Investigation of the common intermediates over Fe-ZSM-5 in NH3-SCR reaction at low temperature by in situ DRIFTS

The surface species formed in the reaction of NO and NO₂ with pre-adsorbed NH₃ over a Fe-ZSM-5 catalyst (1.27 wt.% Fe, SiO₂/Al₂O₃ = 25) at low temperature (140°C) were studied by in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Through using a background spectrum of NH₃-saturated Fe-ZSM-5, we clearly observed the formation of common intermediates resulting from the reaction of NO₂ or NO + O₂ with pre-adsorbed NH₃. This presents strong evidence that the oxidation of NO to form surface nitrates and nitrites is the key step for standard SCR at low temperature. In addition, the results suggest that in the SCR reaction at low temperature, the NH₄⁺ ions absorbed on Brønsted acid sites are less active than NH₃ adsorbed on Lewis acid sites related to Fe species.     

金属阳离子对高硅分子筛催化氧化NO的影响

采用离子交换法制备了Na-、K-、Co-、NiZSM-5分子筛催化剂.测试了它们催化氧化NO的性能并通过XRD、BET、ICP-MS和Py-IR等表征,结果表明,CoZSM-5分子筛对NO催化氧化具有最高的活性,氧化率达到47%,主要是引入Co离子的ZSM-5表面酸性最适宜NO氧化.同时,在湿度100%条件下,考察了氧气浓度（5%~20%）,空速与二氧化硫浓度（0~200×10^-6）等对CoZSM-5分子筛催化氧化NO性能的影响.实验结果表明,在30℃、空速14400h^-1和相对湿度100%条件下,SO₂浓度在200×10^-6以下对催化氧化NO基本无影响.56h催化剂稳定性实验结果表明,在30℃、NO进口浓度600×10^-6、空速18000h^-1和饱和水汽（RH：100%）条件下,CoZSM-5分子筛催化剂对NO的氧化率可维持在40%左右.因此CoZSM-5分子筛催化剂具有良好的NO氧化稳定性、抗水性和一定的抗硫性.     

佛山市南海城区环境空气中铅污染现状分析研究

为了解佛山市南海城区环境空气中铅污染现状,在南海城区中心设置空气质量监测点,采用重量法和电感耦合等离子体质谱法分别对空气颗粒物及不同粒径颗粒物的铅含量进行定量分析,测定结果为:TSP、PM10、PM2.5平均浓度分别是150 ug/m3、99 ug/m3、67 ug/m3,其中铅平均浓度分别是214 ng/m3、175 ng/m3、156 ng/m3.结论为:南海城区环境空气中的铅浓度达到国家环境空气质量二级标准,铅污染水平处于珠江三角洲的中游;大气中的铅主要分布在PM2.5中,机动车尾气是其主要来源.     

生活垃圾制备衍生燃料(RDF-5)——以重庆市为例

以重庆市生活垃圾为例,通过分选、破碎和干燥预处理后,得到以塑料、纸类、竹木、织物和厨余为主要成分的制备衍生燃料(RDF-5)的原料,测试了不同含水率和成型压力条件下制得的RDF-5的理化性质.结果表明,原料含水率为8%,成型压力为10 MPa时,RDF-5的延展率和耐性指数良好,便于贮存和运输.燃烧试验表明,RDF-5燃烧后灰渣的热灼减率满足《生活垃圾焚烧污染控制标准》(GB 18485—2014)的要求(5%).另外,根据2006 IPCC国家温室气体名录导则和生命周期评价(LCA),制备RDF-5对温室气体排放贡献为455.92 g·kg-1RDF-5(以CO2当量计).     

Refuse-derived fuel as a secondary energy in Taiwan—Using Hotelling space allocation model

Most Taiwanese farmers usually blend rice straws into the soil after harvest. However, rice straws possess great thermal energy, which can be used to produce refuse-derived fuel (RDF-5). As Taiwan faces energy shortage, the development benefits of the RDF-5 industry are tempting. This study employs the Hotelling model to design the locations and the optimal numbers of RDF-5 plants. From the technology and material supply point of view, turning waste rice straws into RDF-5 is feasible in Taiwan. Nevertheless, from the business operation perspective, even if the RDF-5 plant is willing to lower its profit rate, its selling price is still hard to compete with imported RDF-5. If the Taiwanese government decides to pursue RDF-5 as an alternative energy, they might need to take a step further to subsidize entrepreneurs or provide appropriate tax benefits. Otherwise, the RDF-5 industry is hard to survive in Taiwan.     

芽孢杆菌Z5溶铜绿微囊藻特性研究

从利用铜绿微囊藻液人工驯化的活性污泥中分离出一株编号为Z5的溶藻细菌,通过生理生化实验及16S rDNA序列分析,鉴定为芽孢杆菌.研究了Z5菌对铜绿微囊藻(Microcystis aeruginosa PCC 7806)的溶藻能力,考察了不同生长期的Z5菌无菌滤液及添加比例对铜绿微囊藻生长的影响.结果表明,作用6d后,Z5菌稳定期的无菌滤液对处于稳定期的铜绿微囊藻的去除效果达到91.36%.在4%~12%的投加范围内,无菌滤液的投加量与对铜绿微囊藻生长的抑制作用和溶解作用呈正比.研究表明芽孢杆菌Z5是通过分泌具有部分热稳定性的溶藻活性物质进行溶藻.     

MO_x-CeO_2/HZSM-5催化剂催化氧化含氯挥发性有机物研究

采用浸渍法制备了不同过渡金属掺杂的MOx-CeO2/HZSM-5（M分别表示Cr、Mn、Fe、Co、Ni和Cu）催化剂,研究了各催化剂对1,2-二氯乙烷（DCE）的催化降解性能.结果表明,过渡金属掺杂后,MOx-12%CeO2/HZSM-5催化剂催化氧化1,2-二氯乙烷（DCE）的活性明显提高.各催化剂（记为M-CeO...     

多参数水质测定仪测定水中BOD5的不确定度评定

分析多参数水质测定仪测定水中BOD5的影响因素,并对各影响因素的不确定度进行计算和评定。结果表明影响其测量不确定度的主要因素是测量重复性的不确定度,其它因素是次要的。     

Fog simulation using a mesoscale model in and around the Yodo River Basin, Japan

In this study,fog simulations were conducted using the Fifth-Generation NCAR/Penn State Mesoscale Model (MM5) in and around the Yodo River Basin,Japan.The purpose is to investigate the MM5 performance of fog simulation for long-term periods.The simulations were performed for January,February,March,and July,2005 with a coarse 3-kin and a nested fine 1-km grid domains. Results of the simulations were compared with data from ten meteorological observatories,fog sampling site in Mt.Rokko,and visibility measu...     

Biodecolorization and partial mineralization of Reactive Black 5 by a strain of Rhodopseudomonas palustris

A strain of photosynthetic bacterium, Rhodopseudomonas palustris W1, isolated from a lab-scale anaerobic moving bed biofilm reactor (MBBR) treating textile e?uent was demonstrated to decolorize Reactive Black 5 (RB5) effciently under anaerobic condition. By a series of batch tests, the suitable conditions for RB5 decolorization were obtained, namely, pH < 10, light presence, glutamine or lactate as carbon source with concentration more than 500 mg/L when lactate is selected, NH4Cl as a nitrogen source with ...