石灰湿法脱硫过程中pH条件对结垢的影响研究

针对石灰湿法脱硫中存在的结垢问题，在鼓泡床中模拟了石灰湿法脱硫过程，通过分析液相的组成，结合反应机理探讨了pH对结垢的影响。结果表明，当pH控制在6.0～4．0时，既能避免结垢，又能获得较高的脱硫率。提出了实际中预测结垢倾向的方法。     

基于模糊评价的VDT系统搜索策略绩效形成机理研究

为优化视觉显示终端（VDT）结构性搜索界面的布局,提高作业绩效和安全,设计了VDT系统搜索实验,构建了搜索目标位置在4个主观偏好指标下的Pythagorean模糊集决策矩阵,运用交互式多准则决策（TODIM）法计算各目标位置偏好的总体优势度并排序;同时对VDT系统搜索实验中各目标位置的绩效进行方差分析并排序,分析系统搜索策略下作业者对目标位置的主观偏好与绩效之间的关系。研究结果表明:基于系统搜索策略的VDT作业绩效在不同目标位置差异显著;导致绩效差异的根本原因是作业者对搜索目标位置的主观偏好度,而不是搜索目标的位置属性;除中心区域外,偏好度高的区域搜索绩效要优于偏好度低的区域。     

Analysis of crater formation in buried NG pipelines: A survey based on past accidents and evaluation of domino effect

The formation of a crater by the abrupt and catastrophic rupture of a high-pressure pipeline can be highly relevant, especially when the crater uncovers other pipelines, which could undergo a domino effect with a significant increase of the consequences on people or on the environment. However, this scenario has been only partially studied in the literature. To assess the influence of the pipeline parameters on the dimensions of the resulting crater, a statistical analysis of accidental ruptures of buried natural gas pipelines that have involved the formation of a crater was carried out. Mathematical expressions are proposed to describe the proportionality relationships found, which can be very useful to support adequate separation distances in the design and construction of parallel corridors of pipelines after appropriate escalating effects are considered. Finally, detailed event trees were developed to calculate the probability of occurrence of the final outcomes, as well as the identified domino sequences, based on a qualitative and quantitative analysis of the data. The study of these accident scenarios, based on actual cases, represents a useful and needed advance in risk analysis of natural gas transportation through pipelines.     

中国人口集疏格局与形成机制研究

人口集聚和疏散是人口空间分布格局最直观和最集中的体现,基于人口集聚度的中国人口集疏的空间格局和形成机制的研究,有助于准确把握中国人口空间分布的基本脉络,具有重要的学术价值和实践意义。研究采用了人口集聚度分级评价的方法,依据人口集聚度的不同,将各个地区划分为不同等级的人口集聚区,并对其分别讨论。在此基础上,结合中国人口分布格局、自然条件的空间分布格局、人居环境自然适宜性评价结果以及经济发展格局和城市化格局,对中国的人口集疏的空间格局进行了归纳,并进一步对相应的形成机制进行了探讨,得出了我国人口分布的空间不平衡日益加剧,并呈现沿海、沿江、沿线集聚的态势的基本结论,并对我国人口分布集疏格局的形成进行了探讨,提出了自然因素奠定我国人口分布的基本格局,而经济发展不平衡与城市化成为人口集聚的动力的观点。     

Radon, helium and CO2 measurements in soils overlying a former exploited oilfield, Pechelbronn district, Bas-Rhin, France

The Pechelbronn oilfield (Rhine Graben, France), where mining activity ended in the 1960s, has been used for waste disposal for twenty years. Since the wastes are varied, work is underway to identify the discharged materials and their derivatives, as well as to locate and quantify potential discharge sites. Two major goals were assigned to the present work. The first was to identify or refine the location of hidden structures that could facilitate gas emanation up to the surface, by studying soil gas concentrations (mainly ²²²Rn, CO₂, CH₄ and helium) and carbon isotope ratios in the CO₂ phase. The second was devoted to examining, from a health and safety viewpoint, if the use of the oilfield as a waste disposal site might have led to enhanced or modified gas emanation throughout the area.It appeared that CO₂ and ²²²Rn evolution in the whole area were similar, except near some of the faults and fractures that are known through surface mapping and underground observations. These ²²²Rn and CO₂ anomalies made it possible to highlight more emissive zones that are either related to main faults or to secondary fractures acting as migration pathways. In that sense, the CO₂ phase can be used to evaluate ²²²Rn activities distant from tectonic structures but can lead to erroneous evaluations near to gas migration pathways. Dumping of wastes, as well as oil residues, did not appear to have a strong influence on soil gaseous species and emanation. Similarly, enhanced gas migration due to underground galleries and exploitation wells has not been established. Carbon isotope ratios suggested a balance of biological phenomena, despite the high CO₂ contents reached. Other monitored gaseous species (N₂, Ar, H₂ and alkanes), when detected, always showed amounts close to those found subsurface and/or in atmospheric gases.     

The ecological effects of trichloroacetic acid in the environment

Trichloroacetic acid (TCAA) is a member of the family of compounds known as chloroacetic acids, which includes mono-, di- and trichloroacetic acid. The significant property these compounds share is that they are all phytotoxic. TCAA once was widely used as a potent herbicide. However, long after TCAA's use as a herbicide was discontinued, its presence is still detected in the environment in various compartments. Methods for quantifying TCAA in aqueous and solid samples are summarized. Concentrations in various environmental compartments are presented, with a discussion of the possible formation of TCAA through natural processes. Concentrations of TCAA found to be toxic to aquatic and terrestrial organisms in laboratory and field studies were compiled and used to estimate risk quotients for soil and surface waters. TCAA levels in most water bodies not directly affected by point sources appear to be well below toxicity levels for the most sensitive aquatic organisms. Given the phytotoxicity of TCAA, aquatic plants and phytoplankton would be the aquatic species to monitor for potential effects. Given the concentrations of TCAA measured in various soils, there appears to be a risk to terrestrial organisms. Soil uptake of TCAA by plants has been shown to be rapid. Also, combined uptake of TCAA from soil and directly from the atmosphere has been shown. Therefore, risk quotients derived from soil exposure may underestimate the risk TCAA poses to plants. Moreover, TCE and TCA have been shown to be taken up by plants and converted to TCAA, thus leading to an additional exposure route. Mono- and di-chloroacetic acids can co-occur with TCAA in the atmosphere and soil and are more phytotoxic than TCAA. The cumulative effects of TCAA and compounds with similar toxic effects found in air and soil must be considered in subsequent terrestrial ecosystem risk assessments.     

The impact of natural and anthropogenic hydrocarbons on the tropospheric budget of carbon monoxide

A method to quantify the relative contributions of surface sources and photochemical production of atmospheric carbon monoxide has been implemented in a three-dimensional chemical-transport model. The impact of biogenic and anthropogenic hydrocarbons has been calculated. The oxidation of isoprene contributes to about 10% of the global tropospheric burden of carbon monoxide, with a maximum contribution over southern America and Africa. Oxidation of methane and terpenes contribute to 28 and 2%, respectively, of the tropospheric burden of CO. The oxidation of the other hydrocarbons, which include ethane, propane, ethylene, propylene and the surrogate hydrocarbon representing other hydrocarbons results in 12% of the CO tropospheric burden, among which 69% results from the oxidation of hydrocarbons of biologic origin. The overall global CO yield from the oxidation of isoprene is estimated to be 23% on a carbon basis. Comparisons between model results and the few available observations of isoprene, terpenes and their oxidation products show that there is no evidence that the current global isoprene emissions proposed in the IGAC/GEIA emissions data base are substantially overestimated, as suggested by previous studies.     

Biospheric influence on carbon dioxide measurements in Italy

The study concerning carbon dioxide measurements taken during the 1997, 1998 and 1999 summer campaigns at two different altitude stations and biospheric conditions are presented. The higher station (Mt. Cimone, 2165 m a.s.l.) is characterised by 360° free horizon and is located on a rocky mountain while the lower (Ninfa lake, 1550 m a.s.l.) is located inside the red spruce and beech forest. The different behaviour of CO₂ at the two mountain stations has been registered. It shows the strong effect of nighttime soil emission and vegetation respiration on CO₂ mixing ratio increases and of diurnal vegetative activity on CO₂ concentration decreases at the lower measurement site. The baseline character of the higher measurement site has been confirmed by comparison of CO₂ diurnal amplitudes recorded at the two stations.     

Compostability of Poly(lactide): Degradation in an Inert Solid Medium

Commercial poly(lactide) degradation was studied in an inert solid medium simulating compost conditions, with the aim to achieve a complete carbon balance of the polymer degradation. The mineralisation rate at the end of the test was compared to those obtained for poly(lactide) degradation in compost. It was shown that the mineralisation rate after 45 days of degradation was quite lower in inert solid medium than in compost but the standard deviation of data was enhanced. A protocol for both extraction and quantification of the carbon included in the different degradation by-products was proposed and the carbon balance of the polymer degradation was followed during the test with a satisfactory accuracy. The non-degraded PLA material was recovered during the test, hence the evolution of the glass transition temperature and the molecular weight was followed. A two-step degradation mechanism was highlighted in inert solid medium, showing the fundamental role of abiotic reactions for PLA degradation in compost.     

矿产资源规划理论的形成和发展

矿产资源规划是区域发展规划的重要组成部分,是政府对矿业经济进行宏观调控的一种手段。本文从理论更新和完善的角度重新确立了区域矿产资源规划的理论体系,提出矿产资源规划理论经历形成、发展与创新三个阶段,并就矿产资源配置与价格规律、矿产资源经济区划理论和可持续发展理论在其中的深远影响进行了初步探讨。