitated with models which realistically combine these forcings into common frameworks. Here, we evaluate sensitivity of fish recruitment and population dynamics to past and future environmental forcings provided by three ocean-biogeochemical models of the Baltic Sea. Modeled temperature explained nearly as much variability in reproductive success of sprat (Sprattus sprattus; Clupeidae) as measured temperatures during 1973-2005, and both the spawner biomass and the temperature have influenced recruitment for at least 50 years. The three Baltic Sea models estimate relatively similar developments (increases) in biomass and fishery yield during twenty-first century climate change (ca. 28 % range among models). However, this uncertainty is exceeded by the one associated with the fish population model, and by the source of global climate data used by regional models. Knowledge of processes and biases could reduce these uncertainties.     

Climate Change in the Baltic Sea Region: A Cross-Country Analysis of Institutional Stakeholder Perceptions

Before climate change is considered in long-term coastal management, it is necessary to investigate how institutional stakeholders in coastal management conceptualize climate change, as their awareness will ultimately affect their actions. Using questionnaires in eight Baltic Sea riparian countries, this study examines environmental managers' awareness of climate change. Our results indicate that problems related to global warming are deemed secondary to short-term social and economic issues. Respondents agree that problems caused by global warming will become increasingly important, but pay little attention to adaptation and mitigation strategies. Current environmental problems are expected to continue to be urgent in the future. We conclude that an apparent gap exists between decision making, public concerns, and scientific consensus, resulting in a situation in which the latest evidence rarely influences commonly held opinions.     

Modeling Nutrient Transports and Exchanges of Nutrients Between Shallow Regions and the Open Baltic Sea in Present and Future Climate

We quantified horizontal transport patterns and the net exchange of nutrients between shallow regions and the open sea in the Baltic proper. A coupled biogeochemical-physical circulation model was used for transient simulations 1961-2100. The model was driven by regional downscaling of the IPCC climate change scenario A1B from two global General Circulation Models in combination with two nutrient load scenarios. Modeled nutrient transports followed mainly the large-scale internal water circulation and showed only small circulation changes in the future projections. The internal nutrient cycling and exchanges between shallow and deeper waters became intensified, and the internal removal of phosphorus became weaker in the warmer future climate. These effects counteracted the impact from nutrient load reductions according to the Baltic Sea Action Plan. The net effect of climate change and nutrient reductions was an increased net import of dissolved inorganic phosphorus to shallow areas in the Baltic proper.