海洋碳汇渔业绿色发展空间外溢效应评价研究

海洋碳汇渔业绿色发展空间关联性及其外溢效应对于海水养殖业的有效协调和区域海洋环境的有效保护具有重要意义,科学估算沿海各省(自治区)海水养殖渔业碳汇量并探讨其空间相关性特征是制定差异化渔业碳汇发展政策的重要基础。根据2006—2016年中国大陆沿海9个省(自治区)的碳汇渔业资源清查数据,在检验和比较省域空间渔业碳汇总量相关性特征的基础上,运用空间计量模型分析了渔业碳汇的外溢效应及其影响因素。结果表明:①中国海水养殖渔业碳汇量整体上呈现上升趋势,但各省渔业碳汇量也存在明显差异。②研究期内的Moran's I指数整体呈现为"V"型的波动变化特征,渔业碳汇在省域空间分布上的差异性并不是随机的,而是具备显著的空间相关性。③海水养殖渔业碳汇存在明显的空间外溢效应,通过随机效应的杜宾模型分解后得出渔业产值、劳动力投入的直接效应为正,而渔业受灾面积和科研项目经费投入的直接效应为负;从间接效应来看,渔业产值在各省域间存在竞争与依存关系,海水养殖业劳动力投入和渔业技术推广的项目经费投入在各省域间存在互补关系。因此,中国沿海各省份在发挥海洋水产养殖业生态功能时,应当考虑省域区位因素,合理制定兼具差异化和协调性的海洋碳汇渔业发展政策。     

火电厂CO2捕集与封存技术探讨

火电厂CO2减排技术主要包括燃烧前处理、燃烧中减排及燃烧后捕集三类。介绍了IGCC、富氧燃烧、胺吸收法、生物法等CO2捕集与封存技术,分析其存在问题及应用前景。     

Cracking styrene derivative polymers in decalin solvent with metal-supported carbon catalysts

The cracking of styrene derivative polymers dissolved in decalin was conducted with metal-supported carbon catalysts under an inert gas atmosphere to recover monosubstituted styrene or monosubstituted ethylbenzene in higher yields than is obtained by pyrolysis, and to elucidate the detailed reaction mechanisms in the solvent. Poly-(4-methylstyrene), poly-(4-t-butylstyrene), poly-(α-methylstyrene), and polystyrene were used. In decalin without a catalyst, each polymer was decomposed into the monomer, dimer, and trimer derived from the corresponding polymer except for poly-(α-methylstyrene), which was decomposed into the monomer and styrene. By using metal-supported carbon, the olefinic compounds derived from the corresponding polymer were thoroughly hydrogenated to the saturated form in a nitrogen atmosphere by a hydrogen transfer reaction from decalin, which was simultaneously dehydrogenated to tetralin and naphthalene with the evolution of hydrogen gas. In comparison with metal species, Pd- and Ru-supported carbon catalysts maintained the hydrogenation activity for a longer time and with a lower evolution of hydrogen than Pt or Rh. The dehydrogenation of decalin was mainly observed not on the metal surfaces, but on the carbon surfaces over Pd-supported carbon. Stabilization of the monomers will be able to suppress the coking which occurs with repolymerization in long running process. Received: July 19, 2000 / Accepted: March 16, 2001     

碳汇造林项目促进了当地经济发展吗?--基于四川县域面板数据的PSM-DID实证研究

林业是重要的碳汇资源,在减缓全球气候变化、改善自然生态环境、促进经济可持续发展等方面有着至关重要的作用。作为林业碳汇的重要实现形式,碳汇造林项目兼具生态保护、促进经济发展与贫困减缓等重要功能,其实施成效究竟如何需要进一步验证。为此,本文从理论上分析了碳汇造林项目对县域经济发展的影响机理,利用2000—2016年四川47个县域的面板数据,采用PSM-DID模型估计了碳汇造林项目对县域经济发展的平均效应和动态效应,并对其影响机理进行了验证。结果显示:①碳汇造林项目的实施显著地促进了地区实际GDP和人均实际GDP的增长,这一结论在进行稳健性检验后依然成立;②囿于项目周期较长,此促进作用在短期内尚不能立竿见影,具有明显的滞后效应,且实施的时间越长,对当地经济发展的促进作用越大;③碳汇造林项目主要通过优化当地产业结构、提高居民储蓄率、提升地区政府财政收支水平等途径促进当地经济发展。因此,为更好地发挥碳汇造林项目对县域经济发展的促进作用,应继续拓展碳汇造林项目的覆盖区域,加大专项投资力度,引导碳汇造林项目向生态脆弱的深度贫困地区倾斜;在更加注重碳汇造林项目的长期效应的同时,应建立完善项目运行的长效稳定机制,防范潜在的自然与市场风险,保障项目对地区经济发展的长期驱动力;加快改善地区的融资环境,鼓励居民和企业将储蓄和融资能力有效转化为投资能力,充分依托碳汇造林项目促进当地经济可持续发展。     

Estimation of atmospheric trace metal emissions in Vilnius City, Lithuania, using vertical concentration gradient and road tunnel measurement data

A new approach for the estimation of trace metal emissions in Vilnius city was implemented, using vertical concentration profiles in the urban boundary layer and road tunnel measurement data. Heavy metal concentrations were examined in fine and coarse particle fractions using a virtual impactor (cut-off size diameter 2.5 μm). Negative vertical concentration gradients were obtained for all metals (Ba, Pb, V, Sb, Zn) and both fractions. It was estimated that the vertical concentration gradient was formed due to emissions from an area of about 12 km². Road tunnel measurements indicated that trace metal concentrations on fine particles were lower than those on coarse particles, which suggested that re-emitted road dust was highly enriched in trace metal due to historic emissions within the tunnel. Emission rates of different pollutants in the road tunnel were calculated using pollutant concentration differences at the tunnel entrance and exit and traffic flow data. Heavy metal emission rates from the area of Vilnius city were estimated using the vertical gradient of heavy metal concentrations and the coefficient of turbulent mixing, as derived from meteorological measurement data. The emission values calculated by the two different methods coincided reasonably well, which indicated that the main source of airborne trace metals in Vilnius city is traffic. The potential of the vertical concentration gradient method for the direct estimation of urban heavy metal emissions was demonstrated.     

Quantitative analysis of pyrrolizidine alkaloids sequestered from diverse host plants in Longitarsus flea beetles (Coleoptera, Chrysomelidae)

Summary. Several species of the flea beetles genus Longitarsus are able to sequester pyrrolizidine alkaloids (PAs) from their host plants. In five Longitarsus species we compare the concentration of PAs present in their host plants belonging to the Asteraceae or Boraginaceae with those found in the beetles. To get an estimate of the intrapopulation variability, three samples of five beetles each and five individual plants were analyzed for each comparison. A strong intrapopulation variability could be detected both among plant and beetle samples. The total concentration found in the beetles varied strongly between species. The local host plant and its phenology influence the concentrations present in the beetles as evidenced in comparisons of a single beetle species from two different hosts and of one beetle species collected at the same site at different times of the year. In addition, different beetle species apparently vary in their capacity to sequester the alkaloids, at the lowest extreme the mean PA concentration in the beetles (0.034 μg PA/mg dry weight) was 1/30 of the mean concentration found in the plant leaves (L. aeruginosus from Eupatorium cannabinum), at the highest extreme (2.098 μg PA/mg dw) the concentration in the beetles was a 1000 fold higher than in the plant leaves (L. nasturtii from Symphytum officinale). The highest mean concentration found in the beetles was 3.446 μg/mg dw (L. exoletus from Cynoglossum officinale). The absolute concentrations found in the beetles are comparable to other insects which have been shown to be effectively defended against their potential predators. Received 22 June 1999; accepted 25 August 1999     

National policies for biosphere greenhouse gas management: issues and opportunities

Biosphere greenhouse gas (GHG) management consists of preserving and enhancing terrestrial carbon pools and producing biomass as a fossil fuel substitute. The discussion of this topic has focused primarily on carbon-accounting and project-level issues, particularly relating to carbon sequestration as a source of emissions credits under the Kyoto Protocol. While international consensus on these matters is needed, this paper argues that an important domestic policy agenda also deserves attention. National policies for biosphere GHG management are necessary to bring about large-scale changes in land-use, forestry, and agricultural practices and can address some of the technical and policy issues that have proven to be particularly problematic from carbon-accounting and project-level perspectives. These policies should minimize land-use and resource-management conflicts, account for collateral benefits, and ensure institutional compatibility with existing resource-management regimes. Issues relating to project permanence, leakage, and transaction costs should also be addressed. A range of policy instruments should be used and biosphere GHG management should be one component of an integrated approach to environmental and resource management. Countries promoting biosphere GHG management as an important element of their climate change strategies should be developing these domestic policies to complement international negotiations and to demonstrate that carbon sequestration and biomass production can make an effective contribution to the stabilization of atmospheric GHG concentrations.     

Lay concepts on CCS deployment in Switzerland based on qualitative interviews

Laypeople's acceptance and perception of Carbon Dioxide Capture and Storage (CCS) can have an influence on its political feasibility. It is important, therefore, to study how laypeople perceive CCS and which cognitions they hold with respect to this technique. We conducted in-depth interviews with laypeople (N = 16) to explore their mental concepts of CCS. Little knowledge about CCS was detected among laypeople. We also found that laypeople fear that a deployment of CCS could create incentives that would hinder a sustainable development of the energy economy. A misunderstanding of the concepts of hydro- and geostatic pressure, as well as a lack of knowledge about the physical–chemical properties of carbon dioxide seemed to trigger fundamental rejection of CCS among some laypeople. This qualitative study identifies concepts that underlie CCS perception, and these should be objects of future studies. We provide some suggestions for risk management and communication about CCS.     

炭素焙烧沥青烟气治理

采用生石灰吸附袋式除尘法治理炭素焙烧窑沥青烟气 ,具有很好的效果。治理前烟尘 114 8.7mg/ Nm3,沥青烟 480 .5mg/ Nm3,苯并 (a)芘 3 .462 mg/ Nm3;治理后烟尘 12 .8mg/ Nm3,沥青烟 11.0 mg/ Nm3,苯并 (a)芘 3 .0× 10 - 4m g/ Nm3。从运行效果来看 ,烟气的充分冷却和选用生石灰做吸附剂是治理成功的关键。     

炭催化剂吸附剂标准物质的研制

本文介绍了炭催化剂吸附剂标准物质的研制过程。对标准物质的制备技术、均匀性检验、稳定性考察及定值和不确定度进行了逐项分析。采用活性炭浸渍、煅烧技术制得炭催化剂吸附剂标准物质。试验结果表明,该标准物质定值结果准确,均匀性、稳定性良好。铜含量的标准值为11．06％,扩展不确定度为0．13％。