全文获取类型
收费全文 | 765篇 |
免费 | 38篇 |
国内免费 | 273篇 |
专业分类
安全科学 | 123篇 |
废物处理 | 22篇 |
环保管理 | 86篇 |
综合类 | 471篇 |
基础理论 | 143篇 |
污染及防治 | 180篇 |
评价与监测 | 28篇 |
社会与环境 | 20篇 |
灾害及防治 | 3篇 |
出版年
2024年 | 1篇 |
2023年 | 11篇 |
2022年 | 22篇 |
2021年 | 27篇 |
2020年 | 26篇 |
2019年 | 24篇 |
2018年 | 26篇 |
2017年 | 27篇 |
2016年 | 34篇 |
2015年 | 38篇 |
2014年 | 59篇 |
2013年 | 99篇 |
2012年 | 62篇 |
2011年 | 60篇 |
2010年 | 48篇 |
2009年 | 61篇 |
2008年 | 54篇 |
2007年 | 73篇 |
2006年 | 52篇 |
2005年 | 37篇 |
2004年 | 41篇 |
2003年 | 31篇 |
2002年 | 31篇 |
2001年 | 29篇 |
2000年 | 24篇 |
1999年 | 26篇 |
1998年 | 18篇 |
1997年 | 8篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 8篇 |
1992年 | 3篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1985年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有1076条查询结果,搜索用时 15 毫秒
101.
高温热表面油液蒸发的时变性热质传递模型与实验研究 总被引:1,自引:0,他引:1
针对高温热表面油液蒸发热质传递过程的时变性,考虑这一过程中的对流传质传热,建立了热环境作用下油液蒸发的热质传递模型方程,通过无量纲变换,求得空间浓度分布和温度场随时间的变化规律。以庚烷为试验对象,对高温热表面油液蒸发过程进行了实验研究。理论分析与实验表明:庚烷蒸发过程中,刘易斯数大于1,传热速率大于传质速率;蒸发导致的质量损失与时间平方根的成正比,与液面的面积成正比,且与质量扩散系数的平方根成正比,饱和蒸气浓度越大,蒸发速率也越大。油液蒸发计算结果与试验结果基本一致,表明了模型的有效性。 相似文献
102.
采用单波长法和双波长法,分别考察了KH2PO4、H3PO4、H2SO4、KNO3、牛肉膏和蛋白胨对Cr(III)和Cr(VI)质量浓度测定的影响。结果显示,Cr(III)和Cr(VI)在测量中是相互影响的,并且Cr(III)对Cr(VI)影响较显著。在单波长法测定中,牛肉膏、蛋白胨及2种酸对Cr(III)和Cr(VI)的影响较钾盐对其影响更为显著,H3PO4和H2SO4对Cr(III)和Cr(VI)的特征吸收峰值影响最大,降低幅度在20%~50%。这些物质对双波长法测定Cr(VI)几乎没有影响;但对Cr(III)测定中,H2SO4和H3PO4的影响较大,其相对误差分别为14.57%和8.87%,其余物质产生的相对误差均小于1.6%。因此,双波长法可用于生物样品中Cr(III)和Cr(VI)的测定,线性范围分别为0~160 mg/L和0~80mg/L。 相似文献
103.
104.
105.
Spill fires are common during oil product storage and transportation after a loss of containment. Since the burning fuel is moving and the fuel depth is quite shallow, the burning rate in a spill fire is different from that of a pool fire with a static burning zone. Unlike pool fires, which have been studied for decades and have well-established correlations for burning rate, research on spill fires is inadequate. In this paper, continuously released n-heptane spill fire experiments were conducted on open water surfaces with varying fuel discharge rates. The pool diameters were measured, and the spill fire burning rates were estimated based on a dynamic balance between fuel supply and combustion. The burning rates in n-heptane pool fires from the literature were reviewed and compared with the estimated burning rates in spill fires of the same dimension. The spill fire burning rate was found to be close to that in a pool fire during the initial burning phase but lower than that in a bulk burning pool fire and that in a “fuel-level-controlled” pool fire. The distinction between the burning rates of spill fires and pool fires is explained by the heat balance analysis of the fuel layer. A model for the spill fire burning rate was proposed accordingly. The results calculated with the presented model are closer to the measured data than those calculated with pool fire models. 相似文献
106.
贺旭云 《湖南环境生物职业技术学院学报》2005,11(1):37-39
湖南省许多企业由于仍然受计划经济体制的阴影笼罩,缺乏竞争观念,品牌意识淡薄,导致品牌难上档次,知名品牌缺少.因此,必须整合湖南品牌战略、实施企业形象战略、培育品牌文化战略和实施品牌战略. 相似文献
107.
Xyleborini are a species-rich tribe of ambrosia beetles, which are haplodiploid and typically mate among siblings within their
natal brood chamber. Several characteristics of this tribe would predict the evolution of higher levels of sociality: high
genetic relatedness within galleries due to inbreeding, high costs of dispersal and the potential benefit of cooperation in
brood care within the natal gallery (e.g. by fungus gardening, gallery extension, offspring feeding and cleaning). However,
information on the social system of these beetles is very limited. We examined the potential for cooperative breeding in Xyleborinus saxeseni by monitoring dispersal in relation to brood size and composition. Results show that adult female offspring delay dispersal
despite dispersal opportunities, and apparently some females never disperse. The females’ decision to stay seems to depend
on the presence of eggs and dependent siblings. We found no indication that female offspring reproduce in their natal gallery,
as colonies with many mature daughters do not contain more eggs than those with few or no daughters. There is a significant
positive relationship between the number of females present and the number of dependent siblings (but not eggs), which suggests
that cooperative brood care of female offspring raises colony productivity by improving survival rates of immatures. Our results
suggest that cooperative breeding is likely to occur in X. saxeseni and possibly other xyleborine species. We argue that a closer look at sociality within this tribe may yield important information
on the factors determining the evolution of cooperative breeding and advanced social organization. 相似文献
108.
通过转座子Tn5诱变和同源重组,构建了Bradyrhizobium japonicum USDA110聚羟丁酸合成酶基因(phbC)突变体.序列测定确定了转座子插入的精确位置,所获得的4个转座子诱变的质粒其Tn5插在phbC基因内两个相距仅9bp的位点.被Southern和PCR证实的突变体菌株仍能产生相当于野生型菌株12.97%—25.10%的PHB,并且在突变体和野生型菌株总DNA杂交图上都呈现出一条约5kb的阳性带,推测在B.japonicum基因组中存在不止一个聚羟丁酸合成酶基因.图3表4参17 相似文献
109.
X.G. Lin R. Yin H.Y. Zhang J.F. Huang R.R. Chen Z.H. Cao 《Environmental geochemistry and health》2004,26(2):119-128
A survey was done recently in Jiaxing city of Zhejiang Province in the Yangtze River Delta to compare the differences of soil microbiological properties among paddy soils with different land use including continuous open-field vegetable cultivation (OFVC), plastic-greenhouse vegetable cultivation (PGVC) and traditional rice–wheat rotation (RWR). The soil types included are percolating, permeable and waterlogged paddy soils. The results indicate that the microbial flora was markedly changed as the land use changed for all the three soil types. In continuous vegetable cultivation soils, especially in PGVC soils, the bacteria amounts decreased dramatically, but the fungal and actinomyce amounts increased as compared with RWR soils. The dehydrogenase activities decreased significantly in vegetable soils, especially in PGVC soils as compared with RWR soils. The microbial biomass C and the total phospholipid contents (TPL) in vegetable cultivation soil greatly decreased as compared with RWR soils. Biolog analysis indicated that the kinds of carbon sources that could be metabolized by native microbes in PGVC soils greatly decreased as compared with OFVC soils and RWR soils, revealing that microbial diversity had decreased since land use change. The activities of some soil enzymes including urease, invertase and phosphase were all lower in OFVC soils than those in RWR soils, and those in PGVC soils were the lowest. The degradation of microbiological activities in continuous vegetable cultivation soils, especially in PGVC soils, as compared with RWR soils might have been caused by soil acidification and accumulation of salts due to overuse of both organic and inorganic fertilizers in vegetable cultivation. 相似文献
110.
研究了UV/H2O2工艺对2,4-二氯酚(2,4-DCP)的去除效果和水中阴离子、腐殖酸对该工艺降解2,4-DCP的影响。结果表明:UV/H2O2工艺可以有效的去除水中2,4-DCP,光降解过程符合一级反应动力学模型;在H2O2投加量为8mg/L,1个30W低压汞灯照射下,2,4-DCP在蒸馏水和自来水中光降解速率常数分别为0.0232/min和0.0162/min;NO3-、Cl-、HCO3-对2,4-DCP光降解有抑制作用;当3种离子浓度为0.5mmol/L、10mmol/L、20mmol/L时,对2,4-DCP光降解的抑制程度为HCO3->NO3->Cl-;随着离子浓度增大,抑制作用增强;自来水中的光降解速率常数低于蒸馏水中的光降解速率常数是由于水中多种离子影响的结果;腐殖酸在低浓度时,促进光降解反应的进行,在高浓度时,2,4-DCP的光降解氧化受到抑制。 相似文献